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#$Date: 2025-08-20 21:19:29 +0200 (Wed 20 de Aug de 2025) $
#$Revision: 301836 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/30/4303024.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4303024
loop_
_publ_author_name
'Dingxian Jia'
'Qinyan Jin'
'Jiangfang Chen'
'Yingli Pan'
'Yong Zhang'
_publ_contact_author_address
;Soochow University
      College of Chemistry, Chemical Engineering and Materials Science
      P.O. Box 174, Renai Road 199, Suzhou 215123
      P.R.China.
;
_publ_contact_author_email       jiadingxian@suda.edu.cn
_publ_contact_author_fax         86-512-65880089
_publ_contact_author_name        'Dr. Dingxian Jia'
_publ_contact_author_phone       86-512-65880089
_publ_section_title
;
The Coordination of the Tetraselenidoantimonate [SbSe4]3- Anion with
Trivalent Lanthanide Ions Tuned by Ethylene Polyamines
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8286
_journal_page_last               8293
_journal_paper_doi               10.1021/ic900901t
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C8 H26 Eu N6 Sb Se4'
_chemical_formula_sum            'C8 H26 Eu N6 Sb Se4'
_chemical_formula_weight         795.90
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.475(17)
_cell_angle_beta                 104.656(17)
_cell_angle_gamma                108.89(2)
_cell_formula_units_Z            2
_cell_length_a                   8.2239(15)
_cell_length_b                   8.2399(15)
_cell_length_c                   16.173(4)
_cell_measurement_reflns_used    3475
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.5
_cell_measurement_theta_min      3.1
_cell_volume                     990.9(4)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0902
_diffrn_reflns_av_sigmaI/netI    0.1079
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            8845
_diffrn_reflns_theta_full        24.25
_diffrn_reflns_theta_max         24.25
_diffrn_reflns_theta_min         3.06
_exptl_absorpt_coefficient_mu    11.844
_exptl_absorpt_correction_T_max  0.2243
_exptl_absorpt_correction_T_min  0.2004
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.667
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             732
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         2.966
_refine_diff_density_min         -2.288
_refine_diff_density_rms         0.384
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     170
_refine_ls_number_reflns         3170
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.110
_refine_ls_R_factor_all          0.0844
_refine_ls_R_factor_gt           0.0777
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0704P)²+67.0128P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1997
_refine_ls_wR_factor_ref         0.2074
_reflns_number_gt                2378
_reflns_number_total             3170
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic900901t_si_002_1.cif
_cod_data_source_block           complex_IIc
_cod_original_cell_volume        991.0(3)
_cod_database_code               4303024
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.5920(2) -0.2045(2) 0.25107(11) 0.0256(5) Uani 1 1 d . . .
Se1 Se 0.7723(4) -0.1638(3) 0.14662(18) 0.0342(7) Uani 1 1 d . . .
Se2 Se 0.7400(4) 0.0635(3) 0.36113(18) 0.0347(7) Uani 1 1 d . . .
Se3 Se 0.2850(4) -0.2227(4) 0.17758(19) 0.0355(7) Uani 1 1 d . . .
Se4 Se 0.6046(4) -0.4614(4) 0.31694(19) 0.0370(7) Uani 1 1 d . . .
Eu1 Eu 0.97813(16) 0.19523(16) 0.24909(8) 0.0233(4) Uani 1 1 d . . .
N1 N 0.990(3) 0.341(3) 0.1112(14) 0.029(5) Uani 1 1 d . . .
H1 H 1.0809 0.4456 0.1277 0.035 Uiso 1 1 calc R . .
N2 N 0.675(3) 0.221(4) 0.1642(16) 0.048(6) Uani 1 1 d . . .
H2A H 0.5846 0.1270 0.1674 0.057 Uiso 1 1 calc R . .
H2B H 0.6635 0.3150 0.1896 0.057 Uiso 1 1 calc R . .
N3 N 1.236(3) 0.191(3) 0.1902(14) 0.039(6) Uani 1 1 d . . .
H3A H 1.3385 0.2678 0.2261 0.047 Uiso 1 1 calc R . .
H3B H 1.2449 0.0849 0.1917 0.047 Uiso 1 1 calc R . .
N4 N 1.219(3) 0.345(2) 0.3936(14) 0.031(5) Uani 1 1 d . . .
H4 H 1.3203 0.4073 0.3804 0.037 Uiso 1 1 calc R . .
N5 N 1.010(3) 0.509(3) 0.2977(14) 0.037(5) Uani 1 1 d . . .
H5A H 1.0393 0.5713 0.2565 0.045 Uiso 1 1 calc R . .
H5B H 0.9019 0.5086 0.2997 0.045 Uiso 1 1 calc R . .
N6 N 1.129(3) -0.008(3) 0.3293(14) 0.042(6) Uani 1 1 d . . .
H6A H 1.0478 -0.0838 0.3494 0.050 Uiso 1 1 calc R . .
H6B H 1.1569 -0.0686 0.2905 0.050 Uiso 1 1 calc R . .
C1 C 0.826(4) 0.372(4) 0.070(2) 0.050(6) Uani 1 1 d . . .
H1A H 0.8210 0.3841 0.0103 0.061 Uiso 1 1 calc R . .
H1B H 0.8311 0.4814 0.0987 0.061 Uiso 1 1 calc R . .
C2 C 0.661(4) 0.235(4) 0.0722(19) 0.050(6) Uani 1 1 d . . .
H2C H 0.6495 0.1259 0.0409 0.061 Uiso 1 1 calc R . .
H2D H 0.5571 0.2651 0.0457 0.061 Uiso 1 1 calc R . .
C3 C 1.043(4) 0.230(4) 0.0550(19) 0.038(7) Uani 1 1 d . . .
H3C H 1.0477 0.2753 0.0015 0.046 Uiso 1 1 calc R . .
H3D H 0.9557 0.1124 0.0412 0.046 Uiso 1 1 calc R . .
C4 C 1.225(4) 0.229(4) 0.1039(19) 0.038(7) Uani 1 1 d . . .
H4A H 1.2537 0.1442 0.0721 0.046 Uiso 1 1 calc R . .
H4B H 1.3137 0.3424 0.1069 0.046 Uiso 1 1 calc R . .
C5 C 1.167(5) 0.469(4) 0.4399(19) 0.049(8) Uani 1 1 d . . .
H5C H 1.2610 0.5272 0.4931 0.059 Uiso 1 1 calc R . .
H5D H 1.0575 0.4092 0.4541 0.059 Uiso 1 1 calc R . .
C6 C 1.140(4) 0.598(4) 0.3800(18) 0.042(7) Uani 1 1 d . . .
H6C H 1.0965 0.6785 0.4065 0.050 Uiso 1 1 calc R . .
H6D H 1.2529 0.6644 0.3707 0.050 Uiso 1 1 calc R . .
C7 C 1.269(4) 0.221(4) 0.452(2) 0.048(5) Uani 1 1 d . . .
H7A H 1.3826 0.2817 0.4952 0.057 Uiso 1 1 calc R . .
H7B H 1.1780 0.1759 0.4808 0.057 Uiso 1 1 calc R . .
C8 C 1.284(4) 0.075(4) 0.398(2) 0.048(5) Uani 1 1 d . . .
H8A H 1.3857 0.1199 0.3757 0.057 Uiso 1 1 calc R . .
H8B H 1.3061 -0.0089 0.4348 0.057 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Se4 Sb1 Se3 113.20(11) . . ?
Se4 Sb1 Se1 108.66(11) . . ?
Se3 Sb1 Se1 109.78(12) . . ?
Se4 Sb1 Se2 110.95(12) . . ?
Se3 Sb1 Se2 108.85(11) . . ?
Se1 Sb1 Se2 105.08(10) . . ?
Sb1 Se1 Eu1 85.95(9) . . ?
Sb1 Se2 Eu1 86.38(9) . . ?
N3 Eu1 N5 110.3(7) . . ?
N3 Eu1 N4 86.4(7) . . ?
N5 Eu1 N4 64.8(7) . . ?
N3 Eu1 N2 127.3(7) . . ?
N5 Eu1 N2 75.5(8) . . ?
N4 Eu1 N2 135.6(7) . . ?
N3 Eu1 N1 65.4(6) . . ?
N5 Eu1 N1 76.1(7) . . ?
N4 Eu1 N1 119.4(7) . . ?
N2 Eu1 N1 65.7(6) . . ?
N3 Eu1 N6 71.3(7) . . ?
N5 Eu1 N6 130.3(7) . . ?
N4 Eu1 N6 65.7(7) . . ?
N2 Eu1 N6 145.0(8) . . ?
N1 Eu1 N6 135.6(7) . . ?
N3 Eu1 Se2 150.4(5) . . ?
N5 Eu1 Se2 91.0(5) . . ?
N4 Eu1 Se2 84.3(5) . . ?
N2 Eu1 Se2 76.9(5) . . ?
N1 Eu1 Se2 142.4(4) . . ?
N6 Eu1 Se2 79.3(5) . . ?
N3 Eu1 Se1 86.9(5) . . ?
N5 Eu1 Se1 152.8(5) . . ?
N4 Eu1 Se1 139.7(4) . . ?
N2 Eu1 Se1 77.2(6) . . ?
N1 Eu1 Se1 93.4(5) . . ?
N6 Eu1 Se1 74.5(5) . . ?
Se2 Eu1 Se1 82.21(8) . . ?
C1 N1 C3 115(2) . . ?
C1 N1 Eu1 113.5(16) . . ?
C3 N1 Eu1 105.6(15) . . ?
C1 N1 H1 107.5 . . ?
C3 N1 H1 107.5 . . ?
Eu1 N1 H1 107.5 . . ?
C2 N2 Eu1 113.1(17) . . ?
C2 N2 H2A 109.0 . . ?
Eu1 N2 H2A 109.0 . . ?
C2 N2 H2B 109.0 . . ?
Eu1 N2 H2B 109.0 . . ?
H2A N2 H2B 107.8 . . ?
C4 N3 Eu1 116.6(16) . . ?
C4 N3 H3A 108.1 . . ?
Eu1 N3 H3A 108.1 . . ?
C4 N3 H3B 108.1 . . ?
Eu1 N3 H3B 108.1 . . ?
H3A N3 H3B 107.3 . . ?
C5 N4 C7 111(2) . . ?
C5 N4 Eu1 111.1(17) . . ?
C7 N4 Eu1 114.3(16) . . ?
C5 N4 H4 106.8 . . ?
C7 N4 H4 106.8 . . ?
Eu1 N4 H4 106.8 . . ?
C6 N5 Eu1 117.9(16) . . ?
C6 N5 H5A 107.8 . . ?
Eu1 N5 H5A 107.8 . . ?
C6 N5 H5B 107.8 . . ?
Eu1 N5 H5B 107.8 . . ?
H5A N5 H5B 107.2 . . ?
C8 N6 Eu1 115.9(17) . . ?
C8 N6 H6A 108.3 . . ?
Eu1 N6 H6A 108.3 . . ?
C8 N6 H6B 108.3 . . ?
Eu1 N6 H6B 108.3 . . ?
H6A N6 H6B 107.4 . . ?
N1 C1 C2 114(2) . . ?
N1 C1 H1A 108.7 . . ?
C2 C1 H1A 108.7 . . ?
N1 C1 H1B 108.7 . . ?
C2 C1 H1B 108.7 . . ?
H1A C1 H1B 107.6 . . ?
C1 C2 N2 107(3) . . ?
C1 C2 H2C 110.3 . . ?
N2 C2 H2C 110.3 . . ?
C1 C2 H2D 110.3 . . ?
N2 C2 H2D 110.3 . . ?
H2C C2 H2D 108.6 . . ?
N1 C3 C4 108(2) . . ?
N1 C3 H3C 110.2 . . ?
C4 C3 H3C 110.2 . . ?
N1 C3 H3D 110.2 . . ?
C4 C3 H3D 110.2 . . ?
H3C C3 H3D 108.5 . . ?
N3 C4 C3 114(2) . . ?
N3 C4 H4A 108.8 . . ?
C3 C4 H4A 108.8 . . ?
N3 C4 H4B 108.8 . . ?
C3 C4 H4B 108.8 . . ?
H4A C4 H4B 107.7 . . ?
N4 C5 C6 107(2) . . ?
N4 C5 H5C 110.4 . . ?
C6 C5 H5C 110.4 . . ?
N4 C5 H5D 110.4 . . ?
C6 C5 H5D 110.4 . . ?
H5C C5 H5D 108.6 . . ?
N5 C6 C5 110(2) . . ?
N5 C6 H6C 109.6 . . ?
C5 C6 H6C 109.6 . . ?
N5 C6 H6D 109.6 . . ?
C5 C6 H6D 109.6 . . ?
H6C C6 H6D 108.1 . . ?
C8 C7 N4 109(2) . . ?
C8 C7 H7A 109.8 . . ?
N4 C7 H7A 109.8 . . ?
C8 C7 H7B 109.8 . . ?
N4 C7 H7B 109.8 . . ?
H7A C7 H7B 108.3 . . ?
N6 C8 C7 112(2) . . ?
N6 C8 H8A 109.1 . . ?
C7 C8 H8A 109.1 . . ?
N6 C8 H8B 109.1 . . ?
C7 C8 H8B 109.1 . . ?
H8A C8 H8B 107.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Se4 2.446(3) . ?
Sb1 Se3 2.455(3) . ?
Sb1 Se1 2.486(3) . ?
Sb1 Se2 2.492(3) . ?
Se1 Eu1 3.018(3) . ?
Se2 Eu1 2.993(3) . ?
Eu1 N3 2.55(2) . ?
Eu1 N5 2.56(2) . ?
Eu1 N4 2.58(2) . ?
Eu1 N2 2.60(2) . ?
Eu1 N1 2.603(19) . ?
Eu1 N6 2.61(2) . ?
N1 C1 1.46(3) . ?
N1 C3 1.48(3) . ?
N1 H1 0.9100 . ?
N2 C2 1.48(4) . ?
N2 H2A 0.9000 . ?
N2 H2B 0.9000 . ?
N3 C4 1.44(3) . ?
N3 H3A 0.9000 . ?
N3 H3B 0.9000 . ?
N4 C5 1.46(3) . ?
N4 C7 1.51(3) . ?
N4 H4 0.9100 . ?
N5 C6 1.45(3) . ?
N5 H5A 0.9000 . ?
N5 H5B 0.9000 . ?
N6 C8 1.40(4) . ?
N6 H6A 0.9000 . ?
N6 H6B 0.9000 . ?
C1 C2 1.47(4) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 H2C 0.9700 . ?
C2 H2D 0.9700 . ?
C3 C4 1.51(4) . ?
C3 H3C 0.9700 . ?
C3 H3D 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.52(4) . ?
C5 H5C 0.9700 . ?
C5 H5D 0.9700 . ?
C6 H6C 0.9700 . ?
C6 H6D 0.9700 . ?
C7 C8 1.49(4) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1 Se3 0.91 2.65 3.54(2) 166.8 1_665
N2 H2B Se4 0.90 2.91 3.77(3) 159.7 1_565
N3 H3A Se4 0.90 2.60 3.48(2) 167.7 1_665
N3 H3B Se3 0.90 2.66 3.56(2) 172.4 1_655
N4 H4 Se4 0.91 2.72 3.62(2) 168.8 1_665
N5 H5A Se3 0.90 2.82 3.64(2) 153.4 1_665
N5 H5B Se4 0.90 2.62 3.51(2) 174.1 1_565
N6 H6B Se3 0.90 2.76 3.65(2) 172.7 1_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Se4 Sb1 Se1 Eu1 -124.04(10) . . . . ?
Se3 Sb1 Se1 Eu1 111.67(10) . . . . ?
Se2 Sb1 Se1 Eu1 -5.23(11) . . . . ?
Se4 Sb1 Se2 Eu1 122.53(10) . . . . ?
Se3 Sb1 Se2 Eu1 -112.26(10) . . . . ?
Se1 Sb1 Se2 Eu1 5.28(11) . . . . ?
Sb1 Se2 Eu1 N3 -73.7(11) . . . . ?
Sb1 Se2 Eu1 N5 149.3(5) . . . . ?
Sb1 Se2 Eu1 N4 -146.1(4) . . . . ?
Sb1 Se2 Eu1 N2 74.4(6) . . . . ?
Sb1 Se2 Eu1 N1 81.2(8) . . . . ?
Sb1 Se2 Eu1 N6 -79.8(5) . . . . ?
Sb1 Se2 Eu1 Se1 -4.23(9) . . . . ?
Sb1 Se1 Eu1 N3 156.7(5) . . . . ?
Sb1 Se1 Eu1 N5 -72.6(11) . . . . ?
Sb1 Se1 Eu1 N4 75.9(7) . . . . ?
Sb1 Se1 Eu1 N2 -74.0(5) . . . . ?
Sb1 Se1 Eu1 N1 -138.2(4) . . . . ?
Sb1 Se1 Eu1 N6 85.2(6) . . . . ?
Sb1 Se1 Eu1 Se2 4.25(9) . . . . ?
N3 Eu1 N1 C1 166(2) . . . . ?
N5 Eu1 N1 C1 -74(2) . . . . ?
N4 Eu1 N1 C1 -123.5(19) . . . . ?
N2 Eu1 N1 C1 6.7(19) . . . . ?
N6 Eu1 N1 C1 152.2(19) . . . . ?
Se2 Eu1 N1 C1 -1(2) . . . . ?
Se1 Eu1 N1 C1 81.0(19) . . . . ?
N3 Eu1 N1 C3 39.3(15) . . . . ?
N5 Eu1 N1 C3 159.6(17) . . . . ?
N4 Eu1 N1 C3 109.6(16) . . . . ?
N2 Eu1 N1 C3 -120.2(17) . . . . ?
N6 Eu1 N1 C3 25(2) . . . . ?
Se2 Eu1 N1 C3 -127.4(14) . . . . ?
Se1 Eu1 N1 C3 -45.8(15) . . . . ?
N3 Eu1 N2 C2 0(2) . . . . ?
N5 Eu1 N2 C2 104(2) . . . . ?
N4 Eu1 N2 C2 131.2(19) . . . . ?
N1 Eu1 N2 C2 23.2(19) . . . . ?
N6 Eu1 N2 C2 -113(2) . . . . ?
Se2 Eu1 N2 C2 -161(2) . . . . ?
Se1 Eu1 N2 C2 -76(2) . . . . ?
N5 Eu1 N3 C4 -78(2) . . . . ?
N4 Eu1 N3 C4 -140(2) . . . . ?
N2 Eu1 N3 C4 9(2) . . . . ?
N1 Eu1 N3 C4 -14.9(18) . . . . ?
N6 Eu1 N3 C4 155(2) . . . . ?
Se2 Eu1 N3 C4 148.5(15) . . . . ?
Se1 Eu1 N3 C4 80.2(19) . . . . ?
N3 Eu1 N4 C5 146.5(18) . . . . ?
N5 Eu1 N4 C5 32.1(16) . . . . ?
N2 Eu1 N4 C5 3(2) . . . . ?
N1 Eu1 N4 C5 87.4(18) . . . . ?
N6 Eu1 N4 C5 -142.4(19) . . . . ?
Se2 Eu1 N4 C5 -61.6(16) . . . . ?
Se1 Eu1 N4 C5 -132.5(15) . . . . ?
N3 Eu1 N4 C7 -87.4(18) . . . . ?
N5 Eu1 N4 C7 158.2(19) . . . . ?
N2 Eu1 N4 C7 129.2(17) . . . . ?
N1 Eu1 N4 C7 -146.6(17) . . . . ?
N6 Eu1 N4 C7 -16.3(17) . . . . ?
Se2 Eu1 N4 C7 64.4(17) . . . . ?
Se1 Eu1 N4 C7 -6(2) . . . . ?
N3 Eu1 N5 C6 -78(2) . . . . ?
N4 Eu1 N5 C6 -2.1(18) . . . . ?
N2 Eu1 N5 C6 157(2) . . . . ?
N1 Eu1 N5 C6 -135(2) . . . . ?
N6 Eu1 N5 C6 5(2) . . . . ?
Se2 Eu1 N5 C6 81.2(19) . . . . ?
Se1 Eu1 N5 C6 156.0(15) . . . . ?
N3 Eu1 N6 C8 82(2) . . . . ?
N5 Eu1 N6 C8 -19(2) . . . . ?
N4 Eu1 N6 C8 -12.4(19) . . . . ?
N2 Eu1 N6 C8 -149(2) . . . . ?
N1 Eu1 N6 C8 96(2) . . . . ?
Se2 Eu1 N6 C8 -101(2) . . . . ?
Se1 Eu1 N6 C8 174(2) . . . . ?
C3 N1 C1 C2 85(3) . . . . ?
Eu1 N1 C1 C2 -37(3) . . . . ?
N1 C1 C2 N2 58(3) . . . . ?
Eu1 N2 C2 C1 -50(3) . . . . ?
C1 N1 C3 C4 173(2) . . . . ?
Eu1 N1 C3 C4 -61(2) . . . . ?
Eu1 N3 C4 C3 -12(3) . . . . ?
N1 C3 C4 N3 50(3) . . . . ?
C7 N4 C5 C6 174(2) . . . . ?
Eu1 N4 C5 C6 -58(3) . . . . ?
Eu1 N5 C6 C5 -27(3) . . . . ?
N4 C5 C6 N5 55(3) . . . . ?
C5 N4 C7 C8 168(3) . . . . ?
Eu1 N4 C7 C8 42(3) . . . . ?
Eu1 N6 C8 C7 40(3) . . . . ?
N4 C7 C8 N6 -54(3) . . . . ?
loop_
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_cod_related_entry_code
1 PubChem 139127001
