Information card for entry 4301685

Structure parameters

• Common name: {[SiPiPr3]Co(OTf)}{OTf}
• Formula: C38 H54 Co F6 O6 P3 S2 Si
• Calculated formula: C38 H54 Co F6 O6 P3 S2 Si
• SMILES: [Co]123([Si](c4ccccc4[P]1(C(C)C)C(C)C)(c1ccccc1[P]2(C(C)C)C(C)C)c1ccccc1[P]3(C(C)C)C(C)C)OS(=O)(=O)C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands
• Authors of publication: Matthew T. Whited; Neal P. Mankad; Yunho Lee; Paul F. Oblad; Jonas C. Peters
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 2507 - 2517
• a: 10.8159 ± 0.001 Å
• b: 14.3316 ± 0.0013 Å
• c: 28.152 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4363.8 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.1379
• Residual factor for significantly intense reflections: 0.0783
• Weighted residual factors for significantly intense reflections: 0.1895
• Weighted residual factors for all reflections included in the refinement: 0.2174
• Goodness-of-fit parameter for all reflections included in the refinement: 1.007
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No