Information card for entry 4129816

Structure parameters

• Common name: KH-1450
• Chemical name: toste127
• Formula: C73 H50 Au2 Cl4 F10 O4 P2
• Calculated formula: C73 H50 Au2 Cl4 F10 O4 P2
• Title of publication: Phosphonium Formation by Facile Carbon-Phosphorus Reductive Elimination from Gold(III).
• Authors of publication: Kawai, Hiroyuki; Wolf, William J.; DiPasquale, Antonio G.; Winston, Matthew S.; Toste, F. Dean
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2016
• Journal volume: 138
• Journal issue: 2
• Pages of publication: 587 - 593
• a: 8.1704 ± 0.0018 Å
• b: 11.455 ± 0.002 Å
• c: 17.998 ± 0.004 Å
• α: 76.179 ± 0.004°
• β: 85.607 ± 0.004°
• γ: 79.817 ± 0.004°
• Cell volume: 1608.9 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0212
• Residual factor for significantly intense reflections: 0.018
• Weighted residual factors for significantly intense reflections: 0.0384
• Weighted residual factors for all reflections included in the refinement: 0.0405
• Goodness-of-fit parameter for all reflections included in the refinement: 1.085
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No