#------------------------------------------------------------------------------
#$Date: 2016-02-16 21:30:59 +0100 (Tue 16 de Feb de 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/29/4302913.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302913
loop_
_publ_author_name
'Ester Alonso'
'Juan Forniés'
'Consuelo Fortuño'
'Agustí Lledós'
'Antonio Martín'
'Ainara Nova'
_publ_section_title
;
Behavior of P-Pt and P-Pd Bonds in Phosphido Complexes toward
Electrophilic Fragments
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7679
_journal_page_last               7690
_journal_paper_doi               10.1021/ic900415m
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C74.5 H55 Ag Cl6 F10 O4 P4 Pt2'
_chemical_formula_weight         2038.81
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.734(7)
_cell_angle_beta                 91.811(6)
_cell_angle_gamma                113.422(7)
_cell_formula_units_Z            2
_cell_length_a                   12.7400(10)
_cell_length_b                   13.840(2)
_cell_length_c                   23.114(3)
_cell_measurement_reflns_used    350
_cell_measurement_temperature    566(2)
_cell_measurement_theta_max      23.8
_cell_measurement_theta_min      2.34
_cell_volume                     3736.4(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.931
_diffrn_measured_fraction_theta_max 0.840
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0708
_diffrn_reflns_av_sigmaI/netI    0.0548
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            18383
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         26.11
_diffrn_reflns_theta_min         1.60
_exptl_absorpt_coefficient_mu    4.368
_exptl_absorpt_correction_T_max  0.4081
_exptl_absorpt_correction_T_min  0.2740
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.812
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1978
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.25
_refine_diff_density_max         2.914
_refine_diff_density_min         -3.025
_refine_diff_density_rms         0.222
_refine_ls_extinction_coef       0.00112(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.129
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     921
_refine_ls_number_reflns         12478
_refine_ls_number_restraints     26
_refine_ls_restrained_S_all      1.143
_refine_ls_R_factor_all          0.0663
_refine_ls_R_factor_gt           0.0589
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0712P)²+41.8690P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1474
_refine_ls_wR_factor_ref         0.1564
_reflns_number_gt                11270
_reflns_number_total             12478
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic900415m_si_002_1.cif
_cod_data_source_block           2
_cod_original_cell_volume        3736.5(8)
_cod_original_formula_sum        'C74.50 H55 Ag Cl6 F10 O4 P4 Pt2'
_cod_database_code               4302913
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.41247(3) 0.08276(3) 0.256483(14) 0.02297(12) Uani 1 1 d . . .
Pt2 Pt 0.40569(3) 0.19494(3) 0.351956(14) 0.02276(12) Uani 1 1 d . . .
Ag Ag 0.24428(6) -0.10941(6) 0.23242(3) 0.03378(19) Uani 1 1 d . . .
P1 P 0.26731(19) 0.02882(18) 0.31946(10) 0.0234(5) Uani 1 1 d . . .
P2 P 0.54363(19) 0.24202(18) 0.28387(10) 0.0243(5) Uani 1 1 d . . .
P3 P 0.4792(2) 0.02399(18) 0.18058(10) 0.0247(5) Uani 1 1 d . . .
P4 P 0.0959(2) -0.2825(2) 0.21737(12) 0.0327(5) Uani 1 1 d . . .
C1 C 0.4968(8) 0.3390(8) 0.3926(4) 0.032(2) Uani 1 1 d . . .
C2 C 0.4874(8) 0.4299(7) 0.3732(4) 0.031(2) Uani 1 1 d . . .
C3 C 0.5396(10) 0.5277(8) 0.4028(5) 0.039(2) Uani 1 1 d . . .
C4 C 0.6056(10) 0.5353(8) 0.4529(6) 0.047(3) Uani 1 1 d . . .
C5 C 0.6159(9) 0.4473(10) 0.4728(5) 0.046(3) Uani 1 1 d . . .
C6 C 0.5630(8) 0.3526(8) 0.4434(4) 0.033(2) Uani 1 1 d . . .
F2 F 0.4262(5) 0.4286(5) 0.3250(3) 0.0415(14) Uani 1 1 d . . .
F3 F 0.5274(7) 0.6133(5) 0.3827(4) 0.061(2) Uani 1 1 d . . .
F4 F 0.6548(7) 0.6290(6) 0.4815(4) 0.072(2) Uani 1 1 d . . .
F5 F 0.6756(6) 0.4541(6) 0.5231(3) 0.062(2) Uani 1 1 d . . .
F6 F 0.5736(6) 0.2675(5) 0.4668(3) 0.0443(15) Uani 1 1 d . . .
C7 C 0.2943(7) 0.1733(7) 0.4199(4) 0.0261(19) Uani 1 1 d . . .
C8 C 0.2125(8) 0.2149(7) 0.4190(4) 0.029(2) Uani 1 1 d . . .
C9 C 0.1378(9) 0.2010(9) 0.4626(5) 0.044(3) Uani 1 1 d . . .
C10 C 0.1468(10) 0.1463(9) 0.5113(5) 0.047(3) Uani 1 1 d . . .
C11 C 0.2290(10) 0.1057(9) 0.5146(4) 0.042(3) Uani 1 1 d . . .
C12 C 0.3011(8) 0.1202(8) 0.4700(4) 0.033(2) Uani 1 1 d . . .
F8 F 0.2020(5) 0.2700(5) 0.3731(2) 0.0391(13) Uani 1 1 d . . .
F9 F 0.0577(6) 0.2425(6) 0.4594(3) 0.061(2) Uani 1 1 d . . .
F10 F 0.0728(7) 0.1333(7) 0.5539(3) 0.071(2) Uani 1 1 d . . .
F11 F 0.2374(8) 0.0538(7) 0.5619(3) 0.073(2) Uani 1 1 d . . .
F12 F 0.3811(6) 0.0799(5) 0.4763(3) 0.0465(15) Uani 1 1 d . . .
C13 C 0.1328(8) 0.0407(8) 0.3039(4) 0.029(2) Uani 1 1 d . . .
C14 C 0.1189(9) 0.0743(10) 0.2489(5) 0.041(3) Uani 1 1 d . . .
H14A H 0.1743 0.0849 0.2217 0.050 Uiso 1 1 calc R . .
C15 C 0.0206(10) 0.0921(11) 0.2351(5) 0.053(3) Uani 1 1 d . . .
H15A H 0.0109 0.1149 0.1984 0.064 Uiso 1 1 calc R . .
C16 C -0.0622(10) 0.0762(11) 0.2752(6) 0.051(3) Uani 1 1 d . . .
H16A H -0.1279 0.0871 0.2655 0.062 Uiso 1 1 calc R . .
C17 C -0.0465(9) 0.0439(9) 0.3299(5) 0.041(2) Uani 1 1 d . . .
H17A H -0.1017 0.0344 0.3572 0.049 Uiso 1 1 calc R . .
C18 C 0.0496(8) 0.0254(8) 0.3449(4) 0.032(2) Uani 1 1 d . . .
H18A H 0.0589 0.0031 0.3818 0.038 Uiso 1 1 calc R . .
C19 C 0.2510(7) -0.0770(7) 0.3683(4) 0.0256(19) Uani 1 1 d . . .
C20 C 0.3540(9) -0.0849(9) 0.3889(5) 0.043(3) Uani 1 1 d . . .
H20A H 0.4244 -0.0374 0.3770 0.051 Uiso 1 1 calc R . .
C21 C 0.3491(10) -0.1620(9) 0.4262(5) 0.046(3) Uani 1 1 d . . .
H21A H 0.4166 -0.1665 0.4395 0.055 Uiso 1 1 calc R . .
C22 C 0.2451(10) -0.2339(9) 0.4447(5) 0.044(3) Uani 1 1 d . . .
H22A H 0.2425 -0.2861 0.4703 0.053 Uiso 1 1 calc R . .
C23 C 0.1431(9) -0.2261(9) 0.4239(5) 0.042(2) Uani 1 1 d . . .
H23A H 0.0728 -0.2735 0.4361 0.050 Uiso 1 1 calc R . .
C24 C 0.1468(8) -0.1498(7) 0.3860(4) 0.030(2) Uani 1 1 d . . .
H24A H 0.0790 -0.1466 0.3721 0.036 Uiso 1 1 calc R . .
C25 C 0.6861(8) 0.2589(8) 0.3073(4) 0.030(2) Uani 1 1 d . . .
C26 C 0.7004(10) 0.2179(9) 0.3597(4) 0.039(2) Uani 1 1 d . . .
H26A H 0.6377 0.1844 0.3823 0.046 Uiso 1 1 calc R . .
C27 C 0.8090(10) 0.2268(11) 0.3788(6) 0.055(3) Uani 1 1 d . . .
H27A H 0.8183 0.1995 0.4142 0.065 Uiso 1 1 calc R . .
C28 C 0.9022(11) 0.2755(12) 0.3457(6) 0.062(4) Uani 1 1 d . . .
H28A H 0.9749 0.2834 0.3590 0.074 Uiso 1 1 calc R . .
C29 C 0.8859(10) 0.3133(11) 0.2916(6) 0.056(3) Uani 1 1 d . . .
H29A H 0.9479 0.3443 0.2681 0.067 Uiso 1 1 calc R . .
C30 C 0.7800(9) 0.3048(9) 0.2731(5) 0.040(2) Uani 1 1 d . . .
H30A H 0.7704 0.3301 0.2371 0.048 Uiso 1 1 calc R . .
C31 C 0.5541(8) 0.3530(7) 0.2393(4) 0.030(2) Uani 1 1 d . . .
C32 C 0.6427(8) 0.4502(8) 0.2452(5) 0.038(2) Uani 1 1 d . . .
H32A H 0.7027 0.4621 0.2721 0.046 Uiso 1 1 calc R . .
C33 C 0.6411(10) 0.5309(8) 0.2102(5) 0.046(3) Uani 1 1 d . . .
H33A H 0.7000 0.5974 0.2143 0.055 Uiso 1 1 calc R . .
C34 C 0.5549(11) 0.5137(10) 0.1704(6) 0.056(3) Uani 1 1 d . . .
H34A H 0.5570 0.5678 0.1464 0.068 Uiso 1 1 calc R . .
C35 C 0.4651(11) 0.4182(10) 0.1649(6) 0.053(3) Uani 1 1 d . . .
H35A H 0.4048 0.4085 0.1386 0.064 Uiso 1 1 calc R . .
C36 C 0.4634(9) 0.3349(8) 0.1989(4) 0.036(2) Uani 1 1 d . . .
H36A H 0.4036 0.2689 0.1947 0.043 Uiso 1 1 calc R . .
C37 C 0.6182(8) 0.1111(7) 0.1553(4) 0.028(2) Uani 1 1 d . . .
C38 C 0.7139(9) 0.0878(9) 0.1557(4) 0.039(2) Uani 1 1 d . . .
H38A H 0.7104 0.0240 0.1699 0.047 Uiso 1 1 calc R . .
C39 C 0.8160(9) 0.1602(11) 0.1348(5) 0.051(3) Uani 1 1 d . . .
H39A H 0.8803 0.1442 0.1352 0.061 Uiso 1 1 calc R . .
C40 C 0.8231(10) 0.2548(10) 0.1137(5) 0.051(3) Uani 1 1 d . . .
H40A H 0.8920 0.3032 0.1007 0.061 Uiso 1 1 calc R . .
C41 C 0.7268(11) 0.2771(10) 0.1121(5) 0.052(3) Uani 1 1 d . . .
H41A H 0.7309 0.3408 0.0976 0.063 Uiso 1 1 calc R . .
C42 C 0.6248(10) 0.2063(9) 0.1316(5) 0.041(2) Uani 1 1 d . . .
H42A H 0.5600 0.2214 0.1291 0.050 Uiso 1 1 calc R . .
C43 C 0.3892(8) -0.0067(7) 0.1145(4) 0.030(2) Uani 1 1 d . . .
C44 C 0.2995(9) 0.0271(9) 0.1103(5) 0.042(3) Uani 1 1 d . . .
H44A H 0.2830 0.0602 0.1419 0.050 Uiso 1 1 calc R . .
C45 C 0.2353(12) 0.0110(10) 0.0589(5) 0.054(3) Uani 1 1 d . . .
H45A H 0.1771 0.0354 0.0558 0.064 Uiso 1 1 calc R . .
C46 C 0.2564(12) -0.0407(11) 0.0123(5) 0.058(3) Uani 1 1 d . . .
H46A H 0.2119 -0.0516 -0.0218 0.069 Uiso 1 1 calc R . .
C47 C 0.3436(11) -0.0763(10) 0.0160(5) 0.050(3) Uani 1 1 d . . .
H47A H 0.3561 -0.1131 -0.0152 0.060 Uiso 1 1 calc R . .
C48 C 0.4128(10) -0.0570(9) 0.0666(5) 0.043(3) Uani 1 1 d . . .
H48A H 0.4740 -0.0774 0.0684 0.051 Uiso 1 1 calc R . .
C49 C 0.4952(9) -0.0934(8) 0.2057(4) 0.031(2) Uani 1 1 d . . .
C50 C 0.5587(11) -0.0845(10) 0.2561(5) 0.049(3) Uani 1 1 d . . .
H50A H 0.5984 -0.0185 0.2737 0.059 Uiso 1 1 calc R . .
C51 C 0.5644(13) -0.1730(13) 0.2812(6) 0.063(4) Uani 1 1 d . . .
H51A H 0.6096 -0.1657 0.3147 0.075 Uiso 1 1 calc R . .
C52 C 0.5038(13) -0.2711(12) 0.2568(7) 0.068(4) Uani 1 1 d . . .
H52A H 0.5075 -0.3302 0.2738 0.082 Uiso 1 1 calc R . .
C53 C 0.4374(11) -0.2819(9) 0.2070(7) 0.056(4) Uani 1 1 d . . .
H53A H 0.3960 -0.3486 0.1906 0.068 Uiso 1 1 calc R . .
C54 C 0.4316(9) -0.1949(8) 0.1811(5) 0.043(3) Uani 1 1 d . . .
H54A H 0.3862 -0.2029 0.1476 0.051 Uiso 1 1 calc R . .
C55 C -0.0236(8) -0.2913(8) 0.2617(5) 0.039(2) Uani 1 1 d . . .
C56 C -0.0654(9) -0.3610(9) 0.3047(5) 0.047(3) Uani 1 1 d . . .
H56A H -0.0358 -0.4115 0.3113 0.056 Uiso 1 1 calc R . .
C57 C -0.1535(11) -0.3573(12) 0.3394(6) 0.064(4) Uani 1 1 d . . .
H57A H -0.1800 -0.4032 0.3698 0.077 Uiso 1 1 calc R . .
C58 C -0.1988(10) -0.2847(13) 0.3274(7) 0.068(4) Uani 1 1 d . . .
H58A H -0.2572 -0.2818 0.3496 0.081 Uiso 1 1 calc R . .
C59 C -0.1596(11) -0.2166(11) 0.2833(7) 0.062(4) Uani 1 1 d . . .
H59A H -0.1916 -0.1681 0.2756 0.075 Uiso 1 1 calc R . .
C60 C -0.0734(8) -0.2193(9) 0.2502(5) 0.044(3) Uani 1 1 d . . .
H60A H -0.0478 -0.1731 0.2199 0.053 Uiso 1 1 calc R . .
C61 C 0.1404(8) -0.3852(8) 0.2422(5) 0.038(2) Uani 1 1 d . . .
C62 C 0.1922(10) -0.3742(10) 0.2965(5) 0.046(3) Uani 1 1 d . . .
H62A H 0.2046 -0.3149 0.3196 0.055 Uiso 1 1 calc R . .
C63 C 0.2261(11) -0.4520(14) 0.3166(6) 0.068(4) Uani 1 1 d . . .
H63A H 0.2574 -0.4468 0.3540 0.081 Uiso 1 1 calc R . .
C64 C 0.2130(11) -0.5383(12) 0.2805(7) 0.067(4) Uani 1 1 d . . .
H64A H 0.2370 -0.5896 0.2939 0.081 Uiso 1 1 calc R . .
C65 C 0.1661(10) -0.5483(10) 0.2265(7) 0.056(3) Uani 1 1 d . . .
H65A H 0.1579 -0.6061 0.2030 0.068 Uiso 1 1 calc R . .
C66 C 0.1294(10) -0.4708(9) 0.2057(5) 0.043(3) Uani 1 1 d . . .
H66A H 0.0983 -0.4764 0.1682 0.052 Uiso 1 1 calc R . .
C67 C 0.0343(9) -0.3202(8) 0.1456(5) 0.037(2) Uani 1 1 d . . .
C68 C 0.0942(11) -0.2675(10) 0.0982(5) 0.053(3) Uani 1 1 d . . .
H68A H 0.1648 -0.2115 0.1042 0.063 Uiso 1 1 calc R . .
C69 C 0.0493(13) -0.2977(12) 0.0420(6) 0.065(4) Uani 1 1 d . . .
H69A H 0.0897 -0.2611 0.0109 0.078 Uiso 1 1 calc R . .
C70 C -0.0531(14) -0.3803(11) 0.0324(6) 0.066(4) Uani 1 1 d . . .
H70A H -0.0808 -0.4026 -0.0053 0.080 Uiso 1 1 calc R . .
C71 C -0.1168(13) -0.4319(10) 0.0796(6) 0.067(4) Uani 1 1 d . . .
H71A H -0.1887 -0.4858 0.0732 0.081 Uiso 1 1 calc R . .
C72 C -0.0732(11) -0.4029(9) 0.1353(6) 0.054(3) Uani 1 1 d . . .
H72A H -0.1152 -0.4382 0.1663 0.065 Uiso 1 1 calc R . .
Cl1 Cl 0.1598(2) 0.2555(2) 0.08651(13) 0.0480(6) Uani 1 1 d . . .
O1 O 0.0718(9) 0.1710(9) 0.0569(6) 0.096(4) Uani 1 1 d . . .
O2 O 0.2511(9) 0.3030(10) 0.0507(5) 0.086(4) Uani 1 1 d . . .
O3 O 0.1997(9) 0.2204(9) 0.1372(5) 0.082(3) Uani 1 1 d . . .
O4 O 0.1129(13) 0.3293(12) 0.1031(5) 0.108(5) Uani 1 1 d . . .
C73 C 0.6146(12) 0.4335(12) -0.0371(6) 0.063(4) Uani 1 1 d . . .
Cl2 Cl 0.7186(5) 0.3771(4) -0.0501(2) 0.0986(14) Uani 1 1 d . . .
Cl3 Cl 0.5377(8) 0.3844(8) 0.0183(5) 0.184(3) Uani 1 1 d U . .
C74 C 0.8098(17) 0.8121(13) 0.0801(9) 0.089(6) Uani 1 1 d . . .
Cl4 Cl 0.6953(5) 0.7967(4) 0.1249(3) 0.1073(16) Uani 1 1 d U . .
Cl5 Cl 0.9206(4) 0.9335(4) 0.0925(3) 0.1040(16) Uani 1 1 d . . .
C75 C 1.043(2) 0.476(3) 0.4722(10) 0.105(12) Uani 0.50 1 d PDU . .
Cl6 Cl 0.9135(6) 0.4805(6) 0.4547(4) 0.141(2) Uani 1 1 d DU . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Pt1 P3 107.96(8) . . ?
P2 Pt1 P1 110.31(8) . . ?
P3 Pt1 P1 141.33(9) . . ?
P2 Pt1 Pt2 54.39(6) . . ?
P3 Pt1 Pt2 161.21(6) . . ?
P1 Pt1 Pt2 55.94(6) . . ?
P2 Pt1 Ag 174.78(6) . . ?
P3 Pt1 Ag 77.17(6) . . ?
P1 Pt1 Ag 64.49(6) . . ?
Pt2 Pt1 Ag 120.40(2) . . ?
C1 Pt2 C7 84.1(4) . . ?
C1 Pt2 P2 87.5(3) . . ?
C7 Pt2 P2 171.6(2) . . ?
C1 Pt2 P1 166.8(3) . . ?
C7 Pt2 P1 83.0(2) . . ?
P2 Pt2 P1 105.32(8) . . ?
C1 Pt2 Pt1 139.9(3) . . ?
C7 Pt2 Pt1 135.9(2) . . ?
P2 Pt2 Pt1 52.45(6) . . ?
P1 Pt2 Pt1 52.90(5) . . ?
P4 Ag P1 127.50(8) . . ?
P4 Ag Pt1 176.39(7) . . ?
P1 Ag Pt1 50.01(5) . . ?
C19 P1 C13 111.9(4) . . ?
C19 P1 Pt1 120.5(3) . . ?
C13 P1 Pt1 122.0(3) . . ?
C19 P1 Pt2 114.1(3) . . ?
C13 P1 Pt2 109.0(3) . . ?
Pt1 P1 Pt2 71.16(7) . . ?
C19 P1 Ag 87.0(3) . . ?
C13 P1 Ag 95.8(3) . . ?
Pt1 P1 Ag 65.50(6) . . ?
Pt2 P1 Ag 136.61(10) . . ?
C25 P2 C31 108.3(5) . . ?
C25 P2 Pt1 120.8(3) . . ?
C31 P2 Pt1 117.5(3) . . ?
C25 P2 Pt2 117.6(3) . . ?
C31 P2 Pt2 116.2(3) . . ?
Pt1 P2 Pt2 73.16(7) . . ?
C49 P3 C43 110.1(4) . . ?
C49 P3 C37 106.5(5) . . ?
C43 P3 C37 102.5(4) . . ?
C49 P3 Pt1 104.9(3) . . ?
C43 P3 Pt1 115.7(3) . . ?
C37 P3 Pt1 116.8(3) . . ?
C67 P4 C61 107.2(5) . . ?
C67 P4 C55 105.0(5) . . ?
C61 P4 C55 105.8(5) . . ?
C67 P4 Ag 117.8(4) . . ?
C61 P4 Ag 112.3(3) . . ?
C55 P4 Ag 107.9(3) . . ?
C6 C1 C2 114.7(9) . . ?
C6 C1 Pt2 124.1(7) . . ?
C2 C1 Pt2 121.0(7) . . ?
F2 C2 C1 121.3(9) . . ?
F2 C2 C3 116.0(9) . . ?
C1 C2 C3 122.7(10) . . ?
F3 C3 C4 120.1(10) . . ?
F3 C3 C2 120.7(10) . . ?
C4 C3 C2 119.2(10) . . ?
F4 C4 C5 121.8(12) . . ?
F4 C4 C3 119.1(11) . . ?
C5 C4 C3 119.1(10) . . ?
F5 C5 C4 118.8(10) . . ?
F5 C5 C6 120.6(11) . . ?
C4 C5 C6 120.5(11) . . ?
F6 C6 C5 117.3(9) . . ?
F6 C6 C1 118.9(9) . . ?
C5 C6 C1 123.8(10) . . ?
C8 C7 C12 115.6(8) . . ?
C8 C7 Pt2 121.7(7) . . ?
C12 C7 Pt2 122.6(7) . . ?
F8 C8 C9 117.4(9) . . ?
F8 C8 C7 119.7(8) . . ?
C9 C8 C7 122.9(10) . . ?
F9 C9 C8 120.7(11) . . ?
F9 C9 C10 120.0(10) . . ?
C8 C9 C10 119.4(10) . . ?
F10 C10 C11 121.5(11) . . ?
F10 C10 C9 118.8(11) . . ?
C11 C10 C9 119.7(9) . . ?
F11 C11 C12 121.5(11) . . ?
F11 C11 C10 119.1(10) . . ?
C12 C11 C10 119.3(10) . . ?
F12 C12 C11 116.5(9) . . ?
F12 C12 C7 120.4(9) . . ?
C11 C12 C7 123.1(9) . . ?
C14 C13 C18 120.3(9) . . ?
C14 C13 P1 115.9(7) . . ?
C18 C13 P1 123.6(7) . . ?
C13 C14 C15 119.2(10) . . ?
C16 C15 C14 120.7(11) . . ?
C15 C16 C17 119.4(10) . . ?
C18 C17 C16 121.2(10) . . ?
C17 C18 C13 119.1(10) . . ?
C24 C19 C20 118.9(9) . . ?
C24 C19 P1 124.7(7) . . ?
C20 C19 P1 116.4(7) . . ?
C21 C20 C19 120.0(10) . . ?
C20 C21 C22 121.1(10) . . ?
C21 C22 C23 118.7(10) . . ?
C24 C23 C22 120.7(10) . . ?
C23 C24 C19 120.5(9) . . ?
C26 C25 C30 119.1(9) . . ?
C26 C25 P2 118.2(8) . . ?
C30 C25 P2 122.5(8) . . ?
C25 C26 C27 120.0(11) . . ?
C28 C27 C26 120.7(12) . . ?
C27 C28 C29 118.8(11) . . ?
C30 C29 C28 120.4(11) . . ?
C29 C30 C25 120.9(11) . . ?
C32 C31 C36 120.7(9) . . ?
C32 C31 P2 123.2(8) . . ?
C36 C31 P2 116.1(7) . . ?
C31 C32 C33 118.8(9) . . ?
C34 C33 C32 120.9(10) . . ?
C33 C34 C35 120.9(11) . . ?
C34 C35 C36 120.1(11) . . ?
C35 C36 C31 118.5(10) . . ?
C38 C37 C42 118.9(9) . . ?
C38 C37 P3 124.6(8) . . ?
C42 C37 P3 116.4(7) . . ?
C37 C38 C39 119.8(11) . . ?
C40 C39 C38 121.1(11) . . ?
C39 C40 C41 119.2(11) . . ?
C42 C41 C40 120.8(12) . . ?
C41 C42 C37 120.3(11) . . ?
C44 C43 C48 119.5(10) . . ?
C44 C43 P3 118.9(7) . . ?
C48 C43 P3 121.4(8) . . ?
C45 C44 C43 119.6(10) . . ?
C46 C45 C44 120.9(12) . . ?
C45 C46 C47 120.2(11) . . ?
C46 C47 C48 120.0(11) . . ?
C47 C48 C43 119.6(11) . . ?
C50 C49 C54 118.7(10) . . ?
C50 C49 P3 117.7(8) . . ?
C54 C49 P3 122.9(8) . . ?
C49 C50 C51 120.7(13) . . ?
C52 C51 C50 120.3(14) . . ?
C51 C52 C53 119.9(12) . . ?
C52 C53 C54 120.7(13) . . ?
C53 C54 C49 119.6(12) . . ?
C56 C55 C60 119.0(10) . . ?
C56 C55 P4 124.7(9) . . ?
C60 C55 P4 116.4(8) . . ?
C55 C56 C57 120.7(13) . . ?
C58 C57 C56 118.6(14) . . ?
C59 C58 C57 121.0(13) . . ?
C58 C59 C60 120.4(14) . . ?
C59 C60 C55 120.3(12) . . ?
C62 C61 C66 120.1(10) . . ?
C62 C61 P4 118.7(8) . . ?
C66 C61 P4 121.0(9) . . ?
C61 C62 C63 119.8(12) . . ?
C62 C63 C64 119.9(12) . . ?
C65 C64 C63 121.0(13) . . ?
C64 C65 C66 119.9(14) . . ?
C61 C66 C65 119.2(12) . . ?
C68 C67 C72 118.4(11) . . ?
C68 C67 P4 119.9(8) . . ?
C72 C67 P4 121.7(9) . . ?
C69 C68 C67 120.7(12) . . ?
C70 C69 C68 120.5(14) . . ?
C69 C70 C71 119.6(13) . . ?
C72 C71 C70 120.3(12) . . ?
C71 C72 C67 120.3(12) . . ?
O2 Cl1 O1 110.4(8) . . ?
O2 Cl1 O4 109.9(9) . . ?
O1 Cl1 O4 107.2(9) . . ?
O2 Cl1 O3 109.1(7) . . ?
O1 Cl1 O3 111.0(7) . . ?
O4 Cl1 O3 109.2(7) . . ?
Cl3 C73 Cl2 113.0(8) . . ?
Cl5 C74 Cl4 110.9(9) . . ?
Cl6 C75 Cl6 110.8(15) . 2_766 ?
Cl6 C75 C75 57.1(10) . 2_766 ?
Cl6 C75 C75 53.7(10) 2_766 2_766 ?
C75 Cl6 C75 69.2(15) . 2_766 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P2 2.241(2) . ?
Pt1 P3 2.252(2) . ?
Pt1 P1 2.280(2) . ?
Pt1 Pt2 2.7052(5) . ?
Pt1 Ag 2.7076(9) . ?
Pt2 C1 2.061(10) . ?
Pt2 C7 2.094(9) . ?
Pt2 P2 2.298(2) . ?
Pt2 P1 2.368(2) . ?
Ag P4 2.402(3) . ?
Ag P1 2.686(2) . ?
P1 C19 1.810(10) . ?
P1 C13 1.810(9) . ?
P2 C25 1.801(10) . ?
P2 C31 1.822(10) . ?
P3 C49 1.816(10) . ?
P3 C43 1.820(10) . ?
P3 C37 1.821(9) . ?
P4 C67 1.792(11) . ?
P4 C61 1.820(11) . ?
P4 C55 1.827(10) . ?
C1 C6 1.388(14) . ?
C1 C2 1.390(14) . ?
C2 F2 1.334(12) . ?
C2 C3 1.405(14) . ?
C3 F3 1.342(12) . ?
C3 C4 1.388(17) . ?
C4 F4 1.347(13) . ?
C4 C5 1.360(18) . ?
C5 F5 1.350(13) . ?
C5 C6 1.372(15) . ?
C6 F6 1.355(12) . ?
C7 C8 1.376(13) . ?
C7 C12 1.400(14) . ?
C8 F8 1.348(11) . ?
C8 C9 1.371(14) . ?
C9 F9 1.356(13) . ?
C9 C10 1.390(17) . ?
C10 F10 1.348(12) . ?
C10 C11 1.372(17) . ?
C11 F11 1.340(13) . ?
C11 C12 1.366(14) . ?
C12 F12 1.347(11) . ?
C13 C14 1.389(14) . ?
C13 C18 1.399(13) . ?
C14 C15 1.398(15) . ?
C15 C16 1.379(17) . ?
C16 C17 1.382(17) . ?
C17 C18 1.382(14) . ?
C19 C24 1.388(12) . ?
C19 C20 1.428(14) . ?
C20 C21 1.364(15) . ?
C21 C22 1.387(17) . ?
C22 C23 1.417(16) . ?
C23 C24 1.369(15) . ?
C25 C26 1.381(14) . ?
C25 C30 1.389(14) . ?
C26 C27 1.395(15) . ?
C27 C28 1.372(19) . ?
C28 C29 1.403(19) . ?
C29 C30 1.361(16) . ?
C31 C32 1.371(13) . ?
C31 C36 1.403(14) . ?
C32 C33 1.393(16) . ?
C33 C34 1.355(17) . ?
C34 C35 1.362(17) . ?
C35 C36 1.397(15) . ?
C37 C38 1.379(14) . ?
C37 C42 1.407(15) . ?
C38 C39 1.395(16) . ?
C39 C40 1.373(19) . ?
C40 C41 1.379(18) . ?
C41 C42 1.374(16) . ?
C43 C44 1.398(15) . ?
C43 C48 1.404(14) . ?
C44 C45 1.385(16) . ?
C45 C46 1.377(18) . ?
C46 C47 1.383(19) . ?
C47 C48 1.399(16) . ?
C49 C50 1.373(16) . ?
C49 C54 1.415(15) . ?
C50 C51 1.388(17) . ?
C51 C52 1.37(2) . ?
C52 C53 1.38(2) . ?
C53 C54 1.378(16) . ?
C55 C56 1.360(16) . ?
C55 C60 1.401(16) . ?
C56 C57 1.417(17) . ?
C57 C58 1.37(2) . ?
C58 C59 1.36(2) . ?
C59 C60 1.371(17) . ?
C61 C62 1.377(16) . ?
C61 C66 1.404(15) . ?
C62 C63 1.391(19) . ?
C63 C64 1.40(2) . ?
C64 C65 1.35(2) . ?
C65 C66 1.414(16) . ?
C67 C68 1.395(17) . ?
C67 C72 1.402(15) . ?
C68 C69 1.391(18) . ?
C69 C70 1.36(2) . ?
C70 C71 1.41(2) . ?
C71 C72 1.375(18) . ?
Cl1 O2 1.392(10) . ?
Cl1 O1 1.408(11) . ?
Cl1 O4 1.427(11) . ?
Cl1 O3 1.428(10) . ?
C73 Cl3 1.621(16) . ?
C73 Cl2 1.816(16) . ?
C74 Cl5 1.725(18) . ?
C74 Cl4 1.761(17) . ?
C75 Cl6 1.710(19) . ?
C75 Cl6 1.781(19) 2_766 ?
C75 C75 1.98(5) 2_766 ?
Cl6 C75 1.781(19) 2_766 ?
