Information card for entry 4302900

Structure parameters

• Chemical name: tris(μ~2~-Hydrido)-trihydrido-tetrakis(diisopropylphenylphosphine)-di-osmium
• Formula: C48 H82 Os2 P4
• Calculated formula: C48 H82 Os2 P4
• SMILES: [OsH]123([OsH2]([P](c4ccccc4)(C(C)C)C(C)C)([P](c4ccccc4)(C(C)C)C(C)C)([H]1)([H]2)[H]3)([P](C(C)C)(C(C)C)c1ccccc1)[P](c1ccccc1)(C(C)C)C(C)C
• Title of publication: Synthesis and Characterization of the Dinuclear Polyhydrides [Os2H7(PPhiPr2)4]+ and [Os2H6(PPhiPr2)4]
• Authors of publication: Bradley G. Anderson; Sarah A. Hoyte; John L. Spencer
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 7977 - 7983
• a: 17.9836 ± 0.0006 Å
• b: 15.1146 ± 0.0005 Å
• c: 18.9267 ± 0.0006 Å
• α: 90°
• β: 106.994 ± 0.002°
• γ: 90°
• Cell volume: 4919.9 ± 0.3 ų
• Cell temperature: 119 K
• Ambient diffraction temperature: 119 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.056
• Residual factor for significantly intense reflections: 0.0318
• Weighted residual factors for significantly intense reflections: 0.0617
• Weighted residual factors for all reflections included in the refinement: 0.0715
• Goodness-of-fit parameter for all reflections included in the refinement: 1.092
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No