#------------------------------------------------------------------------------
#$Date: 2025-08-20 21:19:29 +0200 (Wed 20 de Aug de 2025) $
#$Revision: 301836 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/25/4302534.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302534
loop_
_publ_author_name
'Jean-Claude G. Bünzli'
'Nail M. Shavaleev'
'Rosario Scopelliti'
'Frédéric Gumy'
_publ_contact_author_address
;Ecole polytechnique fédérale de Lausanne
Institut des sciences et ingénierie chimiques
EPFL SB ISIC LCSL
BCH 1402 (Bât. BCH)
CH-1015 Lausanne
Switzerland
;
_publ_contact_author_email       jean-claude.bunzli@epfl.ch
_publ_contact_author_fax         '+41 21 693 98 25'
_publ_contact_author_name        'Jean-Claude Bünzli'
_publ_contact_author_phone       '+41 21 693 98 21'
_publ_section_title
;
Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as
Efficient Sensitizers of Europium Luminescence
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6178
_journal_page_last               6191
_journal_paper_doi               10.1021/ic9005136
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C39 H21 Eu N6 O9, 2(C2 H6 O)'
_chemical_formula_sum            'C43 H33 Eu N6 O11'
_chemical_formula_weight         961.71
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.734(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.3155(14)
_cell_length_b                   26.6467(16)
_cell_length_c                   13.1243(9)
_cell_measurement_reflns_used    239
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      21.220
_cell_measurement_theta_min      4.601
_cell_volume                     3846.6(6)
_computing_cell_refinement       'Dirax/lsq (Duisenberg & Schreurs, 1989-2000)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction        'EvalCCD (Duisenberg & Schreurs, 1990-2000)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0420
_diffrn_reflns_av_sigmaI/netI    0.0208
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            93628
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_diffrn_reflns_theta_min         3.40
_exptl_absorpt_coefficient_mu    1.704
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8686
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2.10, G.M.Sheldrick, 2003'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.661
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1936
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.581
_refine_diff_density_min         -0.339
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.101
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     550
_refine_ls_number_reflns         8828
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.101
_refine_ls_R_factor_all          0.0288
_refine_ls_R_factor_gt           0.0222
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0138P)²+3.7352P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0440
_refine_ls_wR_factor_ref         0.0462
_reflns_number_gt                7796
_reflns_number_total             8828
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic9005136_si_001_03.cif
_cod_data_source_block           '[Eu(L)3]'
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4302534
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.087512(8) 0.145219(4) 0.358991(8) 0.01025(3) Uani 1 1 d . . .
O1 O 0.16151(13) 0.18921(5) 0.53472(11) 0.0148(3) Uani 1 1 d . . .
O2 O 0.20553(13) 0.25995(5) 0.63884(12) 0.0182(3) Uani 1 1 d . . .
O3 O -0.08423(12) 0.25183(5) 0.03606(11) 0.0151(3) Uani 1 1 d . . .
O4 O -0.11201(12) 0.16889(5) 0.32153(12) 0.0161(3) Uani 1 1 d . . .
O5 O -0.28448(13) 0.16070(6) 0.33972(13) 0.0197(3) Uani 1 1 d . . .
O6 O 0.25620(13) 0.02213(5) 0.64503(12) 0.0173(3) Uani 1 1 d . . .
O7 O -0.00253(13) 0.06988(5) 0.26239(12) 0.0162(3) Uani 1 1 d . . .
O8 O -0.02225(14) 0.00455(6) 0.14700(12) 0.0225(3) Uani 1 1 d . . .
O9 O 0.45039(13) 0.18176(5) 0.32237(12) 0.0170(3) Uani 1 1 d . . .
N1 N 0.07558(14) 0.23979(6) 0.34077(13) 0.0127(3) Uani 1 1 d . . .
N2 N -0.02791(15) 0.18200(6) 0.14583(14) 0.0133(3) Uani 1 1 d . . .
N3 N -0.00059(15) 0.09929(6) 0.47572(13) 0.0129(3) Uani 1 1 d . . .
N4 N 0.23169(15) 0.07946(6) 0.50966(14) 0.0135(3) Uani 1 1 d . . .
N5 N 0.18649(15) 0.10482(6) 0.24128(13) 0.0129(3) Uani 1 1 d . . .
N6 N 0.31232(15) 0.17984(6) 0.39197(14) 0.0131(3) Uani 1 1 d . . .
C1 C 0.16590(17) 0.23706(8) 0.54747(17) 0.0143(4) Uani 1 1 d . . .
C2 C 0.11779(17) 0.26707(8) 0.43675(17) 0.0140(4) Uani 1 1 d . . .
C3 C 0.11534(19) 0.31937(8) 0.43532(18) 0.0178(4) Uani 1 1 d . . .
H3 H 0.1445 0.3377 0.5047 0.021 Uiso 1 1 calc R . .
C4 C 0.0701(2) 0.34424(8) 0.33192(18) 0.0210(5) Uani 1 1 d . . .
H4 H 0.0700 0.3799 0.3293 0.025 Uiso 1 1 calc R . .
C5 C 0.02453(19) 0.31619(8) 0.23151(18) 0.0190(4) Uani 1 1 d . . .
H5 H -0.0078 0.3322 0.1591 0.023 Uiso 1 1 calc R . .
C6 C 0.02770(17) 0.26444(8) 0.24026(17) 0.0145(4) Uani 1 1 d . . .
C7 C -0.02551(17) 0.23085(8) 0.14198(16) 0.0135(4) Uani 1 1 d . . .
C8 C -0.12980(17) 0.21075(8) -0.03601(16) 0.0145(4) Uani 1 1 d . . .
C9 C -0.19736(18) 0.21181(8) -0.15362(17) 0.0178(4) Uani 1 1 d . . .
H9 H -0.2171 0.2422 -0.1962 0.021 Uiso 1 1 calc R . .
C10 C -0.2340(2) 0.16505(9) -0.20452(18) 0.0212(4) Uani 1 1 d . . .
H10 H -0.2805 0.1630 -0.2850 0.025 Uiso 1 1 calc R . .
C11 C -0.2039(2) 0.12084(9) -0.13997(18) 0.0218(5) Uani 1 1 d . . .
H11 H -0.2312 0.0897 -0.1782 0.026 Uiso 1 1 calc R . .
C12 C -0.13570(19) 0.12089(8) -0.02218(17) 0.0185(4) Uani 1 1 d . . .
H12 H -0.1161 0.0906 0.0207 0.022 Uiso 1 1 calc R . .
C13 C -0.09722(17) 0.16759(8) 0.03043(16) 0.0141(4) Uani 1 1 d . . .
C14 C -0.17733(17) 0.15006(8) 0.36472(16) 0.0142(4) Uani 1 1 d . . .
C15 C -0.11476(18) 0.11037(7) 0.45568(16) 0.0139(4) Uani 1 1 d . . .
C16 C -0.17016(19) 0.08733(8) 0.51580(18) 0.0186(4) Uani 1 1 d . . .
H16 H -0.2513 0.0955 0.5000 0.022 Uiso 1 1 calc R . .
C17 C -0.1048(2) 0.05227(8) 0.59893(19) 0.0227(5) Uani 1 1 d . . .
H17 H -0.1405 0.0365 0.6415 0.027 Uiso 1 1 calc R . .
C18 C 0.01339(19) 0.04022(8) 0.61967(18) 0.0190(4) Uani 1 1 d . . .
H18 H 0.0598 0.0162 0.6760 0.023 Uiso 1 1 calc R . .
C19 C 0.06113(18) 0.06465(8) 0.55493(16) 0.0146(4) Uani 1 1 d . . .
C20 C 0.18413(18) 0.05605(7) 0.56748(16) 0.0145(4) Uani 1 1 d . . .
C21 C 0.36529(18) 0.02526(8) 0.63837(17) 0.0167(4) Uani 1 1 d . . .
C22 C 0.47117(19) -0.00106(8) 0.70257(18) 0.0209(4) Uani 1 1 d . . .
H22 H 0.4773 -0.0254 0.7578 0.025 Uiso 1 1 calc R . .
C23 C 0.5679(2) 0.01107(9) 0.67964(19) 0.0237(5) Uani 1 1 d . . .
H23 H 0.6434 -0.0056 0.7207 0.028 Uiso 1 1 calc R . .
C24 C 0.5576(2) 0.04711(9) 0.59801(19) 0.0231(5) Uani 1 1 d . . .
H24 H 0.6265 0.0543 0.5860 0.028 Uiso 1 1 calc R . .
C25 C 0.44996(19) 0.07250(8) 0.53429(18) 0.0199(4) Uani 1 1 d . . .
H25 H 0.4434 0.0968 0.4788 0.024 Uiso 1 1 calc R . .
C26 C 0.35127(18) 0.06065(8) 0.55549(16) 0.0147(4) Uani 1 1 d . . .
C27 C 0.02521(18) 0.04419(8) 0.19492(16) 0.0151(4) Uani 1 1 d . . .
C28 C 0.12801(18) 0.06587(8) 0.17418(16) 0.0146(4) Uani 1 1 d . . .
C29 C 0.15944(19) 0.04688(8) 0.09155(17) 0.0181(4) Uani 1 1 d . . .
H29 H 0.1155 0.0197 0.0440 0.022 Uiso 1 1 calc R . .
C30 C 0.25627(19) 0.06861(8) 0.08052(17) 0.0200(4) Uani 1 1 d . . .
H30 H 0.2784 0.0567 0.0242 0.024 Uiso 1 1 calc R . .
C31 C 0.32051(18) 0.10779(8) 0.15226(17) 0.0171(4) Uani 1 1 d . . .
H31 H 0.3884 0.1225 0.1477 0.020 Uiso 1 1 calc R . .
C32 C 0.28194(17) 0.12475(8) 0.23119(16) 0.0138(4) Uani 1 1 d . . .
C33 C 0.34394(17) 0.16404(7) 0.31493(16) 0.0130(4) Uani 1 1 d . . .
C34 C 0.49340(18) 0.21279(8) 0.41758(17) 0.0160(4) Uani 1 1 d . . .
C35 C 0.60247(19) 0.23860(9) 0.46479(19) 0.0219(5) Uani 1 1 d . . .
H35 H 0.6581 0.2376 0.4329 0.026 Uiso 1 1 calc R . .
C36 C 0.62486(19) 0.26604(8) 0.56235(18) 0.0209(4) Uani 1 1 d . . .
H36 H 0.6974 0.2852 0.5980 0.025 Uiso 1 1 calc R . .
C37 C 0.54240(19) 0.26603(8) 0.60925(18) 0.0188(4) Uani 1 1 d . . .
H37 H 0.5611 0.2851 0.6762 0.023 Uiso 1 1 calc R . .
C38 C 0.43429(18) 0.23901(8) 0.56111(17) 0.0173(4) Uani 1 1 d . . .
H38 H 0.3800 0.2389 0.5945 0.021 Uiso 1 1 calc R . .
C39 C 0.40893(17) 0.21199(7) 0.46112(17) 0.0143(4) Uani 1 1 d . . .
C40 C 0.4796(2) 0.14357(11) 0.8153(2) 0.0392(6) Uani 1 1 d . . .
H40A H 0.4899 0.1092 0.7946 0.059 Uiso 1 1 calc R . .
H40B H 0.5513 0.1534 0.8851 0.059 Uiso 1 1 calc R . .
H40C H 0.4699 0.1664 0.7533 0.059 Uiso 1 1 calc R . .
C41 C 0.3684(2) 0.14623(11) 0.8350(2) 0.0346(6) Uani 1 1 d . . .
H41A H 0.3818 0.1255 0.9023 0.042 Uiso 1 1 calc R . .
H41B H 0.3559 0.1814 0.8519 0.042 Uiso 1 1 calc R . .
O10 O 0.26188(15) 0.12899(6) 0.73876(13) 0.0272(4) Uani 1 1 d . . .
H10A H 0.2406 0.1503 0.6861 0.041 Uiso 1 1 calc R . .
C42 C -0.3517(3) 0.03847(12) 0.0522(3) 0.0524(9) Uani 1 1 d . . .
H42A H -0.3725 0.0093 0.0855 0.079 Uiso 1 1 calc R . .
H42B H -0.2827 0.0301 0.0372 0.079 Uiso 1 1 calc R . .
H42C H -0.4218 0.0477 -0.0195 0.079 Uiso 1 1 calc R . .
C43 C -0.3184(3) 0.08141(11) 0.1331(3) 0.0427(7) Uani 1 1 d . . .
H43A H -0.2484 0.0720 0.2061 0.051 Uiso 1 1 calc R . .
H43B H -0.2941 0.1105 0.1010 0.051 Uiso 1 1 calc R . .
O11 O -0.41911(15) 0.09497(7) 0.15338(15) 0.0320(4) Uani 1 1 d . . .
H11A H -0.3967 0.1164 0.2059 0.048 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Eu1 O7 85.54(5) . . ?
O4 Eu1 O1 88.81(5) . . ?
O7 Eu1 O1 145.28(5) . . ?
O4 Eu1 N1 72.77(5) . . ?
O7 Eu1 N1 143.24(5) . . ?
O1 Eu1 N1 65.19(5) . . ?
O4 Eu1 N3 64.55(5) . . ?
O7 Eu1 N3 72.04(5) . . ?
O1 Eu1 N3 74.61(5) . . ?
N1 Eu1 N3 120.80(5) . . ?
O4 Eu1 N5 135.22(5) . . ?
O7 Eu1 N5 63.98(5) . . ?
O1 Eu1 N5 134.91(5) . . ?
N1 Eu1 N5 112.34(5) . . ?
N3 Eu1 N5 126.80(5) . . ?
O4 Eu1 N4 128.21(5) . . ?
O7 Eu1 N4 80.41(5) . . ?
O1 Eu1 N4 76.42(5) . . ?
N1 Eu1 N4 136.28(5) . . ?
N3 Eu1 N4 63.69(5) . . ?
N5 Eu1 N4 80.37(5) . . ?
O4 Eu1 N2 70.91(5) . . ?
O7 Eu1 N2 81.42(5) . . ?
O1 Eu1 N2 128.55(5) . . ?
N1 Eu1 N2 63.73(5) . . ?
N3 Eu1 N2 129.10(5) . . ?
N5 Eu1 N2 72.64(5) . . ?
N4 Eu1 N2 152.08(5) . . ?
O4 Eu1 N6 144.92(5) . . ?
O7 Eu1 N6 124.22(5) . . ?
O1 Eu1 N6 76.29(5) . . ?
N1 Eu1 N6 72.15(5) . . ?
N3 Eu1 N6 137.13(5) . . ?
N5 Eu1 N6 61.66(5) . . ?
N4 Eu1 N6 79.36(5) . . ?
N2 Eu1 N6 93.71(5) . . ?
C1 O1 Eu1 126.33(12) . . ?
C7 O3 C8 103.72(15) . . ?
C14 O4 Eu1 127.32(13) . . ?
C20 O6 C21 103.82(15) . . ?
C27 O7 Eu1 128.10(13) . . ?
C33 O9 C34 103.73(15) . . ?
C2 N1 C6 117.98(17) . . ?
C2 N1 Eu1 118.03(13) . . ?
C6 N1 Eu1 123.97(13) . . ?
C7 N2 C13 104.04(16) . . ?
C7 N2 Eu1 113.19(12) . . ?
C13 N2 Eu1 142.73(13) . . ?
C19 N3 C15 118.80(17) . . ?
C19 N3 Eu1 123.31(13) . . ?
C15 N3 Eu1 117.88(12) . . ?
C20 N4 C26 103.76(16) . . ?
C20 N4 Eu1 115.18(13) . . ?
C26 N4 Eu1 141.01(12) . . ?
C28 N5 C32 118.29(17) . . ?
C28 N5 Eu1 117.04(12) . . ?
C32 N5 Eu1 123.96(13) . . ?
C33 N6 C39 103.54(16) . . ?
C33 N6 Eu1 113.46(13) . . ?
C39 N6 Eu1 142.88(12) . . ?
O2 C1 O1 126.35(19) . . ?
O2 C1 C2 118.76(18) . . ?
O1 C1 C2 114.89(17) . . ?
N1 C2 C3 122.18(19) . . ?
N1 C2 C1 115.55(17) . . ?
C3 C2 C1 122.25(18) . . ?
C4 C3 C2 119.30(19) . . ?
C4 C3 H3 120.4 . . ?
C2 C3 H3 120.4 . . ?
C3 C4 C5 118.94(19) . . ?
C3 C4 H4 120.5 . . ?
C5 C4 H4 120.5 . . ?
C6 C5 C4 118.14(19) . . ?
C6 C5 H5 120.9 . . ?
C4 C5 H5 120.9 . . ?
N1 C6 C5 123.39(19) . . ?
N1 C6 C7 112.97(17) . . ?
C5 C6 C7 123.58(18) . . ?
N2 C7 O3 115.95(17) . . ?
N2 C7 C6 125.92(18) . . ?
O3 C7 C6 118.03(17) . . ?
C9 C8 C13 125.13(19) . . ?
C9 C8 O3 126.75(18) . . ?
C13 C8 O3 108.12(16) . . ?
C8 C9 C10 114.80(19) . . ?
C8 C9 H9 122.6 . . ?
C10 C9 H9 122.6 . . ?
C9 C10 C11 121.56(19) . . ?
C9 C10 H10 119.2 . . ?
C11 C10 H10 119.2 . . ?
C12 C11 C10 122.4(2) . . ?
C12 C11 H11 118.8 . . ?
C10 C11 H11 118.8 . . ?
C11 C12 C13 116.85(19) . . ?
C11 C12 H12 121.6 . . ?
C13 C12 H12 121.6 . . ?
C8 C13 C12 119.26(18) . . ?
C8 C13 N2 108.16(17) . . ?
C12 C13 N2 132.57(18) . . ?
O5 C14 O4 126.89(19) . . ?
O5 C14 C15 118.02(17) . . ?
O4 C14 C15 115.09(17) . . ?
N3 C15 C16 121.86(18) . . ?
N3 C15 C14 115.05(16) . . ?
C16 C15 C14 123.09(18) . . ?
C17 C16 C15 118.89(19) . . ?
C17 C16 H16 120.6 . . ?
C15 C16 H16 120.6 . . ?
C16 C17 C18 119.65(19) . . ?
C16 C17 H17 120.2 . . ?
C18 C17 H17 120.2 . . ?
C17 C18 C19 117.63(19) . . ?
C17 C18 H18 121.2 . . ?
C19 C18 H18 121.2 . . ?
N3 C19 C18 123.14(18) . . ?
N3 C19 C20 113.04(17) . . ?
C18 C19 C20 123.81(18) . . ?
N4 C20 O6 116.24(17) . . ?
N4 C20 C19 124.78(18) . . ?
O6 C20 C19 118.97(17) . . ?
C22 C21 O6 127.25(19) . . ?
C22 C21 C26 124.87(19) . . ?
O6 C21 C26 107.88(17) . . ?
C21 C22 C23 114.5(2) . . ?
C21 C22 H22 122.8 . . ?
C23 C22 H22 122.8 . . ?
C22 C23 C24 122.2(2) . . ?
C22 C23 H23 118.9 . . ?
C24 C23 H23 118.9 . . ?
C25 C24 C23 122.0(2) . . ?
C25 C24 H24 119.0 . . ?
C23 C24 H24 119.0 . . ?
C24 C25 C26 116.8(2) . . ?
C24 C25 H25 121.6 . . ?
C26 C25 H25 121.6 . . ?
C21 C26 C25 119.68(18) . . ?
C21 C26 N4 108.26(17) . . ?
C25 C26 N4 132.02(18) . . ?
O8 C27 O7 126.68(19) . . ?
O8 C27 C28 118.34(18) . . ?
O7 C27 C28 114.98(17) . . ?
N5 C28 C29 122.29(19) . . ?
N5 C28 C27 114.83(17) . . ?
C29 C28 C27 122.89(18) . . ?
C30 C29 C28 118.62(19) . . ?
C30 C29 H29 120.7 . . ?
C28 C29 H29 120.7 . . ?
C31 C30 C29 119.71(19) . . ?
C31 C30 H30 120.1 . . ?
C29 C30 H30 120.1 . . ?
C30 C31 C32 117.79(19) . . ?
C30 C31 H31 121.1 . . ?
C32 C31 H31 121.1 . . ?
N5 C32 C31 123.22(19) . . ?
N5 C32 C33 113.07(16) . . ?
C31 C32 C33 123.64(18) . . ?
N6 C33 O9 116.59(17) . . ?
N6 C33 C32 125.23(18) . . ?
O9 C33 C32 117.75(16) . . ?
C35 C34 O9 126.82(18) . . ?
C35 C34 C39 125.27(19) . . ?
O9 C34 C39 107.86(17) . . ?
C34 C35 C36 115.11(19) . . ?
C34 C35 H35 122.4 . . ?
C36 C35 H35 122.4 . . ?
C35 C36 C37 121.4(2) . . ?
C35 C36 H36 119.3 . . ?
C37 C36 H36 119.3 . . ?
C38 C37 C36 122.30(19) . . ?
C38 C37 H37 118.9 . . ?
C36 C37 H37 118.9 . . ?
C37 C38 C39 117.09(19) . . ?
C37 C38 H38 121.5 . . ?
C39 C38 H38 121.5 . . ?
C34 C39 C38 118.83(18) . . ?
C34 C39 N6 108.27(17) . . ?
C38 C39 N6 132.82(18) . . ?
C41 C40 H40A 109.5 . . ?
C41 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C41 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
O10 C41 C40 112.2(2) . . ?
O10 C41 H41A 109.2 . . ?
C40 C41 H41A 109.2 . . ?
O10 C41 H41B 109.2 . . ?
C40 C41 H41B 109.2 . . ?
H41A C41 H41B 107.9 . . ?
C41 O10 H10A 109.5 . . ?
C43 C42 H42A 109.5 . . ?
C43 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C43 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
O11 C43 C42 110.2(2) . . ?
O11 C43 H43A 109.6 . . ?
C42 C43 H43A 109.6 . . ?
O11 C43 H43B 109.6 . . ?
C42 C43 H43B 109.6 . . ?
H43A C43 H43B 108.1 . . ?
C43 O11 H11A 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O4 2.3644(14) . ?
Eu1 O7 2.3669(14) . ?
Eu1 O1 2.3733(13) . ?
Eu1 N1 2.5293(17) . ?
Eu1 N3 2.5530(16) . ?
Eu1 N5 2.5934(16) . ?
Eu1 N4 2.6410(16) . ?
Eu1 N2 2.6888(16) . ?
Eu1 N6 2.7614(16) . ?
O1 C1 1.284(2) . ?
O2 C1 1.234(2) . ?
O3 C7 1.365(2) . ?
O3 C8 1.389(2) . ?
O4 C14 1.277(2) . ?
O5 C14 1.241(2) . ?
O6 C20 1.352(2) . ?
O6 C21 1.388(2) . ?
O7 C27 1.281(2) . ?
O8 C27 1.234(2) . ?
O9 C33 1.355(2) . ?
O9 C34 1.389(2) . ?
N1 C2 1.340(2) . ?
N1 C6 1.349(2) . ?
N2 C7 1.303(3) . ?
N2 C13 1.417(2) . ?
N3 C19 1.341(3) . ?
N3 C15 1.342(2) . ?
N4 C20 1.307(2) . ?
N4 C26 1.409(2) . ?
N5 C28 1.342(3) . ?
N5 C32 1.350(2) . ?
N6 C33 1.306(2) . ?
N6 C39 1.415(2) . ?
C1 C2 1.525(3) . ?
C2 C3 1.394(3) . ?
C3 C4 1.382(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.395(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.383(3) . ?
C5 H5 0.9500 . ?
C6 C7 1.461(3) . ?
C8 C9 1.386(3) . ?
C8 C13 1.389(3) . ?
C9 C10 1.390(3) . ?
C9 H9 0.9500 . ?
C10 C11 1.400(3) . ?
C10 H10 0.9500 . ?
C11 C12 1.388(3) . ?
C11 H11 0.9500 . ?
C12 C13 1.398(3) . ?
C12 H12 0.9500 . ?
C14 C15 1.520(3) . ?
C15 C16 1.396(3) . ?
C16 C17 1.386(3) . ?
C16 H16 0.9500 . ?
C17 C18 1.393(3) . ?
C17 H17 0.9500 . ?
C18 C19 1.393(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.466(3) . ?
C21 C22 1.383(3) . ?
C21 C26 1.390(3) . ?
C22 C23 1.391(3) . ?
C22 H22 0.9500 . ?
C23 C24 1.401(3) . ?
C23 H23 0.9500 . ?
C24 C25 1.384(3) . ?
C24 H24 0.9500 . ?
C25 C26 1.400(3) . ?
C25 H25 0.9500 . ?
C27 C28 1.523(3) . ?
C28 C29 1.400(3) . ?
C29 C30 1.391(3) . ?
C29 H29 0.9500 . ?
C30 C31 1.390(3) . ?
C30 H30 0.9500 . ?
C31 C32 1.395(3) . ?
C31 H31 0.9500 . ?
C32 C33 1.460(3) . ?
C34 C35 1.383(3) . ?
C34 C39 1.394(3) . ?
C35 C36 1.390(3) . ?
C35 H35 0.9500 . ?
C36 C37 1.405(3) . ?
C36 H36 0.9500 . ?
C37 C38 1.390(3) . ?
C37 H37 0.9500 . ?
C38 C39 1.403(3) . ?
C38 H38 0.9500 . ?
C40 C41 1.505(4) . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 O10 1.427(3) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
O10 H10A 0.8400 . ?
C42 C43 1.488(4) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 O11 1.426(3) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
O11 H11A 0.8400 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O10 H10A O1 0.84 2.06 2.880(2) 167.0 .
O11 H11A O5 0.84 2.05 2.855(2) 160.0 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O4 Eu1 O1 C1 -72.17(15) . . . . ?
O7 Eu1 O1 C1 -152.58(14) . . . . ?
N1 Eu1 O1 C1 -0.64(14) . . . . ?
N3 Eu1 O1 C1 -136.06(16) . . . . ?
N5 Eu1 O1 C1 96.86(16) . . . . ?
N4 Eu1 O1 C1 157.93(16) . . . . ?
N2 Eu1 O1 C1 -7.96(17) . . . . ?
N6 Eu1 O1 C1 75.78(15) . . . . ?
O7 Eu1 O4 C14 68.91(16) . . . . ?
O1 Eu1 O4 C14 -76.80(16) . . . . ?
N1 Eu1 O4 C14 -141.15(16) . . . . ?
N3 Eu1 O4 C14 -3.30(15) . . . . ?
N5 Eu1 O4 C14 114.22(16) . . . . ?
N4 Eu1 O4 C14 -5.18(18) . . . . ?
N2 Eu1 O4 C14 151.37(17) . . . . ?
N6 Eu1 O4 C14 -140.57(15) . . . . ?
O4 Eu1 O7 C27 142.45(16) . . . . ?
O1 Eu1 O7 C27 -136.14(15) . . . . ?
N1 Eu1 O7 C27 89.37(17) . . . . ?
N3 Eu1 O7 C27 -152.88(17) . . . . ?
N5 Eu1 O7 C27 -3.69(15) . . . . ?
N4 Eu1 O7 C27 -87.58(16) . . . . ?
N2 Eu1 O7 C27 71.12(16) . . . . ?
N6 Eu1 O7 C27 -17.54(18) . . . . ?
O4 Eu1 N1 C2 98.00(14) . . . . ?
O7 Eu1 N1 C2 154.56(12) . . . . ?
O1 Eu1 N1 C2 1.15(12) . . . . ?
N3 Eu1 N1 C2 53.13(15) . . . . ?
N5 Eu1 N1 C2 -129.46(13) . . . . ?
N4 Eu1 N1 C2 -29.79(16) . . . . ?
N2 Eu1 N1 C2 174.77(15) . . . . ?
N6 Eu1 N1 C2 -81.65(13) . . . . ?
O4 Eu1 N1 C6 -80.99(14) . . . . ?
O7 Eu1 N1 C6 -24.43(18) . . . . ?
O1 Eu1 N1 C6 -177.84(16) . . . . ?
N3 Eu1 N1 C6 -125.86(14) . . . . ?
N5 Eu1 N1 C6 51.55(15) . . . . ?
N4 Eu1 N1 C6 151.23(13) . . . . ?
N2 Eu1 N1 C6 -4.22(13) . . . . ?
N6 Eu1 N1 C6 99.36(15) . . . . ?
O4 Eu1 N2 C7 82.98(13) . . . . ?
O7 Eu1 N2 C7 171.21(14) . . . . ?
O1 Eu1 N2 C7 10.69(15) . . . . ?
N1 Eu1 N2 C7 3.27(12) . . . . ?
N3 Eu1 N2 C7 112.83(13) . . . . ?
N5 Eu1 N2 C7 -123.48(14) . . . . ?
N4 Eu1 N2 C7 -138.90(13) . . . . ?
N6 Eu1 N2 C7 -64.72(13) . . . . ?
O4 Eu1 N2 C13 -94.0(2) . . . . ?
O7 Eu1 N2 C13 -5.82(19) . . . . ?
O1 Eu1 N2 C13 -166.34(18) . . . . ?
N1 Eu1 N2 C13 -173.7(2) . . . . ?
N3 Eu1 N2 C13 -64.2(2) . . . . ?
N5 Eu1 N2 C13 59.50(19) . . . . ?
N4 Eu1 N2 C13 44.1(2) . . . . ?
N6 Eu1 N2 C13 118.3(2) . . . . ?
O4 Eu1 N3 C19 -178.76(16) . . . . ?
O7 Eu1 N3 C19 87.59(15) . . . . ?
O1 Eu1 N3 C19 -82.61(15) . . . . ?
N1 Eu1 N3 C19 -130.49(14) . . . . ?
N5 Eu1 N3 C19 52.51(17) . . . . ?
N4 Eu1 N3 C19 -0.41(14) . . . . ?
N2 Eu1 N3 C19 149.85(14) . . . . ?
N6 Eu1 N3 C19 -33.74(18) . . . . ?
O4 Eu1 N3 C15 1.70(13) . . . . ?
O7 Eu1 N3 C15 -91.96(14) . . . . ?
O1 Eu1 N3 C15 97.84(14) . . . . ?
N1 Eu1 N3 C15 49.97(15) . . . . ?
N5 Eu1 N3 C15 -127.04(13) . . . . ?
N4 Eu1 N3 C15 -179.95(15) . . . . ?
N2 Eu1 N3 C15 -29.69(16) . . . . ?
N6 Eu1 N3 C15 146.72(13) . . . . ?
O4 Eu1 N4 C20 2.60(16) . . . . ?
O7 Eu1 N4 C20 -73.91(14) . . . . ?
O1 Eu1 N4 C20 80.04(14) . . . . ?
N1 Eu1 N4 C20 108.72(14) . . . . ?
N3 Eu1 N4 C20 0.70(13) . . . . ?
N5 Eu1 N4 C20 -138.91(14) . . . . ?
N2 Eu1 N4 C20 -123.99(14) . . . . ?
N6 Eu1 N4 C20 158.35(14) . . . . ?
O4 Eu1 N4 C26 -174.26(18) . . . . ?
O7 Eu1 N4 C26 109.2(2) . . . . ?
O1 Eu1 N4 C26 -96.8(2) . . . . ?
N1 Eu1 N4 C26 -68.1(2) . . . . ?
N3 Eu1 N4 C26 -176.2(2) . . . . ?
N5 Eu1 N4 C26 44.2(2) . . . . ?
N2 Eu1 N4 C26 59.1(2) . . . . ?
N6 Eu1 N4 C26 -18.51(19) . . . . ?
O4 Eu1 N5 C28 -43.69(16) . . . . ?
O7 Eu1 N5 C28 8.38(13) . . . . ?
O1 Eu1 N5 C28 151.98(12) . . . . ?
N1 Eu1 N5 C28 -131.37(13) . . . . ?
N3 Eu1 N5 C28 45.85(15) . . . . ?
N4 Eu1 N5 C28 92.34(14) . . . . ?
N2 Eu1 N5 C28 -80.40(14) . . . . ?
N6 Eu1 N5 C28 175.38(15) . . . . ?
O4 Eu1 N5 C32 126.52(14) . . . . ?
O7 Eu1 N5 C32 178.58(16) . . . . ?
O1 Eu1 N5 C32 -37.82(17) . . . . ?
N1 Eu1 N5 C32 38.83(16) . . . . ?
N3 Eu1 N5 C32 -143.95(14) . . . . ?
N4 Eu1 N5 C32 -97.46(15) . . . . ?
N2 Eu1 N5 C32 89.80(15) . . . . ?
N6 Eu1 N5 C32 -14.42(13) . . . . ?
O4 Eu1 N6 C33 -117.47(14) . . . . ?
O7 Eu1 N6 C33 26.12(15) . . . . ?
O1 Eu1 N6 C33 175.14(14) . . . . ?
N1 Eu1 N6 C33 -116.89(14) . . . . ?
N3 Eu1 N6 C33 126.76(13) . . . . ?
N5 Eu1 N6 C33 11.97(13) . . . . ?
N4 Eu1 N6 C33 96.69(14) . . . . ?
N2 Eu1 N6 C33 -56.03(14) . . . . ?
O4 Eu1 N6 C39 57.7(2) . . . . ?
O7 Eu1 N6 C39 -158.68(19) . . . . ?
O1 Eu1 N6 C39 -9.7(2) . . . . ?
N1 Eu1 N6 C39 58.3(2) . . . . ?
N3 Eu1 N6 C39 -58.0(2) . . . . ?
N5 Eu1 N6 C39 -172.8(2) . . . . ?
N4 Eu1 N6 C39 -88.1(2) . . . . ?
N2 Eu1 N6 C39 119.2(2) . . . . ?
Eu1 O1 C1 O2 -179.18(14) . . . . ?
Eu1 O1 C1 C2 0.1(2) . . . . ?
C6 N1 C2 C3 -1.1(3) . . . . ?
Eu1 N1 C2 C3 179.85(15) . . . . ?
C6 N1 C2 C1 177.52(16) . . . . ?
Eu1 N1 C2 C1 -1.5(2) . . . . ?
O2 C1 C2 N1 -179.66(17) . . . . ?
O1 C1 C2 N1 1.0(2) . . . . ?
O2 C1 C2 C3 -1.0(3) . . . . ?
O1 C1 C2 C3 179.61(18) . . . . ?
N1 C2 C3 C4 -1.2(3) . . . . ?
C1 C2 C3 C4 -179.73(18) . . . . ?
C2 C3 C4 C5 2.0(3) . . . . ?
C3 C4 C5 C6 -0.5(3) . . . . ?
C2 N1 C6 C5 2.7(3) . . . . ?
Eu1 N1 C6 C5 -178.30(15) . . . . ?
C2 N1 C6 C7 -174.54(16) . . . . ?
Eu1 N1 C6 C7 4.4(2) . . . . ?
C4 C5 C6 N1 -1.9(3) . . . . ?
C4 C5 C6 C7 175.04(18) . . . . ?
C13 N2 C7 O3 -0.9(2) . . . . ?
Eu1 N2 C7 O3 -179.08(11) . . . . ?
C13 N2 C7 C6 175.35(18) . . . . ?
Eu1 N2 C7 C6 -2.8(2) . . . . ?
C8 O3 C7 N2 0.2(2) . . . . ?
C8 O3 C7 C6 -176.37(16) . . . . ?
N1 C6 C7 N2 -0.7(3) . . . . ?
C5 C6 C7 N2 -178.0(2) . . . . ?
N1 C6 C7 O3 175.49(16) . . . . ?
C5 C6 C7 O3 -1.8(3) . . . . ?
C7 O3 C8 C9 179.94(19) . . . . ?
C7 O3 C8 C13 0.63(19) . . . . ?
C13 C8 C9 C10 0.7(3) . . . . ?
O3 C8 C9 C10 -178.54(18) . . . . ?
C8 C9 C10 C11 0.1(3) . . . . ?
C9 C10 C11 C12 -0.4(3) . . . . ?
C10 C11 C12 C13 -0.2(3) . . . . ?
C9 C8 C13 C12 -1.2(3) . . . . ?
O3 C8 C13 C12 178.12(17) . . . . ?
C9 C8 C13 N2 179.48(18) . . . . ?
O3 C8 C13 N2 -1.2(2) . . . . ?
C11 C12 C13 C8 0.9(3) . . . . ?
C11 C12 C13 N2 -180.0(2) . . . . ?
C7 N2 C13 C8 1.3(2) . . . . ?
Eu1 N2 C13 C8 178.46(14) . . . . ?
C7 N2 C13 C12 -177.9(2) . . . . ?
Eu1 N2 C13 C12 -0.7(4) . . . . ?
Eu1 O4 C14 O5 -175.48(15) . . . . ?
Eu1 O4 C14 C15 4.2(2) . . . . ?
C19 N3 C15 C16 0.8(3) . . . . ?
Eu1 N3 C15 C16 -179.66(15) . . . . ?
C19 N3 C15 C14 179.91(17) . . . . ?
Eu1 N3 C15 C14 -0.5(2) . . . . ?
O5 C14 C15 N3 177.65(18) . . . . ?
O4 C14 C15 N3 -2.1(3) . . . . ?
O5 C14 C15 C16 -3.2(3) . . . . ?
O4 C14 C15 C16 177.06(19) . . . . ?
N3 C15 C16 C17 0.4(3) . . . . ?
C14 C15 C16 C17 -178.66(19) . . . . ?
C15 C16 C17 C18 -0.9(3) . . . . ?
C16 C17 C18 C19 0.3(3) . . . . ?
C15 N3 C19 C18 -1.5(3) . . . . ?
Eu1 N3 C19 C18 179.00(15) . . . . ?
C15 N3 C19 C20 179.63(17) . . . . ?
Eu1 N3 C19 C20 0.1(2) . . . . ?
C17 C18 C19 N3 0.9(3) . . . . ?
C17 C18 C19 C20 179.7(2) . . . . ?
C26 N4 C20 O6 -2.1(2) . . . . ?
Eu1 N4 C20 O6 179.90(12) . . . . ?
C26 N4 C20 C19 176.92(19) . . . . ?
Eu1 N4 C20 C19 -1.1(2) . . . . ?
C21 O6 C20 N4 1.9(2) . . . . ?
C21 O6 C20 C19 -177.19(17) . . . . ?
N3 C19 C20 N4 0.7(3) . . . . ?
C18 C19 C20 N4 -178.2(2) . . . . ?
N3 C19 C20 O6 179.71(17) . . . . ?
C18 C19 C20 O6 0.8(3) . . . . ?
C20 O6 C21 C22 178.4(2) . . . . ?
C20 O6 C21 C26 -0.8(2) . . . . ?
O6 C21 C22 C23 -178.0(2) . . . . ?
C26 C21 C22 C23 1.0(3) . . . . ?
C21 C22 C23 C24 0.1(3) . . . . ?
C22 C23 C24 C25 -0.7(4) . . . . ?
C23 C24 C25 C26 0.3(3) . . . . ?
C22 C21 C26 C25 -1.5(3) . . . . ?
O6 C21 C26 C25 177.71(18) . . . . ?
C22 C21 C26 N4 -179.6(2) . . . . ?
O6 C21 C26 N4 -0.4(2) . . . . ?
C24 C25 C26 C21 0.7(3) . . . . ?
C24 C25 C26 N4 178.3(2) . . . . ?
C20 N4 C26 C21 1.4(2) . . . . ?
Eu1 N4 C26 C21 178.52(15) . . . . ?
C20 N4 C26 C25 -176.3(2) . . . . ?
Eu1 N4 C26 C25 0.7(4) . . . . ?
Eu1 O7 C27 O8 178.83(15) . . . . ?
Eu1 O7 C27 C28 -0.9(2) . . . . ?
C32 N5 C28 C29 -2.8(3) . . . . ?
Eu1 N5 C28 C29 168.02(15) . . . . ?
C32 N5 C28 C27 177.33(16) . . . . ?
Eu1 N5 C28 C27 -11.9(2) . . . . ?
O8 C27 C28 N5 -170.88(18) . . . . ?
O7 C27 C28 N5 8.9(2) . . . . ?
O8 C27 C28 C29 9.2(3) . . . . ?
O7 C27 C28 C29 -171.03(18) . . . . ?
N5 C28 C29 C30 1.3(3) . . . . ?
C27 C28 C29 C30 -178.78(18) . . . . ?
C28 C29 C30 C31 1.1(3) . . . . ?
C29 C30 C31 C32 -1.9(3) . . . . ?
C28 N5 C32 C31 1.9(3) . . . . ?
Eu1 N5 C32 C31 -168.19(14) . . . . ?
C28 N5 C32 C33 -175.25(17) . . . . ?
Eu1 N5 C32 C33 14.7(2) . . . . ?
C30 C31 C32 N5 0.4(3) . . . . ?
C30 C31 C32 C33 177.24(19) . . . . ?
C39 N6 C33 O9 -0.4(2) . . . . ?
Eu1 N6 C33 O9 176.57(12) . . . . ?
C39 N6 C33 C32 171.79(18) . . . . ?
Eu1 N6 C33 C32 -11.2(2) . . . . ?
C34 O9 C33 N6 0.6(2) . . . . ?
C34 O9 C33 C32 -172.28(17) . . . . ?
N5 C32 C33 N6 -0.9(3) . . . . ?
C31 C32 C33 N6 -178.02(19) . . . . ?
N5 C32 C33 O9 171.26(16) . . . . ?
C31 C32 C33 O9 -5.9(3) . . . . ?
C33 O9 C34 C35 177.2(2) . . . . ?
C33 O9 C34 C39 -0.4(2) . . . . ?
O9 C34 C35 C36 -178.3(2) . . . . ?
C39 C34 C35 C36 -1.1(3) . . . . ?
C34 C35 C36 C37 1.3(3) . . . . ?
C35 C36 C37 C38 -0.3(3) . . . . ?
C36 C37 C38 C39 -1.1(3) . . . . ?
C35 C34 C39 C38 -0.3(3) . . . . ?
O9 C34 C39 C38 177.38(17) . . . . ?
C35 C34 C39 N6 -177.5(2) . . . . ?
O9 C34 C39 N6 0.2(2) . . . . ?
C37 C38 C39 C34 1.4(3) . . . . ?
C37 C38 C39 N6 177.8(2) . . . . ?
C33 N6 C39 C34 0.1(2) . . . . ?
Eu1 N6 C39 C34 -175.32(15) . . . . ?
C33 N6 C39 C38 -176.5(2) . . . . ?
Eu1 N6 C39 C38 8.0(4) . . . . ?
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 139126796
