Information card for entry 4300781

Structure parameters

• Formula: Cl2 Co15 H155 Na5 O172 Si3 W24
• Calculated formula: Cl2 Co15 Na3 O176 Si3 W24
• SMILES: [W]1234(O[W]567(O[W]89%10(O[W]%11%12(O1)(O[W]1%13(O8)(O[W]8%14(O[W]%15%16(O[W]%17(O2)(O5)(=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])[O]47[Si]([O]8%16)([O]2[Co]45([Cl]7[Co]8%16%18([O]%19[Co]%20%21%22([O]=[W]%23%24%25(O[W]%26%27%28(O[W]%29%30%31(O[W]%32(O%26)(O%23)(O[W]%23%26%33(O[W]%34%35(O%29)(O[W]%29%36(O%23)(O[W](O%24)([O]%25[Si]([O]%27%31%32)([O]%23[Co]%247([O]7[Co]([O]=%15)([O]%30%24)([OH2])([O]=%14)[O]%34[Co]%237([Cl]7[Co]%142([O]4[Co]2([OH2])([O]=[W]4%15%23(O[W]%24%25(O[W]%27%30(O[W]%31(O%24)(O4)(O[W]4%24%32(O[W]%34%37(O%27)(O[W]%27%38(O4)(O[W](O%15)([O]%23[Si]([O]%25%30%31)([O]%18[Co]%197([O]%22%34)([OH2])[O]=%38)[O]%32%37%27)([O]%24)(=[O]2)=O)=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])[OH2])=O)=O)(=O)[O]8%20)(=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])=[O]%16)=O)([O]35)[O]%11%14)([OH2])[O]=%13)([OH2])[O]=%36)([OH2])[O]=%28)[O]%33%35%29)(O%26)(=[O]%21)=O)=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])=O)=O)=O)=O)=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])=O)[OH2])[OH2])([OH2])[O]=%17)[O]%10%121)(O6)=O)(O9)=O)=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])=O)=O)=O)=O.[Na+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O
• Title of publication: The Satellite-Shaped Co-15 Polyoxotungstate [Co~6~(H~2~O)~30~{Co~9~Cl~2~(OH)~3~(H~2~O)~9~(SiW~8~O~31~)~3~}]^5-^
• Authors of publication: Bassil, Bassem S.; Nellutla, Saritha; Kortz, Ulrich; Stowe, Ashley C.; van Tol, Johan; Dalal, Naresh S.; Keita, Bineta; Nadjo, Louis
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Journal issue: 8
• Pages of publication: 2659 - 2665
• a: 19.8754 ± 0.0017 Å
• b: 19.8754 ± 0.0017 Å
• c: 22.344 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 7644 ± 1.7 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 473 ± 2 K
• Number of distinct elements: 7
• Space group number: 176
• Hermann-Mauguin space group symbol: P 63/m
• Hall space group symbol: -P 6c
• Residual factor for all reflections: 0.0854
• Residual factor for significantly intense reflections: 0.0805
• Weighted residual factors for significantly intense reflections: 0.1496
• Weighted residual factors for all reflections included in the refinement: 0.1517
• Goodness-of-fit parameter for all reflections included in the refinement: 1.349
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No