Information card for entry 4301681

Structure parameters

• Common name: [SiPiPr3]Co(N2)
• Formula: C42 H60 Co N2 P3 Si
• Calculated formula: C42 H60 Co N2 P3 Si
• SMILES: [Co]123([N]#N)[P](c4c([Si]3(c3c([P]1(C(C)C)C(C)C)cccc3)c1c([P]2(C(C)C)C(C)C)cccc1)cccc4)(C(C)C)C(C)C.c1ccccc1
• Title of publication: Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands
• Authors of publication: Matthew T. Whited; Neal P. Mankad; Yunho Lee; Paul F. Oblad; Jonas C. Peters
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 2507 - 2517
• a: 12.6932 ± 0.0009 Å
• b: 15.4021 ± 0.0011 Å
• c: 20.6008 ± 0.0015 Å
• α: 90°
• β: 91.916 ± 0.001°
• γ: 90°
• Cell volume: 4025.2 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0823
• Residual factor for significantly intense reflections: 0.0475
• Weighted residual factors for significantly intense reflections: 0.105
• Weighted residual factors for all reflections included in the refinement: 0.1218
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No