Information card for entry 4301294

Structure parameters

• Formula: C24 H54 I2 P4 Si2
• Calculated formula: C24 H54 I2 P4 Si2
• SMILES: IP1P([Si](C(C)(C)C)(C(C)(C)C)C(C)(C)C)P(I)P1[Si](C(C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Supersilylated Tetraphosphene Derivatives M2[t-Bu3SiPPPPSi-t-Bu3] (M = Li, Na, Rb, Cs) and Ba[t-Bu3SiPPPPSi-t-Bu3]: Reactivity and Cis-Trans Isomerization
• Authors of publication: Andreas Lorbach; Andor Nadj; Sandor Tüllmann; Franz Dornhaus; Frauke Schödel; Inge Sänger; Günter Margraf; Jan W. Bats; Michael Bolte; Max C. Holthausen; Matthias Wagner; Hans-Wolfram Lerner
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 1005 - 1017
• a: 15.226 ± 0.005 Å
• b: 8.4316 ± 0.0008 Å
• c: 26.135 ± 0.008 Å
• α: 90°
• β: 90.4 ± 0.03°
• γ: 90°
• Cell volume: 3355.1 ± 1.5 ų
• Cell temperature: 149 ± 2 K
• Ambient diffraction temperature: 149 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.074
• Residual factor for significantly intense reflections: 0.0514
• Weighted residual factors for significantly intense reflections: 0.1154
• Weighted residual factors for all reflections included in the refinement: 0.1237
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No