Information card for entry 4302863

Structure parameters

• Chemical name: 1-chloro-2,4-bis[2,4-bis-(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa -2,4-diazenium bis[hexachloridogallate(III)]
• Formula: C48 H50 As2 Cl7 Ga2 N5
• Calculated formula: C48 H50 As2 Cl7 Ga2 N5
• SMILES: N1([As]=[N]([As]1Cl)c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C.[Ga]([N]([Ga](Cl)(Cl)Cl)=N#N)(Cl)(Cl)Cl
• Title of publication: Cyclic Arsenic-Nitrogen Cations
• Authors of publication: Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 7359 - 7367
• a: 16.129 ± 0.003 Å
• b: 15.157 ± 0.003 Å
• c: 22.317 ± 0.005 Å
• α: 90°
• β: 104.36 ± 0.03°
• γ: 90°
• Cell volume: 5285 ± 2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0605
• Residual factor for significantly intense reflections: 0.0319
• Weighted residual factors for significantly intense reflections: 0.0655
• Weighted residual factors for all reflections included in the refinement: 0.073
• Goodness-of-fit parameter for all reflections included in the refinement: 1.01
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No