Information card for entry 4134380

Structure parameters

• Formula: C55 H50 Cl12 Ge N4 O4
• Calculated formula: C55 H50 Cl12 Ge N4 O4
• SMILES: [Ge]12(Oc3c(Cl)c(Cl)c(Cl)c(Cl)c3O1)(Oc1c(O2)c(Cl)c(Cl)c(Cl)c1Cl)=C1N(/C(=N/c2c(cccc2C(C)C)C(C)C)c2ccccc2)C=CN1C(=N\c1c(cccc1C(C)C)C(C)C)\c1ccccc1.ClCCl.ClCCl
• Title of publication: Ge(0) Compound Stabilized by a Diimino-Carbene Ligand: Synthesis and Ambiphilic Reactivity.
• Authors of publication: Nguyen, Minh Tho; Gusev, Dmitry; Dmitrienko, Anton; Gabidullin, Bulat M.; Spasyuk, Denis; Pilkington, Melanie; Nikonov, Georgii I.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2020
• Journal volume: 142
• Journal issue: 12
• Pages of publication: 5852 - 5861
• a: 9.0522 ± 0.0006 Å
• b: 12.8275 ± 0.0009 Å
• c: 25.9222 ± 0.0019 Å
• α: 85.175 ± 0.003°
• β: 82.476 ± 0.003°
• γ: 78.104 ± 0.003°
• Cell volume: 2914.9 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0658
• Residual factor for significantly intense reflections: 0.053
• Weighted residual factors for significantly intense reflections: 0.1112
• Weighted residual factors for all reflections included in the refinement: 0.1174
• Goodness-of-fit parameter for all reflections included in the refinement: 1.067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No