Information card for entry 4302912

Structure parameters

• Formula: C33 H50 Ge N4 Si
• Calculated formula: C33 H50 Ge N4 Si
• SMILES: [Ge]1(N(C(=CC(=[N]1c1c(cccc1C(C)C)C(C)C)C)C)c1c(cccc1C(C)C)C(C)C)N([Si](C)(C)C)[N]#[C]
• Title of publication: Dehydrogenation of LGeH by a Lewis N-Heterocyclic Carbene Borane Pair under the Formation of L'Ge and its Reactions with B(C6F5)3 and Trimethylsilyl Diazomethane: An Unprecedented Rearrangement of a Diazocompound to an Isonitrile
• Authors of publication: Anukul Jana; Ina Objartel; Herbert W. Roesky; Dietmar Stalke
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 7645 - 7649
• a: 10.778 ± 0.003 Å
• b: 12.04 ± 0.004 Å
• c: 14.445 ± 0.004 Å
• α: 107.113 ± 0.003°
• β: 94.231 ± 0.004°
• γ: 109.254 ± 0.003°
• Cell volume: 1660.7 ± 0.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0331
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.0869
• Weighted residual factors for all reflections included in the refinement: 0.088
• Goodness-of-fit parameter for all reflections included in the refinement: 1.063
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No