#------------------------------------------------------------------------------
#$Date: 2025-08-20 21:19:29 +0200 (Wed 20 de Aug de 2025) $
#$Revision: 301836 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/20/4302093.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302093
loop_
_publ_author_name
'Gerardo González-García'
'Eleuterio Álvarez'
'Ángel Marcos-Fernández'
'J. Alfredo Gutiérrez'
_publ_contact_author_address
;
 Dr. J. Alfredo Gutiérrez
 Departamento de Química, Universidad de Guanajuato. Noria Alta s/n.
 Guanajuato, Gto. 36050, México.
;
_publ_contact_author_email       jagutier@quijote.ugto.mx
_publ_contact_author_fax         'Ext. 8108'
_publ_contact_author_name        'Dr. J. Alfredo Gutiérrez'
_publ_contact_author_phone
'01 (473) 7320006, 7322034, 7324250 Ext 8101 y 8103'
_publ_section_title
;
Hexacoordinated Oligosilanes from a Hexacoordinated Silicon(IV) Complex
Containing an O,N,N,O Salen-type and Thiocyanato-N Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4231
_journal_page_last               4238
_journal_paper_doi               10.1021/ic8024364
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C32 H26 N4 O4 S2 Si'
_chemical_formula_sum            'C32 H26 N4 O4 S2 Si'
_chemical_formula_weight         622.78
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.786(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.2201(5)
_cell_length_b                   15.3980(7)
_cell_length_c                   34.5168(16)
_cell_measurement_reflns_used    9974
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.76
_cell_measurement_theta_min      2.13
_cell_volume                     5960.5(5)
_computing_cell_refinement       'Bruker (2006). APEX 2. Version 2.1.'
_computing_data_collection       'Bruker (2006). APEX 2. Version 2.1.'
_computing_data_reduction        'Bruker (2006). APEX 2. Version 2.1.'
_computing_molecular_graphics    'XP, SHELXTL v. 6.14 (Bruker, 2003)'
_computing_publication_material  'XCIF, SHELXTL v. 6.14 (Bruker, 2003)'
_computing_structure_refinement  'XL, SHELXTL v. 6.14 (Bruker, 2003)'
_computing_structure_solution    'Bruker (2006). APEX 2. Version 2.1.'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type
;
 Bruker-Nonius X8kappa APEX II CCD area detector'
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0660
_diffrn_reflns_av_sigmaI/netI    0.0627
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       49
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_number            97001
_diffrn_reflns_theta_full        30.58
_diffrn_reflns_theta_max         30.58
_diffrn_reflns_theta_min         1.45
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    0.264
_exptl_absorpt_correction_T_max  0.9540
_exptl_absorpt_correction_T_min  0.9226
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS, Bruker (2006). APEX 2. Version 2.1. Bruker Analytical
 X-ray Solutions, Madison, Wisconsin, USA.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.388
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2592
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.485
_refine_diff_density_min         -0.545
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.012
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     779
_refine_ls_number_reflns         18056
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.012
_refine_ls_R_factor_all          0.0918
_refine_ls_R_factor_gt           0.0481
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0414P)²+3.0257P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0946
_refine_ls_wR_factor_ref         0.1104
_reflns_number_gt                11876
_reflns_number_total             18056
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic8024364_si_002_2.cif
_cod_data_source_block           6
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4302093
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.50968(4) 0.47421(3) 0.372010(13) 0.01175(9) Uani 1 1 d . . .
S1 S 0.69306(5) 0.49269(5) 0.491209(15) 0.03787(15) Uani 1 1 d . . .
S2 S 0.21953(5) 0.43036(4) 0.281788(16) 0.02977(12) Uani 1 1 d . . .
O1 O 0.52340(10) 0.57576(7) 0.35312(3) 0.0141(2) Uani 1 1 d . . .
O2 O 0.64546(10) 0.44620(7) 0.35434(3) 0.0136(2) Uani 1 1 d . . .
O3 O 0.40860(11) 0.83333(8) 0.28589(4) 0.0192(3) Uani 1 1 d . . .
O4 O 0.86832(12) 0.28883(8) 0.26306(4) 0.0208(3) Uani 1 1 d . . .
N1 N 0.35748(12) 0.49611(9) 0.39303(4) 0.0125(3) Uani 1 1 d . . .
N2 N 0.49020(13) 0.36116(9) 0.39393(4) 0.0135(3) Uani 1 1 d . . .
N3 N 0.58136(13) 0.50668(10) 0.41872(4) 0.0160(3) Uani 1 1 d . . .
N4 N 0.42651(13) 0.43473(9) 0.32772(4) 0.0153(3) Uani 1 1 d . . .
C1 C 0.29107(15) 0.56465(11) 0.38643(5) 0.0127(3) Uani 1 1 d . . .
C2 C 0.33018(15) 0.63739(11) 0.36374(5) 0.0128(3) Uani 1 1 d . . .
C3 C 0.44156(15) 0.63711(11) 0.34583(5) 0.0120(3) Uani 1 1 d . . .
C4 C 0.47050(15) 0.70211(11) 0.31963(5) 0.0139(3) Uani 1 1 d . . .
H4 H 0.5446 0.7005 0.3071 0.017 Uiso 1 1 calc R . .
C5 C 0.39081(15) 0.76909(11) 0.31198(5) 0.0148(3) Uani 1 1 d . . .
C6 C 0.28280(16) 0.77397(12) 0.33138(5) 0.0174(4) Uani 1 1 d . . .
H6 H 0.2307 0.8219 0.3273 0.021 Uiso 1 1 calc R . .
C7 C 0.25365(16) 0.70846(11) 0.35630(5) 0.0163(4) Uani 1 1 d . . .
H7 H 0.1797 0.7111 0.3689 0.020 Uiso 1 1 calc R . .
C8 C 0.50617(16) 0.82237(12) 0.26025(5) 0.0206(4) Uani 1 1 d . . .
H8A H 0.5818 0.8260 0.2752 0.031 Uiso 1 1 calc R . .
H8B H 0.5033 0.8682 0.2405 0.031 Uiso 1 1 calc R . .
H8C H 0.4999 0.7655 0.2476 0.031 Uiso 1 1 calc R . .
C9 C 0.16630(15) 0.56704(11) 0.40032(5) 0.0148(3) Uani 1 1 d . . .
C10 C 0.07635(16) 0.52446(12) 0.37893(5) 0.0191(4) Uani 1 1 d . . .
H10 H 0.0951 0.4919 0.3566 0.023 Uiso 1 1 calc R . .
C11 C -0.04059(17) 0.53002(13) 0.39054(6) 0.0254(4) Uani 1 1 d . . .
H11 H -0.1020 0.5008 0.3762 0.031 Uiso 1 1 calc R . .
C12 C -0.06815(18) 0.57788(14) 0.42292(6) 0.0299(5) Uani 1 1 d . . .
H12 H -0.1485 0.5818 0.4307 0.036 Uiso 1 1 calc R . .
C13 C 0.02106(18) 0.61992(15) 0.44395(6) 0.0291(5) Uani 1 1 d . . .
H13 H 0.0017 0.6527 0.4662 0.035 Uiso 1 1 calc R . .
C14 C 0.13882(17) 0.61486(13) 0.43294(5) 0.0205(4) Uani 1 1 d . . .
H14 H 0.1999 0.6438 0.4476 0.025 Uiso 1 1 calc R . .
C15 C 0.30459(15) 0.42025(11) 0.41212(5) 0.0155(3) Uani 1 1 d . . .
H15A H 0.2508 0.3888 0.3937 0.019 Uiso 1 1 calc R . .
H15B H 0.2578 0.4392 0.4345 0.019 Uiso 1 1 calc R . .
C16 C 0.40625(15) 0.36160(11) 0.42575(5) 0.0157(3) Uani 1 1 d . . .
H16A H 0.4450 0.3846 0.4498 0.019 Uiso 1 1 calc R . .
H16B H 0.3768 0.3022 0.4308 0.019 Uiso 1 1 calc R . .
C17 C 0.53922(15) 0.28973(11) 0.38172(5) 0.0131(3) Uani 1 1 d . . .
C18 C 0.61995(15) 0.29144(11) 0.34986(5) 0.0145(3) Uani 1 1 d . . .
C19 C 0.67168(15) 0.37013(11) 0.33790(5) 0.0138(3) Uani 1 1 d . . .
C20 C 0.75732(15) 0.37090(11) 0.30948(5) 0.0147(3) Uani 1 1 d . . .
H20 H 0.7945 0.4239 0.3025 0.018 Uiso 1 1 calc R . .
C21 C 0.78804(15) 0.29386(11) 0.29135(5) 0.0161(3) Uani 1 1 d . . .
C22 C 0.73563(16) 0.21489(12) 0.30214(5) 0.0184(4) Uani 1 1 d . . .
H22 H 0.7556 0.1625 0.2894 0.022 Uiso 1 1 calc R . .
C23 C 0.65539(16) 0.21426(11) 0.33125(5) 0.0172(4) Uani 1 1 d . . .
H23 H 0.6226 0.1604 0.3392 0.021 Uiso 1 1 calc R . .
C24 C 0.92281(17) 0.36830(12) 0.25128(6) 0.0219(4) Uani 1 1 d . . .
H24A H 0.8612 0.4081 0.2412 0.033 Uiso 1 1 calc R . .
H24B H 0.9798 0.3562 0.2310 0.033 Uiso 1 1 calc R . .
H24C H 0.9647 0.3950 0.2736 0.033 Uiso 1 1 calc R . .
C25 C 0.51690(16) 0.20505(11) 0.40171(5) 0.0150(3) Uani 1 1 d . . .
C26 C 0.58357(18) 0.18444(12) 0.43492(6) 0.0219(4) Uani 1 1 d . . .
H26 H 0.6428 0.2236 0.4446 0.026 Uiso 1 1 calc R . .
C27 C 0.56421(19) 0.10695(13) 0.45409(6) 0.0268(4) Uani 1 1 d . . .
H27 H 0.6102 0.0932 0.4768 0.032 Uiso 1 1 calc R . .
C28 C 0.47838(19) 0.04969(12) 0.44026(6) 0.0256(4) Uani 1 1 d . . .
H28 H 0.4650 -0.0034 0.4535 0.031 Uiso 1 1 calc R . .
C29 C 0.4121(2) 0.06985(13) 0.40714(6) 0.0297(5) Uani 1 1 d . . .
H29 H 0.3530 0.0305 0.3975 0.036 Uiso 1 1 calc R . .
C30 C 0.43110(18) 0.14733(13) 0.38778(6) 0.0243(4) Uani 1 1 d . . .
H30 H 0.3853 0.1608 0.3650 0.029 Uiso 1 1 calc R . .
C31 C 0.62788(16) 0.50167(12) 0.44940(5) 0.0193(4) Uani 1 1 d . . .
C32 C 0.33847(16) 0.43342(11) 0.30841(5) 0.0160(3) Uani 1 1 d . . .
Si2 Si -0.01260(4) 0.42714(3) 0.126982(14) 0.01328(10) Uani 1 1 d . . .
S3 S 0.33229(5) 0.48347(3) 0.180929(17) 0.02823(12) Uani 1 1 d . . .
S4 S -0.17224(5) 0.32314(4) 0.011904(15) 0.03327(13) Uani 1 1 d . . .
O5 O -0.14156(11) 0.45893(8) 0.14801(4) 0.0160(3) Uani 1 1 d . . .
O6 O -0.02279(10) 0.32954(8) 0.14942(3) 0.0151(2) Uani 1 1 d . . .
O7 O -0.35809(11) 0.62978(8) 0.23555(4) 0.0210(3) Uani 1 1 d . . .
O8 O 0.10026(11) 0.08050(8) 0.22076(3) 0.0171(3) Uani 1 1 d . . .
N5 N 0.00212(13) 0.53572(10) 0.10162(4) 0.0169(3) Uani 1 1 d . . .
N6 N 0.12779(13) 0.39691(9) 0.10004(4) 0.0146(3) Uani 1 1 d . . .
N7 N 0.08794(13) 0.47164(10) 0.16691(4) 0.0167(3) Uani 1 1 d . . .
N8 N -0.09914(14) 0.38715(10) 0.08400(4) 0.0189(3) Uani 1 1 d . . .
C33 C -0.03962(16) 0.60961(11) 0.11428(5) 0.0162(3) Uani 1 1 d . . .
C34 C -0.11285(15) 0.61316(11) 0.14795(5) 0.0158(3) Uani 1 1 d . . .
C35 C -0.16533(15) 0.53702(11) 0.16233(5) 0.0148(3) Uani 1 1 d . . .
C36 C -0.25018(15) 0.54051(11) 0.19104(5) 0.0158(3) Uani 1 1 d . . .
H36 H -0.2886 0.4890 0.1993 0.019 Uiso 1 1 calc R . .
C37 C -0.27776(16) 0.61997(12) 0.20742(5) 0.0173(4) Uani 1 1 d . . .
C38 C -0.22188(17) 0.69664(12) 0.19510(5) 0.0198(4) Uani 1 1 d . . .
H38 H -0.2387 0.7505 0.2072 0.024 Uiso 1 1 calc R . .
C39 C -0.14304(16) 0.69299(12) 0.16559(5) 0.0190(4) Uani 1 1 d . . .
H39 H -0.1078 0.7452 0.1567 0.023 Uiso 1 1 calc R . .
C40 C -0.41710(18) 0.55275(13) 0.24841(6) 0.0236(4) Uani 1 1 d . . .
H40A H -0.3579 0.5121 0.2593 0.035 Uiso 1 1 calc R . .
H40B H -0.4598 0.5255 0.2264 0.035 Uiso 1 1 calc R . .
H40C H -0.4739 0.5681 0.2683 0.035 Uiso 1 1 calc R . .
C41 C -0.01718(16) 0.69186(11) 0.09269(5) 0.0169(4) Uani 1 1 d . . .
C42 C 0.08716(18) 0.73893(13) 0.09961(6) 0.0242(4) Uani 1 1 d . . .
H42 H 0.1454 0.7187 0.1180 0.029 Uiso 1 1 calc R . .
C43 C 0.10573(19) 0.81572(13) 0.07942(6) 0.0269(4) Uani 1 1 d . . .
H43 H 0.1768 0.8481 0.0842 0.032 Uiso 1 1 calc R . .
C44 C 0.02136(19) 0.84515(12) 0.05247(5) 0.0244(4) Uani 1 1 d . . .
H44 H 0.0345 0.8975 0.0387 0.029 Uiso 1 1 calc R . .
C45 C -0.08188(18) 0.79827(12) 0.04565(5) 0.0220(4) Uani 1 1 d . . .
H45 H -0.1396 0.8184 0.0270 0.026 Uiso 1 1 calc R . .
C46 C -0.10223(17) 0.72186(12) 0.06577(5) 0.0193(4) Uani 1 1 d . . .
H46 H -0.1740 0.6902 0.0612 0.023 Uiso 1 1 calc R . .
C47 C 0.06956(17) 0.52892(12) 0.06581(5) 0.0212(4) Uani 1 1 d . . .
H47A H 0.1011 0.5865 0.0585 0.025 Uiso 1 1 calc R . .
H47B H 0.0176 0.5070 0.0443 0.025 Uiso 1 1 calc R . .
C48 C 0.17122(17) 0.46598(12) 0.07429(6) 0.0209(4) Uani 1 1 d . . .
H48A H 0.1987 0.4403 0.0498 0.025 Uiso 1 1 calc R . .
H48B H 0.2392 0.4969 0.0870 0.025 Uiso 1 1 calc R . .
C49 C 0.19355(15) 0.32754(11) 0.10641(5) 0.0131(3) Uani 1 1 d . . .
C50 C 0.16492(15) 0.26323(11) 0.13521(5) 0.0131(3) Uani 1 1 d . . .
C51 C 0.06013(15) 0.26872(11) 0.15643(5) 0.0121(3) Uani 1 1 d . . .
C52 C 0.03596(15) 0.20856(11) 0.18536(5) 0.0135(3) Uani 1 1 d . . .
H52 H -0.0350 0.2131 0.1995 0.016 Uiso 1 1 calc R . .
C53 C 0.11618(15) 0.14215(11) 0.19325(5) 0.0136(3) Uani 1 1 d . . .
C54 C 0.22002(15) 0.13416(11) 0.17203(5) 0.0152(3) Uani 1 1 d . . .
H54 H 0.2743 0.0880 0.1773 0.018 Uiso 1 1 calc R . .
C55 C 0.24262(15) 0.19338(11) 0.14357(5) 0.0142(3) Uani 1 1 d . . .
H55 H 0.3127 0.1872 0.1291 0.017 Uiso 1 1 calc R . .
C56 C -0.00029(16) 0.09148(12) 0.24518(5) 0.0180(4) Uani 1 1 d . . .
H56A H -0.0742 0.0886 0.2293 0.027 Uiso 1 1 calc R . .
H56B H 0.0051 0.1480 0.2581 0.027 Uiso 1 1 calc R . .
H56C H -0.0002 0.0452 0.2647 0.027 Uiso 1 1 calc R . .
C57 C 0.30235(16) 0.31155(11) 0.08355(5) 0.0168(4) Uani 1 1 d . . .
C58 C 0.2900(2) 0.26564(16) 0.04907(6) 0.0340(5) Uani 1 1 d . . .
H58 H 0.2130 0.2497 0.0393 0.041 Uiso 1 1 calc R . .
C59 C 0.3906(2) 0.24303(19) 0.02891(7) 0.0480(7) Uani 1 1 d . . .
H59 H 0.3823 0.2111 0.0054 0.058 Uiso 1 1 calc R . .
C60 C 0.5024(2) 0.26656(15) 0.04278(7) 0.0376(6) Uani 1 1 d . . .
H60 H 0.5709 0.2511 0.0288 0.045 Uiso 1 1 calc R . .
C61 C 0.51477(18) 0.31242(14) 0.07680(6) 0.0296(5) Uani 1 1 d . . .
H61 H 0.5919 0.3288 0.0863 0.036 Uiso 1 1 calc R . .
C62 C 0.41503(16) 0.33494(13) 0.09736(6) 0.0228(4) Uani 1 1 d . . .
H62 H 0.4241 0.3664 0.1209 0.027 Uiso 1 1 calc R . .
C63 C 0.19143(17) 0.47695(11) 0.17365(5) 0.0175(4) Uani 1 1 d . . .
C64 C -0.13060(16) 0.36019(12) 0.05381(5) 0.0190(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Si1 O2 90.16(6) . . ?
O1 Si1 N3 92.49(7) . . ?
O2 Si1 N3 90.63(6) . . ?
O1 Si1 N4 91.97(6) . . ?
O2 Si1 N4 93.08(6) . . ?
N3 Si1 N4 174.19(7) . . ?
O1 Si1 N1 94.36(6) . . ?
O2 Si1 N1 175.46(6) . . ?
N3 Si1 N1 89.47(6) . . ?
N4 Si1 N1 86.48(6) . . ?
O1 Si1 N2 178.37(6) . . ?
O2 Si1 N2 91.46(6) . . ?
N3 Si1 N2 87.32(7) . . ?
N4 Si1 N2 88.12(7) . . ?
N1 Si1 N2 84.02(6) . . ?
C3 O1 Si1 130.66(11) . . ?
C19 O2 Si1 125.51(11) . . ?
C5 O3 C8 116.95(13) . . ?
C21 O4 C24 117.14(14) . . ?
C1 N1 C15 118.82(14) . . ?
C1 N1 Si1 126.07(12) . . ?
C15 N1 Si1 114.06(11) . . ?
C17 N2 C16 122.12(14) . . ?
C17 N2 Si1 125.77(12) . . ?
C16 N2 Si1 112.04(11) . . ?
C31 N3 Si1 160.52(15) . . ?
C32 N4 Si1 149.31(14) . . ?
N1 C1 C2 122.67(15) . . ?
N1 C1 C9 119.89(15) . . ?
C2 C1 C9 117.31(14) . . ?
C7 C2 C3 117.71(15) . . ?
C7 C2 C1 120.52(15) . . ?
C3 C2 C1 121.59(15) . . ?
O1 C3 C4 117.22(15) . . ?
O1 C3 C2 122.16(15) . . ?
C4 C3 C2 120.62(15) . . ?
C5 C4 C3 119.75(15) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
O3 C5 C4 124.19(15) . . ?
O3 C5 C6 115.11(15) . . ?
C4 C5 C6 120.70(16) . . ?
C7 C6 C5 119.06(16) . . ?
C7 C6 H6 120.5 . . ?
C5 C6 H6 120.5 . . ?
C6 C7 C2 121.96(16) . . ?
C6 C7 H7 119.0 . . ?
C2 C7 H7 119.0 . . ?
O3 C8 H8A 109.5 . . ?
O3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
O3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C14 C9 C10 120.21(17) . . ?
C14 C9 C1 120.48(16) . . ?
C10 C9 C1 119.22(15) . . ?
C11 C10 C9 119.56(18) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C12 C11 C10 120.30(19) . . ?
C12 C11 H11 119.9 . . ?
C10 C11 H11 119.9 . . ?
C13 C12 C11 119.92(18) . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C12 C13 C14 120.72(19) . . ?
C12 C13 H13 119.6 . . ?
C14 C13 H13 119.6 . . ?
C9 C14 C13 119.29(19) . . ?
C9 C14 H14 120.4 . . ?
C13 C14 H14 120.4 . . ?
N1 C15 C16 107.50(14) . . ?
N1 C15 H15A 110.2 . . ?
C16 C15 H15A 110.2 . . ?
N1 C15 H15B 110.2 . . ?
C16 C15 H15B 110.2 . . ?
H15A C15 H15B 108.5 . . ?
N2 C16 C15 105.32(13) . . ?
N2 C16 H16A 110.7 . . ?
C15 C16 H16A 110.7 . . ?
N2 C16 H16B 110.7 . . ?
C15 C16 H16B 110.7 . . ?
H16A C16 H16B 108.8 . . ?
N2 C17 C18 120.67(15) . . ?
N2 C17 C25 120.39(15) . . ?
C18 C17 C25 118.88(15) . . ?
C19 C18 C23 117.71(15) . . ?
C19 C18 C17 120.74(15) . . ?
C23 C18 C17 121.45(16) . . ?
O2 C19 C20 117.15(15) . . ?
O2 C19 C18 121.99(15) . . ?
C20 C19 C18 120.79(15) . . ?
C21 C20 C19 119.71(16) . . ?
C21 C20 H20 120.1 . . ?
C19 C20 H20 120.1 . . ?
O4 C21 C20 123.69(16) . . ?
O4 C21 C22 115.81(15) . . ?
C20 C21 C22 120.49(16) . . ?
C23 C22 C21 119.35(16) . . ?
C23 C22 H22 120.3 . . ?
C21 C22 H22 120.3 . . ?
C22 C23 C18 121.86(17) . . ?
C22 C23 H23 119.1 . . ?
C18 C23 H23 119.1 . . ?
O4 C24 H24A 109.5 . . ?
O4 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
O4 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C30 C25 C26 119.44(17) . . ?
C30 C25 C17 121.48(16) . . ?
C26 C25 C17 119.08(16) . . ?
C27 C26 C25 120.26(18) . . ?
C27 C26 H26 119.9 . . ?
C25 C26 H26 119.9 . . ?
C28 C27 C26 120.22(18) . . ?
C28 C27 H27 119.9 . . ?
C26 C27 H27 119.9 . . ?
C29 C28 C27 119.70(18) . . ?
C29 C28 H28 120.1 . . ?
C27 C28 H28 120.1 . . ?
C28 C29 C30 120.36(19) . . ?
C28 C29 H29 119.8 . . ?
C30 C29 H29 119.8 . . ?
C25 C30 C29 120.03(18) . . ?
C25 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
N3 C31 S1 178.67(18) . . ?
N4 C32 S2 179.10(18) . . ?
O6 Si2 O5 89.42(6) . . ?
O6 Si2 N8 91.72(7) . . ?
O5 Si2 N8 90.33(7) . . ?
O6 Si2 N7 92.04(6) . . ?
O5 Si2 N7 94.63(7) . . ?
N8 Si2 N7 173.81(7) . . ?
O6 Si2 N5 178.80(7) . . ?
O5 Si2 N5 91.75(6) . . ?
N8 Si2 N5 88.54(7) . . ?
N7 Si2 N5 87.61(7) . . ?
O6 Si2 N6 94.28(6) . . ?
O5 Si2 N6 175.53(7) . . ?
N8 Si2 N6 87.06(7) . . ?
N7 Si2 N6 87.75(7) . . ?
N5 Si2 N6 84.56(6) . . ?
C35 O5 Si2 126.75(11) . . ?
C51 O6 Si2 130.31(11) . . ?
C37 O7 C40 116.96(14) . . ?
C53 O8 C56 116.73(13) . . ?
C33 N5 C47 122.67(15) . . ?
C33 N5 Si2 125.04(12) . . ?
C47 N5 Si2 112.27(11) . . ?
C49 N6 C48 119.48(14) . . ?
C49 N6 Si2 125.72(12) . . ?
C48 N6 Si2 114.16(11) . . ?
C63 N7 Si2 137.14(14) . . ?
C64 N8 Si2 165.99(15) . . ?
N5 C33 C34 121.27(16) . . ?
N5 C33 C41 120.11(16) . . ?
C34 C33 C41 118.54(15) . . ?
C35 C34 C39 117.54(16) . . ?
C35 C34 C33 120.40(16) . . ?
C39 C34 C33 121.85(16) . . ?
O5 C35 C36 116.59(15) . . ?
O5 C35 C34 122.04(15) . . ?
C36 C35 C34 121.29(16) . . ?
C37 C36 C35 119.28(17) . . ?
C37 C36 H36 120.4 . . ?
C35 C36 H36 120.4 . . ?
O7 C37 C36 123.57(17) . . ?
O7 C37 C38 115.82(16) . . ?
C36 C37 C38 120.61(16) . . ?
C39 C38 C37 119.57(17) . . ?
C39 C38 H38 120.2 . . ?
C37 C38 H38 120.2 . . ?
C38 C39 C34 121.54(17) . . ?
C38 C39 H39 119.2 . . ?
C34 C39 H39 119.2 . . ?
O7 C40 H40A 109.5 . . ?
O7 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
O7 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C46 C41 C42 119.89(17) . . ?
C46 C41 C33 119.47(16) . . ?
C42 C41 C33 120.64(16) . . ?
C41 C42 C43 119.67(18) . . ?
C41 C42 H42 120.2 . . ?
C43 C42 H42 120.2 . . ?
C44 C43 C42 120.35(19) . . ?
C44 C43 H43 119.8 . . ?
C42 C43 H43 119.8 . . ?
C45 C44 C43 119.82(18) . . ?
C45 C44 H44 120.1 . . ?
C43 C44 H44 120.1 . . ?
C44 C45 C46 120.56(18) . . ?
C44 C45 H45 119.7 . . ?
C46 C45 H45 119.7 . . ?
C45 C46 C41 119.71(18) . . ?
C45 C46 H46 120.1 . . ?
C41 C46 H46 120.1 . . ?
N5 C47 C48 106.62(14) . . ?
N5 C47 H47A 110.4 . . ?
C48 C47 H47A 110.4 . . ?
N5 C47 H47B 110.4 . . ?
C48 C47 H47B 110.4 . . ?
H47A C47 H47B 108.6 . . ?
N6 C48 C47 108.39(14) . . ?
N6 C48 H48A 110.0 . . ?
C47 C48 H48A 110.0 . . ?
N6 C48 H48B 110.0 . . ?
C47 C48 H48B 110.0 . . ?
H48A C48 H48B 108.4 . . ?
N6 C49 C50 122.45(15) . . ?
N6 C49 C57 120.64(15) . . ?
C50 C49 C57 116.91(15) . . ?
C51 C50 C55 117.47(15) . . ?
C51 C50 C49 121.58(15) . . ?
C55 C50 C49 120.94(15) . . ?
O6 C51 C52 116.43(14) . . ?
O6 C51 C50 122.42(15) . . ?
C52 C51 C50 121.12(15) . . ?
C53 C52 C51 119.48(15) . . ?
C53 C52 H52 120.3 . . ?
C51 C52 H52 120.3 . . ?
O8 C53 C52 123.72(15) . . ?
O8 C53 C54 115.71(15) . . ?
C52 C53 C54 120.56(15) . . ?
C55 C54 C53 119.48(16) . . ?
C55 C54 H54 120.3 . . ?
C53 C54 H54 120.3 . . ?
C54 C55 C50 121.86(16) . . ?
C54 C55 H55 119.1 . . ?
C50 C55 H55 119.1 . . ?
O8 C56 H56A 109.5 . . ?
O8 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
O8 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C62 C57 C58 119.54(17) . . ?
C62 C57 C49 121.85(16) . . ?
C58 C57 C49 118.40(17) . . ?
C57 C58 C59 119.8(2) . . ?
C57 C58 H58 120.1 . . ?
C59 C58 H58 120.1 . . ?
C60 C59 C58 120.4(2) . . ?
C60 C59 H59 119.8 . . ?
C58 C59 H59 119.8 . . ?
C61 C60 C59 119.9(2) . . ?
C61 C60 H60 120.0 . . ?
C59 C60 H60 120.0 . . ?
C60 C61 C62 120.3(2) . . ?
C60 C61 H61 119.9 . . ?
C62 C61 H61 119.9 . . ?
C57 C62 C61 120.09(19) . . ?
C57 C62 H62 120.0 . . ?
C61 C62 H62 120.0 . . ?
N7 C63 S3 177.65(17) . . ?
N8 C64 S4 179.23(18) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 O1 1.7029(12) . ?
Si1 O2 1.7137(12) . ?
Si1 N3 1.8482(16) . ?
Si1 N4 1.8679(15) . ?
Si1 N1 1.9063(14) . ?
Si1 N2 1.9133(15) . ?
S1 C31 1.603(2) . ?
S2 C32 1.5971(19) . ?
O1 C3 1.3360(19) . ?
O2 C19 1.338(2) . ?
O3 C5 1.357(2) . ?
O3 C8 1.439(2) . ?
O4 C21 1.351(2) . ?
O4 C24 1.433(2) . ?
N1 C1 1.308(2) . ?
N1 C15 1.475(2) . ?
N2 C17 1.305(2) . ?
N2 C16 1.469(2) . ?
N3 C31 1.169(2) . ?
N4 C32 1.174(2) . ?
C1 C2 1.443(2) . ?
C1 C9 1.494(2) . ?
C2 C7 1.410(2) . ?
C2 C3 1.412(2) . ?
C3 C4 1.394(2) . ?
C4 C5 1.385(2) . ?
C4 H4 0.9500 . ?
C5 C6 1.405(2) . ?
C6 C7 1.372(2) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C14 1.388(2) . ?
C9 C10 1.395(3) . ?
C10 C11 1.387(3) . ?
C10 H10 0.9500 . ?
C11 C12 1.382(3) . ?
C11 H11 0.9500 . ?
C12 C13 1.379(3) . ?
C12 H12 0.9500 . ?
C13 C14 1.388(3) . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C15 C16 1.518(2) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.447(2) . ?
C17 C25 1.500(2) . ?
C18 C19 1.411(2) . ?
C18 C23 1.414(2) . ?
C19 C20 1.394(2) . ?
C20 C21 1.390(2) . ?
C20 H20 0.9500 . ?
C21 C22 1.406(2) . ?
C22 C23 1.370(2) . ?
C22 H22 0.9500 . ?
C23 H23 0.9500 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C30 1.385(3) . ?
C25 C26 1.386(3) . ?
C26 C27 1.385(3) . ?
C26 H26 0.9500 . ?
C27 C28 1.380(3) . ?
C27 H27 0.9500 . ?
C28 C29 1.380(3) . ?
C28 H28 0.9500 . ?
C29 C30 1.387(3) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
Si2 O6 1.6961(13) . ?
Si2 O5 1.7104(13) . ?
Si2 N8 1.8530(17) . ?
Si2 N7 1.8827(16) . ?
Si2 N5 1.8968(15) . ?
Si2 N6 1.9116(15) . ?
S3 C63 1.596(2) . ?
S4 C64 1.610(2) . ?
O5 C35 1.330(2) . ?
O6 C51 1.337(2) . ?
O7 C37 1.354(2) . ?
O7 C40 1.436(2) . ?
O8 C53 1.358(2) . ?
O8 C56 1.439(2) . ?
N5 C33 1.310(2) . ?
N5 C47 1.473(2) . ?
N6 C49 1.313(2) . ?
N6 C48 1.478(2) . ?
N7 C63 1.180(2) . ?
N8 C64 1.166(2) . ?
C33 C34 1.445(2) . ?
C33 C41 1.495(2) . ?
C34 C35 1.409(2) . ?
C34 C39 1.417(2) . ?
C35 C36 1.397(2) . ?
C36 C37 1.387(2) . ?
C36 H36 0.9500 . ?
C37 C38 1.409(3) . ?
C38 C39 1.371(3) . ?
C38 H38 0.9500 . ?
C39 H39 0.9500 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C46 1.390(3) . ?
C41 C42 1.391(3) . ?
C42 C43 1.391(3) . ?
C42 H42 0.9500 . ?
C43 C44 1.383(3) . ?
C43 H43 0.9500 . ?
C44 C45 1.379(3) . ?
C44 H44 0.9500 . ?
C45 C46 1.389(3) . ?
C45 H45 0.9500 . ?
C46 H46 0.9500 . ?
C47 C48 1.518(3) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 H48A 0.9900 . ?
C48 H48B 0.9900 . ?
C49 C50 1.446(2) . ?
C49 C57 1.494(2) . ?
C50 C51 1.407(2) . ?
C50 C55 1.409(2) . ?
C51 C52 1.395(2) . ?
C52 C53 1.384(2) . ?
C52 H52 0.9500 . ?
C53 C54 1.401(2) . ?
C54 C55 1.370(2) . ?
C54 H54 0.9500 . ?
C55 H55 0.9500 . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C57 C62 1.385(3) . ?
C57 C58 1.388(3) . ?
C58 C59 1.388(3) . ?
C58 H58 0.9500 . ?
C59 C60 1.377(4) . ?
C59 H59 0.9500 . ?
C60 C61 1.374(3) . ?
C60 H60 0.9500 . ?
C61 C62 1.388(3) . ?
C61 H61 0.9500 . ?
C62 H62 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 Si1 O1 C3 162.27(14) . . . . ?
N3 Si1 O1 C3 -107.09(15) . . . . ?
N4 Si1 O1 C3 69.18(15) . . . . ?
N1 Si1 O1 C3 -17.44(15) . . . . ?
O1 Si1 O2 C19 -139.17(13) . . . . ?
N3 Si1 O2 C19 128.33(14) . . . . ?
N4 Si1 O2 C19 -47.19(14) . . . . ?
N2 Si1 O2 C19 41.00(14) . . . . ?
O1 Si1 N1 C1 9.63(15) . . . . ?
N3 Si1 N1 C1 102.09(15) . . . . ?
N4 Si1 N1 C1 -82.08(15) . . . . ?
N2 Si1 N1 C1 -170.55(15) . . . . ?
O1 Si1 N1 C15 177.63(12) . . . . ?
N3 Si1 N1 C15 -89.91(12) . . . . ?
N4 Si1 N1 C15 85.92(12) . . . . ?
N2 Si1 N1 C15 -2.55(12) . . . . ?
O2 Si1 N2 C17 -25.86(15) . . . . ?
N3 Si1 N2 C17 -116.42(15) . . . . ?
N4 Si1 N2 C17 67.18(15) . . . . ?
N1 Si1 N2 C17 153.83(15) . . . . ?
O2 Si1 N2 C16 157.40(12) . . . . ?
N3 Si1 N2 C16 66.84(12) . . . . ?
N4 Si1 N2 C16 -109.56(12) . . . . ?
N1 Si1 N2 C16 -22.91(12) . . . . ?
O1 Si1 N3 C31 -166.0(4) . . . . ?
O2 Si1 N3 C31 -75.9(4) . . . . ?
N1 Si1 N3 C31 99.6(4) . . . . ?
N2 Si1 N3 C31 15.6(4) . . . . ?
O1 Si1 N4 C32 -73.3(3) . . . . ?
O2 Si1 N4 C32 -163.6(3) . . . . ?
N1 Si1 N4 C32 20.9(3) . . . . ?
N2 Si1 N4 C32 105.1(3) . . . . ?
C15 N1 C1 C2 -172.10(15) . . . . ?
Si1 N1 C1 C2 -4.6(2) . . . . ?
C15 N1 C1 C9 3.6(2) . . . . ?
Si1 N1 C1 C9 171.14(12) . . . . ?
N1 C1 C2 C7 177.74(16) . . . . ?
C9 C1 C2 C7 1.9(2) . . . . ?
N1 C1 C2 C3 2.7(3) . . . . ?
C9 C1 C2 C3 -173.10(15) . . . . ?
Si1 O1 C3 C4 -160.35(12) . . . . ?
Si1 O1 C3 C2 19.9(2) . . . . ?
C7 C2 C3 O1 175.37(15) . . . . ?
C1 C2 C3 O1 -9.5(3) . . . . ?
C7 C2 C3 C4 -4.3(2) . . . . ?
C1 C2 C3 C4 170.79(16) . . . . ?
O1 C3 C4 C5 -177.74(15) . . . . ?
C2 C3 C4 C5 2.0(3) . . . . ?
C8 O3 C5 C4 11.0(2) . . . . ?
C8 O3 C5 C6 -168.63(16) . . . . ?
C3 C4 C5 O3 -177.27(16) . . . . ?
C3 C4 C5 C6 2.3(3) . . . . ?
O3 C5 C6 C7 175.55(16) . . . . ?
C4 C5 C6 C7 -4.0(3) . . . . ?
C5 C6 C7 C2 1.6(3) . . . . ?
C3 C2 C7 C6 2.6(3) . . . . ?
C1 C2 C7 C6 -172.62(17) . . . . ?
N1 C1 C9 C14 103.4(2) . . . . ?
C2 C1 C9 C14 -80.6(2) . . . . ?
N1 C1 C9 C10 -80.0(2) . . . . ?
C2 C1 C9 C10 96.0(2) . . . . ?
C14 C9 C10 C11 -0.2(3) . . . . ?
C1 C9 C10 C11 -176.77(16) . . . . ?
C9 C10 C11 C12 0.5(3) . . . . ?
C10 C11 C12 C13 -0.4(3) . . . . ?
C11 C12 C13 C14 0.1(3) . . . . ?
C10 C9 C14 C13 -0.1(3) . . . . ?
C1 C9 C14 C13 176.42(17) . . . . ?
C12 C13 C14 C9 0.2(3) . . . . ?
C1 N1 C15 C16 -165.14(15) . . . . ?
Si1 N1 C15 C16 25.92(17) . . . . ?
C17 N2 C16 C15 -135.32(16) . . . . ?
Si1 N2 C16 C15 41.56(16) . . . . ?
N1 C15 C16 N2 -41.76(18) . . . . ?
C16 N2 C17 C18 178.92(15) . . . . ?
Si1 N2 C17 C18 2.5(2) . . . . ?
C16 N2 C17 C25 -3.8(2) . . . . ?
Si1 N2 C17 C25 179.74(12) . . . . ?
N2 C17 C18 C19 16.6(3) . . . . ?
C25 C17 C18 C19 -160.73(16) . . . . ?
N2 C17 C18 C23 -167.36(16) . . . . ?
C25 C17 C18 C23 15.3(3) . . . . ?
Si1 O2 C19 C20 149.30(13) . . . . ?
Si1 O2 C19 C18 -33.7(2) . . . . ?
C23 C18 C19 O2 -178.65(16) . . . . ?
C17 C18 C19 O2 -2.4(3) . . . . ?
C23 C18 C19 C20 -1.8(3) . . . . ?
C17 C18 C19 C20 174.40(16) . . . . ?
O2 C19 C20 C21 -179.90(15) . . . . ?
C18 C19 C20 C21 3.1(3) . . . . ?
C24 O4 C21 C20 -0.7(3) . . . . ?
C24 O4 C21 C22 179.65(16) . . . . ?
C19 C20 C21 O4 178.74(16) . . . . ?
C19 C20 C21 C22 -1.6(3) . . . . ?
O4 C21 C22 C23 178.49(16) . . . . ?
C20 C21 C22 C23 -1.2(3) . . . . ?
C21 C22 C23 C18 2.5(3) . . . . ?
C19 C18 C23 C22 -1.0(3) . . . . ?
C17 C18 C23 C22 -177.23(17) . . . . ?
N2 C17 C25 C30 97.3(2) . . . . ?
C18 C17 C25 C30 -85.4(2) . . . . ?
N2 C17 C25 C26 -82.5(2) . . . . ?
C18 C17 C25 C26 94.8(2) . . . . ?
C30 C25 C26 C27 -0.3(3) . . . . ?
C17 C25 C26 C27 179.56(18) . . . . ?
C25 C26 C27 C28 0.0(3) . . . . ?
C26 C27 C28 C29 0.2(3) . . . . ?
C27 C28 C29 C30 -0.1(3) . . . . ?
C26 C25 C30 C29 0.3(3) . . . . ?
C17 C25 C30 C29 -179.50(18) . . . . ?
C28 C29 C30 C25 -0.1(3) . . . . ?
O6 Si2 O5 C35 140.73(14) . . . . ?
N8 Si2 O5 C35 -127.56(14) . . . . ?
N7 Si2 O5 C35 48.73(14) . . . . ?
N5 Si2 O5 C35 -39.01(14) . . . . ?
O5 Si2 O6 C51 -161.56(15) . . . . ?
N8 Si2 O6 C51 108.13(15) . . . . ?
N7 Si2 O6 C51 -66.95(15) . . . . ?
N6 Si2 O6 C51 20.95(15) . . . . ?
O5 Si2 N5 C33 27.89(16) . . . . ?
N8 Si2 N5 C33 118.17(16) . . . . ?
N7 Si2 N5 C33 -66.68(16) . . . . ?
N6 Si2 N5 C33 -154.65(16) . . . . ?
O5 Si2 N5 C47 -153.57(13) . . . . ?
N8 Si2 N5 C47 -63.29(13) . . . . ?
N7 Si2 N5 C47 111.86(13) . . . . ?
N6 Si2 N5 C47 23.89(13) . . . . ?
O6 Si2 N6 C49 -10.71(15) . . . . ?
N8 Si2 N6 C49 -102.21(15) . . . . ?
N7 Si2 N6 C49 81.17(15) . . . . ?
N5 Si2 N6 C49 168.98(15) . . . . ?
O6 Si2 N6 C48 178.55(12) . . . . ?
N8 Si2 N6 C48 87.05(13) . . . . ?
N7 Si2 N6 C48 -89.57(13) . . . . ?
N5 Si2 N6 C48 -1.76(13) . . . . ?
O6 Si2 N7 C63 92.1(2) . . . . ?
O5 Si2 N7 C63 -178.3(2) . . . . ?
N5 Si2 N7 C63 -86.7(2) . . . . ?
N6 Si2 N7 C63 -2.1(2) . . . . ?
O6 Si2 N8 C64 -99.7(6) . . . . ?
O5 Si2 N8 C64 170.9(6) . . . . ?
N5 Si2 N8 C64 79.1(6) . . . . ?
N6 Si2 N8 C64 -5.5(6) . . . . ?
C47 N5 C33 C34 175.40(16) . . . . ?
Si2 N5 C33 C34 -6.2(2) . . . . ?
C47 N5 C33 C41 -1.4(3) . . . . ?
Si2 N5 C33 C41 176.98(13) . . . . ?
N5 C33 C34 C35 -15.6(3) . . . . ?
C41 C33 C34 C35 161.23(16) . . . . ?
N5 C33 C34 C39 169.92(17) . . . . ?
C41 C33 C34 C39 -13.2(3) . . . . ?
Si2 O5 C35 C36 -154.89(13) . . . . ?
Si2 O5 C35 C34 28.5(2) . . . . ?
C39 C34 C35 O5 -179.20(16) . . . . ?
C33 C34 C35 O5 6.1(3) . . . . ?
C39 C34 C35 C36 4.3(3) . . . . ?
C33 C34 C35 C36 -170.36(16) . . . . ?
O5 C35 C36 C37 179.25(16) . . . . ?
C34 C35 C36 C37 -4.1(3) . . . . ?
C40 O7 C37 C36 -0.4(3) . . . . ?
C40 O7 C37 C38 179.49(16) . . . . ?
C35 C36 C37 O7 -179.58(16) . . . . ?
C35 C36 C37 C38 0.6(3) . . . . ?
O7 C37 C38 C39 -177.28(16) . . . . ?
C36 C37 C38 C39 2.6(3) . . . . ?
C37 C38 C39 C34 -2.3(3) . . . . ?
C35 C34 C39 C38 -1.1(3) . . . . ?
C33 C34 C39 C38 173.50(17) . . . . ?
N5 C33 C41 C46 94.9(2) . . . . ?
C34 C33 C41 C46 -82.0(2) . . . . ?
N5 C33 C41 C42 -85.9(2) . . . . ?
C34 C33 C41 C42 97.2(2) . . . . ?
C46 C41 C42 C43 -0.2(3) . . . . ?
C33 C41 C42 C43 -179.44(18) . . . . ?
C41 C42 C43 C44 -0.3(3) . . . . ?
C42 C43 C44 C45 0.2(3) . . . . ?
C43 C44 C45 C46 0.3(3) . . . . ?
C44 C45 C46 C41 -0.7(3) . . . . ?
C42 C41 C46 C45 0.7(3) . . . . ?
C33 C41 C46 C45 179.95(16) . . . . ?
C33 N5 C47 C48 139.10(17) . . . . ?
Si2 N5 C47 C48 -39.49(18) . . . . ?
C49 N6 C48 C47 169.16(16) . . . . ?
Si2 N6 C48 C47 -19.48(19) . . . . ?
N5 C47 C48 N6 36.5(2) . . . . ?
C48 N6 C49 C50 171.30(16) . . . . ?
Si2 N6 C49 C50 1.0(2) . . . . ?
C48 N6 C49 C57 -9.1(2) . . . . ?
Si2 N6 C49 C57 -179.41(12) . . . . ?
N6 C49 C50 C51 4.1(3) . . . . ?
C57 C49 C50 C51 -175.49(15) . . . . ?
N6 C49 C50 C55 -174.65(16) . . . . ?
C57 C49 C50 C55 5.8(2) . . . . ?
Si2 O6 C51 C52 160.76(12) . . . . ?
Si2 O6 C51 C50 -21.1(2) . . . . ?
C55 C50 C51 O6 -176.29(15) . . . . ?
C49 C50 C51 O6 4.9(3) . . . . ?
C55 C50 C51 C52 1.7(2) . . . . ?
C49 C50 C51 C52 -177.08(16) . . . . ?
O6 C51 C52 C53 177.91(15) . . . . ?
C50 C51 C52 C53 -0.2(3) . . . . ?
C56 O8 C53 C52 -6.4(2) . . . . ?
C56 O8 C53 C54 174.80(15) . . . . ?
C51 C52 C53 O8 -179.84(15) . . . . ?
C51 C52 C53 C54 -1.1(3) . . . . ?
O8 C53 C54 C55 179.64(15) . . . . ?
C52 C53 C54 C55 0.8(3) . . . . ?
C53 C54 C55 C50 0.8(3) . . . . ?
C51 C50 C55 C54 -2.0(2) . . . . ?
C49 C50 C55 C54 176.78(16) . . . . ?
N6 C49 C57 C62 96.3(2) . . . . ?
C50 C49 C57 C62 -84.1(2) . . . . ?
N6 C49 C57 C58 -89.1(2) . . . . ?
C50 C49 C57 C58 90.5(2) . . . . ?
C62 C57 C58 C59 0.5(3) . . . . ?
C49 C57 C58 C59 -174.3(2) . . . . ?
C57 C58 C59 C60 -0.6(4) . . . . ?
C58 C59 C60 C61 0.2(4) . . . . ?
C59 C60 C61 C62 0.2(3) . . . . ?
C58 C57 C62 C61 -0.1(3) . . . . ?
C49 C57 C62 C61 174.53(17) . . . . ?
C60 C61 C62 C57 -0.3(3) . . . . ?
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1 PubChem 139126695
