Efficient Cobalt Catalyst for Ambient-Temperature Nitrile Dihydroboration, the Elucidation of a Chelate-Assisted Borylation Mechanism, and a New Synthetic Route to Amides.
Authors of publication
Ghosh, Chandrani; Kim, Suyeon; Mena, Matthew R.; Kim, Jun-Hyeong; Pal, Raja; Rock, Christopher L.; Groy, Thomas L.; Baik, Mu-Hyun; Trovitch, Ryan J.
Journal of publication
Journal of the American Chemical Society
Year of publication
2019
Journal volume
141
Journal issue
38
Pages of publication
15327 - 15337
a
8.6432 ± 0.001 Å
b
11.3302 ± 0.0013 Å
c
11.4891 ± 0.0014 Å
α
105.192 ± 0.002°
β
92.884 ± 0.002°
γ
107.735 ± 0.002°
Cell volume
1023.8 ± 0.2 Å3
Cell temperature
123 ± 0.1 K
Ambient diffraction temperature
123 ± 0.1 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.052
Residual factor for significantly intense reflections
0.0412
Weighted residual factors for significantly intense reflections
0.0925
Weighted residual factors for all reflections included in the refinement
0.0974
Goodness-of-fit parameter for all reflections included in the refinement
