Information card for entry 4302026

Structure parameters

• Chemical name: /m-{1,4-Bis[bis(bis(o-methoxyphenoxy)phosphino)amino] benzene-1κP;2κP';3κP";4κP'"}tetrakis(chlorogold(I))
• Formula: C62 H60 Au4 Cl4 N2 O16 P4
• Calculated formula: C62 H60 Au4 Cl4 N2 O16 P4
• SMILES: c1(ccccc1OC)O[P](N([P](Oc1ccccc1OC)(Oc1c(OC)cccc1)[Au]Cl)c1ccc(N([P](Oc2ccccc2OC)(Oc2ccccc2OC)[Au]Cl)[P](Oc2ccccc2OC)(Oc2ccccc2OC)[Au]Cl)cc1)(Oc1ccccc1OC)[Au]Cl
• Title of publication: Group 11 Metal Chemistry of a Tetradentate Ligand, Phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2
• Authors of publication: Chelladurai Ganesamoorthy; Maravanji S. Balakrishna; Joel T. Mague
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 3768 - 3782
• a: 10.74 ± 0.0008 Å
• b: 12.1116 ± 0.0008 Å
• c: 25.674 ± 0.002 Å
• α: 90°
• β: 92.88 ± 0.001°
• γ: 90°
• Cell volume: 3335.4 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0243
• Residual factor for significantly intense reflections: 0.0219
• Weighted residual factors for significantly intense reflections: 0.0553
• Weighted residual factors for all reflections included in the refinement: 0.0564
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No