#------------------------------------------------------------------------------
#$Date: 2025-08-20 21:19:29 +0200 (Wed 20 de Aug de 2025) $
#$Revision: 301836 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/31/4303196.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4303196
loop_
_publ_author_name
'Jin-Xia Xu'
'Yue Ma'
'Dai-zheng Liao'
'Gong-Feng Xu'
'Jinkui Tang'
'Chao Wang'
'Na Zhou'
'Shi-Ping Yan'
'Peng Cheng'
'Li-Cun Li'
_publ_section_title
;
Four New Lanthanide-Nitronyl Nitroxide (LnIII= PrIII, SmIII, EuIII,
TmIII) Complexes and a TbIII Complex Exhibiting Single-Molecule Magnet
Behavior
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8890
_journal_page_last               8896
_journal_paper_doi               10.1021/ic901169p
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C54 H36 Br2 Eu2 F36 N6 O16'
_chemical_formula_weight         2172.63
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.74(3)
_cell_angle_beta                 107.02(3)
_cell_angle_gamma                115.58(3)
_cell_formula_units_Z            1
_cell_length_a                   11.462(2)
_cell_length_b                   11.482(2)
_cell_length_c                   16.833(3)
_cell_measurement_reflns_used    2451
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.931
_cell_measurement_theta_min      2.321
_cell_volume                     1853.7(10)
_computing_cell_refinement       crystalclear
_computing_data_collection       crystalclear
_computing_data_reduction        crystalclear
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'rigaku saturn'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0523
_diffrn_reflns_av_sigmaI/netI    0.0603
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            16251
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.03
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.910
_exptl_absorpt_correction_T_max  0.8448
_exptl_absorpt_correction_T_min  0.7215
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   crystalclear
_exptl_crystal_density_diffrn    1.946
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1050
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.116
_refine_diff_density_min         -1.493
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     770
_refine_ls_number_reflns         6546
_refine_ls_number_restraints     324
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.0409
_refine_ls_R_factor_gt           0.0360
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0419P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0807
_refine_ls_wR_factor_ref         0.0831
_reflns_number_gt                5704
_reflns_number_total             6546
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic901169p_si_002_3.cif
_cod_data_source_block           r80317c
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed to
'constr' according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        1853.7(6)
_cod_database_code               4303196
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.64582(2) 0.09050(2) 0.225236(12) 0.02225(9) Uani 1 1 d . . .
N1 N 0.6826(3) 0.1704(3) 0.0873(2) 0.0222(8) Uani 1 1 d . A .
N2 N 0.4004(4) 0.2086(3) -0.1381(2) 0.0229(8) Uani 1 1 d . A .
N3 N 0.5492(4) 0.4194(4) -0.0982(2) 0.0252(8) Uani 1 1 d . A .
Br1 Br 1.03161(5) 0.33485(5) 0.02641(3) 0.03832(14) Uani 1 1 d . . .
C13 C 0.2196(5) 0.0743(6) 0.0981(3) 0.0382(12) Uani 1 1 d . . .
C14 C 0.3133(5) 0.0190(5) 0.1448(3) 0.0269(10) Uani 1 1 d . A .
C15 C 0.2630(5) -0.0772(5) 0.1887(3) 0.0323(11) Uani 1 1 d . . .
H15 H 0.1765 -0.1017 0.1924 0.039 Uiso 1 1 calc R B .
C16 C 0.3394(5) -0.1374(5) 0.2270(3) 0.0314(11) Uani 1 1 d . A .
C17 C 0.2725(6) -0.2515(5) 0.2667(3) 0.0433(13) Uani 1 1 d . . .
C18 C 0.6303(4) 0.2702(4) -0.0289(3) 0.0219(9) Uani 1 1 d . A .
C19 C 0.7615(4) 0.3150(4) -0.0306(3) 0.0263(10) Uani 1 1 d . . .
H19 H 0.7894 0.3656 -0.0684 0.032 Uiso 1 1 calc R . .
C20 C 0.8508(4) 0.2823(4) 0.0257(3) 0.0260(10) Uani 1 1 d . A .
C21 C 0.8088(4) 0.2105(4) 0.0831(3) 0.0268(10) Uani 1 1 d . . .
H21 H 0.8703 0.1890 0.1201 0.032 Uiso 1 1 calc R A .
C22 C 0.5925(4) 0.1968(4) 0.0304(2) 0.0220(9) Uani 1 1 d . . .
H22 H 0.5029 0.1656 0.0303 0.026 Uiso 1 1 calc R A .
C23 C 0.5277(5) 0.2973(4) -0.0876(3) 0.0233(10) Uani 1 1 d . . .
C24 C 0.3140(5) 0.2687(4) -0.1834(3) 0.0273(10) Uani 1 1 d . . .
C25 C 0.2165(5) 0.2579(5) -0.1353(3) 0.0404(12) Uani 1 1 d . A .
H25A H 0.1612 0.1662 -0.1367 0.061 Uiso 1 1 calc R . .
H25B H 0.1567 0.2929 -0.1621 0.061 Uiso 1 1 calc R . .
H25C H 0.2704 0.3077 -0.0769 0.061 Uiso 1 1 calc R . .
C26 C 0.2324(6) 0.1894(5) -0.2758(3) 0.0454(14) Uani 1 1 d . A .
H26A H 0.2954 0.1895 -0.3029 0.068 Uiso 1 1 calc R . .
H26B H 0.1796 0.2290 -0.3056 0.068 Uiso 1 1 calc R . .
H26C H 0.1704 0.0995 -0.2774 0.068 Uiso 1 1 calc R . .
C27 C 0.4300(5) 0.4135(5) -0.1707(3) 0.0289(10) Uani 1 1 d . A .
C28 C 0.4799(5) 0.4377(5) -0.2459(3) 0.0419(13) Uani 1 1 d . . .
H28A H 0.5645 0.5205 -0.2280 0.063 Uiso 1 1 calc R A .
H28B H 0.4102 0.4412 -0.2925 0.063 Uiso 1 1 calc R . .
H28C H 0.4962 0.3665 -0.2641 0.063 Uiso 1 1 calc R . .
C29 C 0.4011(5) 0.5238(4) -0.1414(3) 0.0343(11) Uani 1 1 d . . .
H29A H 0.3768 0.5108 -0.0917 0.052 Uiso 1 1 calc R A .
H29B H 0.3256 0.5220 -0.1865 0.052 Uiso 1 1 calc R . .
H29C H 0.4826 0.6083 -0.1275 0.052 Uiso 1 1 calc R . .
O1 O 0.745(2) 0.065(4) 0.3621(7) 0.0263(19) Uani 0.743(3) 1 d PD A 1
O2 O 0.552(3) 0.1678(19) 0.3174(7) 0.028(2) Uani 0.743(3) 1 d PD A 1
O3 O 0.8923(11) 0.1557(15) 0.2548(6) 0.023(2) Uani 0.743(3) 1 d PD A 1
O4 O 0.7775(17) 0.325(12) 0.276(4) 0.0307(10) Uani 0.743(3) 1 d PD A 1
C1 C 0.8332(7) 0.0612(8) 0.5039(4) 0.0324(13) Uani 0.743(3) 1 d PD A 1
C2 C 0.7421(6) 0.0957(6) 0.4350(3) 0.0234(13) Uani 0.743(3) 1 d PD A 1
C3 C 0.6721(6) 0.1567(6) 0.4576(4) 0.0324(16) Uani 0.743(3) 1 d PD A 1
H3 H 0.6816 0.1752 0.5147 0.039 Uiso 0.743(3) 1 calc PR A 1
C4 C 0.5871(6) 0.1915(7) 0.3975(4) 0.0255(15) Uani 0.743(3) 1 d PD A 1
C5 C 0.5221(8) 0.2674(7) 0.4294(4) 0.048(2) Uani 0.743(3) 1 d PD A 1
C6 C 1.1284(8) 0.2404(7) 0.3319(4) 0.0413(17) Uani 0.743(3) 1 d PD A 1
C7 C 0.9971(8) 0.2539(7) 0.3120(5) 0.0295(18) Uani 0.743(3) 1 d PD A 1
C8 C 1.0084(6) 0.3720(6) 0.3540(4) 0.0329(16) Uani 0.743(3) 1 d PD A 1
H8 H 1.0905 0.4319 0.3987 0.040 Uiso 0.743(3) 1 calc PR A 1
C9 C 0.8986(6) 0.3994(6) 0.3294(4) 0.0290(15) Uani 0.743(3) 1 d PD A 1
C10 C 0.9176(7) 0.5311(7) 0.3726(5) 0.0401(15) Uani 0.743(3) 1 d PD A 1
O1' O 0.730(6) 0.070(13) 0.360(2) 0.0263(19) Uani 0.257(3) 1 d PD A 2
O4' O 0.566(8) 0.157(6) 0.315(2) 0.028(2) Uani 0.257(3) 1 d PD A 2
O2' O 0.876(4) 0.163(5) 0.263(2) 0.023(2) Uani 0.257(3) 1 d PD A 2
O3' O 0.777(5) 0.32(3) 0.273(12) 0.0307(10) Uani 0.257(3) 1 d PD A 2
C1' C 0.8430(15) 0.0588(17) 0.4985(9) 0.0324(13) Uani 0.257(3) 1 d PD A 2
C2' C 0.8463(17) 0.0978(16) 0.4155(9) 0.033(5) Uani 0.257(3) 1 d PD A 2
C3' C 0.9737(15) 0.1690(17) 0.4063(9) 0.028(4) Uani 0.257(3) 1 d PD A 2
H3' H 1.0550 0.2051 0.4543 0.033 Uiso 0.257(3) 1 calc PR A 2
C4' C 0.9826(19) 0.188(3) 0.3262(11) 0.043(6) Uani 0.257(3) 1 d PD A 2
C5' C 1.1237(19) 0.2566(17) 0.3192(11) 0.0413(17) Uani 0.257(3) 1 d PD A 2
C7' C 0.7992(15) 0.3893(17) 0.3439(11) 0.034(5) Uani 0.257(3) 1 d PD A 2
C6' C 0.9308(15) 0.5189(18) 0.3697(12) 0.0401(15) Uani 0.257(3) 1 d PD A 2
C8' C 0.7227(18) 0.3678(18) 0.3970(10) 0.039(5) Uani 0.257(3) 1 d PD A 2
H8' H 0.7568 0.4297 0.4484 0.047 Uiso 0.257(3) 1 calc PR A 2
C9' C 0.5939(18) 0.252(2) 0.3727(13) 0.049(7) Uani 0.257(3) 1 d PD A 2
C10' C 0.5048(15) 0.2225(17) 0.4264(11) 0.048(2) Uani 0.257(3) 1 d PD A 2
F1 F 0.9656(4) 0.1265(5) 0.5104(3) 0.0533(12) Uani 0.743(3) 1 d PDU A 1
F2 F 0.7948(9) -0.0667(7) 0.4833(7) 0.057(4) Uani 0.743(3) 1 d PDU A 1
F3 F 0.8326(5) 0.0893(4) 0.5813(2) 0.0535(12) Uani 0.743(3) 1 d PDU A 1
F4 F 0.6082(7) 0.3547(6) 0.5038(3) 0.095(2) Uani 0.743(3) 1 d PDU A 1
F5 F 0.4153(7) 0.1862(6) 0.4444(5) 0.126(3) Uani 0.743(3) 1 d PDU A 1
F6 F 0.4853(5) 0.3350(5) 0.3791(3) 0.0804(17) Uani 0.743(3) 1 d PDU A 1
F7 F 1.2190(8) 0.3111(7) 0.4092(4) 0.069(2) Uani 0.743(3) 1 d PDU A 1
F8 F 1.1049(5) 0.1169(5) 0.3277(4) 0.0795(18) Uani 0.743(3) 1 d PDU A 1
F9 F 1.1876(6) 0.2827(7) 0.2762(4) 0.093(2) Uani 0.743(3) 1 d PDU A 1
F10 F 1.0402(4) 0.6033(5) 0.4362(3) 0.0603(16) Uani 0.743(3) 1 d PDU A 1
F11 F 0.8200(4) 0.5156(4) 0.4039(3) 0.0602(13) Uani 0.743(3) 1 d PDU A 1
F12 F 0.9106(9) 0.6051(8) 0.3162(4) 0.048(2) Uani 0.743(3) 1 d PDU A 1
F13 F 0.2739(19) 0.2008(19) 0.1217(17) 0.055(4) Uani 0.68(7) 1 d PU B 1
F14 F 0.1958(19) 0.042(3) 0.0125(9) 0.050(3) Uani 0.68(7) 1 d PU B 1
F15 F 0.0918(15) 0.011(2) 0.0960(16) 0.043(3) Uani 0.68(7) 1 d PU B 1
F16 F 0.294(5) -0.341(5) 0.254(3) 0.045(13) Uani 0.100(10) 1 d PU B 1
F17 F 0.123(4) -0.328(4) 0.209(3) 0.073(14) Uani 0.100(10) 1 d PU B 1
F18 F 0.254(5) -0.224(4) 0.327(3) 0.061(13) Uani 0.100(10) 1 d PU B 1
F1' F 0.9670(11) 0.1159(12) 0.5628(8) 0.050(3) Uani 0.257(3) 1 d PDU A 2
F2' F 0.7928(18) -0.0731(14) 0.4878(18) 0.030(9) Uani 0.257(3) 1 d PDU A 2
F3' F 0.7605(12) 0.0885(13) 0.5298(9) 0.060(4) Uani 0.257(3) 1 d PDU A 2
F4' F 1.239(3) 0.334(2) 0.3884(10) 0.080(9) Uani 0.257(3) 1 d PDU A 2
F5' F 1.1445(16) 0.1598(16) 0.2865(10) 0.071(5) Uani 0.257(3) 1 d PDU A 2
F6' F 1.1286(18) 0.3328(17) 0.2618(11) 0.102(6) Uani 0.257(3) 1 d PDU A 2
F7' F 0.930(3) 0.600(3) 0.3165(15) 0.086(13) Uani 0.257(3) 1 d PDU A 2
F8' F 1.0438(13) 0.5067(14) 0.3719(9) 0.076(4) Uani 0.257(3) 1 d PDU A 2
F9' F 0.974(2) 0.599(2) 0.4466(11) 0.091(7) Uani 0.257(3) 1 d PDU A 2
F10' F 0.3703(11) 0.1719(14) 0.3787(7) 0.050(4) Uani 0.257(3) 1 d PDU A 2
F11' F 0.529(2) 0.3227(19) 0.4860(14) 0.154(11) Uani 0.257(3) 1 d PDU A 2
F12' F 0.5047(17) 0.1303(17) 0.4722(10) 0.111(6) Uani 0.257(3) 1 d PDU A 2
F13' F 0.280(4) 0.210(4) 0.147(3) 0.044(6) Uani 0.32(7) 1 d PU B 2
F14' F 0.224(4) 0.093(5) 0.023(2) 0.048(6) Uani 0.32(7) 1 d PU B 2
F15' F 0.099(4) 0.033(4) 0.119(3) 0.041(6) Uani 0.32(7) 1 d PU B 2
F16' F 0.2470(6) -0.3667(5) 0.2211(3) 0.0570(15) Uani 0.900(10) 1 d PU B 2
F17' F 0.1544(5) -0.2666(5) 0.2713(4) 0.081(2) Uani 0.900(10) 1 d PU B 2
F18' F 0.3551(5) -0.2342(4) 0.3455(2) 0.0748(19) Uani 0.900(10) 1 d PU B 2
O5 O 0.4297(3) 0.0682(3) 0.13707(17) 0.0276(7) Uani 1 1 d . A .
O6 O 0.4602(3) -0.1120(3) 0.23141(18) 0.0307(7) Uani 1 1 d . A .
O7 O 0.3471(3) 0.0808(3) -0.14368(18) 0.0264(7) Uani 1 1 d . . .
O8 O 0.6603(3) 0.5269(3) -0.0576(2) 0.0378(8) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4' Eu1 O2' 120(2) . . ?
O4' Eu1 O1' 66.4(19) . . ?
O2' Eu1 O1' 71.4(19) . . ?
O4' Eu1 O3' 72(3) . . ?
O2' Eu1 O3' 68(4) . . ?
O1' Eu1 O3' 90(8) . . ?
O4' Eu1 O7 150.2(18) . 2_655 ?
O2' Eu1 O7 77.2(11) . 2_655 ?
O1' Eu1 O7 102(3) . 2_655 ?
O3' Eu1 O7 136.9(15) . 2_655 ?
O4' Eu1 O1 70.7(13) . . ?
O2' Eu1 O1 67.9(13) . . ?
O1' Eu1 O1 4.3(15) . . ?
O3' Eu1 O1 91(8) . . ?
O7 Eu1 O1 98.0(7) 2_655 . ?
O4' Eu1 O4 71(2) . . ?
O2' Eu1 O4 68.0(18) . . ?
O1' Eu1 O4 90(4) . . ?
O3' Eu1 O4 1(6) . . ?
O7 Eu1 O4 137.8(5) 2_655 . ?
O1 Eu1 O4 91(3) . . ?
O4' Eu1 O5 74.9(15) . . ?
O2' Eu1 O5 153.2(12) . . ?
O1' Eu1 O5 134.3(12) . . ?
O3' Eu1 O5 100(6) . . ?
O7 Eu1 O5 100.18(11) 2_655 . ?
O1 Eu1 O5 138.1(4) . . ?
O4 Eu1 O5 100(2) . . ?
O4' Eu1 O6 75.2(19) . . ?
O2' Eu1 O6 131.8(13) . . ?
O1' Eu1 O6 76(3) . . ?
O3' Eu1 O6 147(2) . . ?
O7 Eu1 O6 75.42(10) 2_655 . ?
O1 Eu1 O6 77.5(9) . . ?
O4 Eu1 O6 146.5(9) . . ?
O5 Eu1 O6 71.13(10) . . ?
O4' Eu1 O2 3.1(16) . . ?
O2' Eu1 O2 121.9(11) . . ?
O1' Eu1 O2 69.5(15) . . ?
O3' Eu1 O2 71(2) . . ?
O7 Eu1 O2 151.5(6) 2_655 . ?
O1 Eu1 O2 73.8(5) . . ?
O4 Eu1 O2 70.4(9) . . ?
O5 Eu1 O2 72.3(4) . . ?
O6 Eu1 O2 76.2(6) . . ?
O4' Eu1 O3 125.1(18) . . ?
O2' Eu1 O3 4.9(12) . . ?
O1' Eu1 O3 74.3(14) . . ?
O3' Eu1 O3 71(4) . . ?
O7 Eu1 O3 72.6(3) 2_655 . ?
O1 Eu1 O3 70.7(6) . . ?
O4 Eu1 O3 71.6(12) . . ?
O5 Eu1 O3 151.1(3) . . ?
O6 Eu1 O3 130.4(4) . . ?
O2 Eu1 O3 126.8(5) . . ?
O4' Eu1 N1 129.6(13) . . ?
O2' Eu1 N1 80.0(12) . . ?
O1' Eu1 N1 151.2(18) . . ?
O3' Eu1 N1 76(7) . . ?
O7 Eu1 N1 74.19(10) 2_655 . ?
O1 Eu1 N1 147.9(5) . . ?
O4 Eu1 N1 77(2) . . ?
O5 Eu1 N1 73.75(10) . . ?
O6 Eu1 N1 127.79(11) . . ?
O2 Eu1 N1 126.7(4) . . ?
O3 Eu1 N1 77.3(3) . . ?
C21 N1 C22 117.9(4) . . ?
C21 N1 Eu1 117.3(3) . . ?
C22 N1 Eu1 123.6(3) . . ?
O7 N2 C23 124.3(3) . . ?
O7 N2 C24 121.7(3) . . ?
C23 N2 C24 113.8(3) . . ?
O8 N3 C23 124.8(4) . . ?
O8 N3 C27 122.7(3) . . ?
C23 N3 C27 112.3(4) . . ?
F13 C13 F14' 85.8(15) . . ?
F13 C13 F15 113.2(18) . . ?
F14' C13 F15 112(2) . . ?
F13 C13 F14 107.5(8) . . ?
F14' C13 F14 21.9(15) . . ?
F15 C13 F14 99.9(18) . . ?
F13 C13 F15' 101(2) . . ?
F14' C13 F15' 124(2) . . ?
F15 C13 F15' 16.6(15) . . ?
F14 C13 F15' 115(2) . . ?
F13 C13 F13' 15.3(17) . . ?
F14' C13 F13' 101(2) . . ?
F15 C13 F13' 107(2) . . ?
F14 C13 F13' 122.9(13) . . ?
F15' C13 F13' 93(2) . . ?
F13 C13 C14 113.6(10) . . ?
F14' C13 C14 115.1(13) . . ?
F15 C13 C14 113.8(8) . . ?
F14 C13 C14 107.5(8) . . ?
F15' C13 C14 112.1(16) . . ?
F13' C13 C14 105.8(19) . . ?
O5 C14 C15 127.8(4) . . ?
O5 C14 C13 113.4(4) . . ?
C15 C14 C13 118.9(4) . . ?
C16 C15 C14 121.3(4) . . ?
C16 C15 H15 119.3 . . ?
C14 C15 H15 119.3 . . ?
O6 C16 C15 127.6(4) . . ?
O6 C16 C17 113.8(4) . . ?
C15 C16 C17 118.6(5) . . ?
F18 C17 F16 121(3) . . ?
F18 C17 F17' 53(3) . . ?
F16 C17 F17' 123(2) . . ?
F18 C17 F18' 56(3) . . ?
F16 C17 F18' 81(2) . . ?
F17' C17 F18' 106.8(5) . . ?
F18 C17 F16' 133(2) . . ?
F16 C17 F16' 26(2) . . ?
F17' C17 F16' 107.5(5) . . ?
F18' C17 F16' 106.6(5) . . ?
F18 C17 F17 97(3) . . ?
F16 C17 F17 94(3) . . ?
F17' C17 F17 44.6(18) . . ?
F18' C17 F17 140.7(17) . . ?
F16' C17 F17 69.9(19) . . ?
F18 C17 C16 117(2) . . ?
F16 C17 C16 115(2) . . ?
F17' C17 C16 113.3(5) . . ?
F18' C17 C16 111.7(5) . . ?
F16' C17 C16 110.6(4) . . ?
F17 C17 C16 105.7(16) . . ?
C19 C18 C22 119.7(4) . . ?
C19 C18 C23 121.6(4) . . ?
C22 C18 C23 118.7(4) . . ?
C18 C19 C20 117.8(4) . . ?
C18 C19 H19 121.1 . . ?
C20 C19 H19 121.1 . . ?
C21 C20 C19 120.2(4) . . ?
C21 C20 Br1 118.7(3) . . ?
C19 C20 Br1 121.1(3) . . ?
N1 C21 C20 122.5(4) . . ?
N1 C21 H21 118.8 . . ?
C20 C21 H21 118.8 . . ?
N1 C22 C18 121.8(4) . . ?
N1 C22 H22 119.1 . . ?
C18 C22 H22 119.1 . . ?
N2 C23 N3 108.9(4) . . ?
N2 C23 C18 126.3(4) . . ?
N3 C23 C18 124.8(4) . . ?
N2 C24 C26 109.0(3) . . ?
N2 C24 C25 105.4(3) . . ?
C26 C24 C25 111.0(4) . . ?
N2 C24 C27 100.6(3) . . ?
C26 C24 C27 115.0(4) . . ?
C25 C24 C27 114.7(4) . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N3 C27 C29 108.0(4) . . ?
N3 C27 C28 106.1(4) . . ?
C29 C27 C28 110.6(4) . . ?
N3 C27 C24 100.8(3) . . ?
C29 C27 C24 115.4(4) . . ?
C28 C27 C24 114.9(4) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C2 O1 Eu1 134.4(15) . . ?
C4 O2 Eu1 130.6(11) . . ?
C7 O3 Eu1 126.7(7) . . ?
C9 O4 Eu1 131(9) . . ?
F3 C1 F2 107.7(6) . . ?
F3 C1 F1 106.4(5) . . ?
F2 C1 F1 106.5(6) . . ?
F3 C1 C2 114.9(5) . . ?
F2 C1 C2 110.2(7) . . ?
F1 C1 C2 110.7(6) . . ?
O1 C2 C3 128.6(11) . . ?
O1 C2 C1 112.1(11) . . ?
C3 C2 C1 119.3(5) . . ?
C2 C3 C4 122.2(5) . . ?
C2 C3 H3 118.9 . . ?
C4 C3 H3 118.9 . . ?
O2 C4 C3 129.3(8) . . ?
O2 C4 C5 112.3(8) . . ?
C3 C4 C5 118.4(5) . . ?
F5 C5 F6 108.7(6) . . ?
F5 C5 F4 105.2(6) . . ?
F6 C5 F4 105.4(6) . . ?
F5 C5 C4 109.8(6) . . ?
F6 C5 C4 115.6(6) . . ?
F4 C5 C4 111.6(6) . . ?
F8 C6 F7 107.2(6) . . ?
F8 C6 F9 106.7(6) . . ?
F7 C6 F9 108.0(6) . . ?
F8 C6 C7 113.3(6) . . ?
F7 C6 C7 111.5(6) . . ?
F9 C6 C7 109.9(6) . . ?
O3 C7 C8 129.5(7) . . ?
O3 C7 C6 112.5(7) . . ?
C8 C7 C6 117.8(6) . . ?
C9 C8 C7 120.6(6) . . ?
C9 C8 H8 119.7 . . ?
C7 C8 H8 119.7 . . ?
O4 C9 C8 128(5) . . ?
O4 C9 C10 113(5) . . ?
C8 C9 C10 119.1(5) . . ?
F11 C10 F10 107.6(5) . . ?
F11 C10 F12 106.6(6) . . ?
F10 C10 F12 106.5(6) . . ?
F11 C10 C9 112.5(6) . . ?
F10 C10 C9 113.1(6) . . ?
F12 C10 C9 110.1(6) . . ?
C2' O1' Eu1 138(6) . . ?
C9' O4' Eu1 144(6) . . ?
C4' O2' Eu1 141(3) . . ?
C7' O3' Eu1 125(10) . . ?
F1' C1' F2' 106.5(10) . . ?
F1' C1' F3' 105.1(10) . . ?
F2' C1' F3' 105.7(10) . . ?
F1' C1' C2' 114.7(14) . . ?
F2' C1' C2' 110.6(19) . . ?
F3' C1' C2' 113.5(13) . . ?
O1' C2' C3' 124(5) . . ?
O1' C2' C1' 116(4) . . ?
C3' C2' C1' 119.7(14) . . ?
C2' C3' C4' 121.8(14) . . ?
C2' C3' H3' 119.1 . . ?
C4' C3' H3' 119.1 . . ?
O2' C4' C3' 121(3) . . ?
O2' C4' C5' 119(3) . . ?
C3' C4' C5' 119.3(15) . . ?
F5' C5' F4' 105.9(11) . . ?
F5' C5' F6' 104.8(11) . . ?
F4' C5' F6' 104.4(11) . . ?
F5' C5' C4' 106.0(16) . . ?
F4' C5' C4' 121.4(19) . . ?
F6' C5' C4' 113.0(16) . . ?
O3' C7' C8' 132(10) . . ?
O3' C7' C6' 110(10) . . ?
C8' C7' C6' 117.4(16) . . ?
F9' C6' F7' 102.9(11) . . ?
F9' C6' F8' 103.0(10) . . ?
F7' C6' F8' 102.0(11) . . ?
F9' C6' C7' 117.6(18) . . ?
F7' C6' C7' 115(2) . . ?
F8' C6' C7' 114.4(14) . . ?
C7' C8' C9' 119.7(15) . . ?
C7' C8' H8' 120.2 . . ?
C9' C8' H8' 120.2 . . ?
O4' C9' C8' 118(4) . . ?
O4' C9' C10' 117(4) . . ?
C8' C9' C10' 122.8(17) . . ?
F11' C10' F10' 103.6(11) . . ?
F11' C10' F12' 101.7(11) . . ?
F10' C10' F12' 102.5(11) . . ?
F11' C10' C9' 118.3(19) . . ?
F10' C10' C9' 111.9(14) . . ?
F12' C10' C9' 116.8(16) . . ?
C14 O5 Eu1 130.8(3) . . ?
C16 O6 Eu1 129.5(3) . . ?
N2 O7 Eu1 132.5(2) . 2_655 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O4' 2.22(5) . ?
Eu1 O2' 2.26(3) . ?
Eu1 O1' 2.27(6) . ?
Eu1 O3' 2.3(3) . ?
Eu1 O7 2.349(3) 2_655 ?
Eu1 O1 2.358(19) . ?
Eu1 O4 2.37(11) . ?
Eu1 O5 2.376(3) . ?
Eu1 O6 2.417(3) . ?
Eu1 O2 2.430(15) . ?
Eu1 O3 2.466(10) . ?
Eu1 N1 2.645(3) . ?
N1 C21 1.342(5) . ?
N1 C22 1.348(5) . ?
N2 O7 1.306(4) . ?
N2 C23 1.318(5) . ?
N2 C24 1.508(5) . ?
N3 O8 1.267(4) . ?
N3 C23 1.351(5) . ?
N3 C27 1.514(5) . ?
Br1 C20 1.888(4) . ?
C13 F13 1.28(2) . ?
C13 F14' 1.30(3) . ?
C13 F15 1.312(16) . ?
C13 F14 1.371(15) . ?
C13 F15' 1.41(4) . ?
C13 F13' 1.45(5) . ?
C13 C14 1.533(6) . ?
C14 O5 1.257(5) . ?
C14 C15 1.390(6) . ?
C15 C16 1.387(6) . ?
C15 H15 0.9300 . ?
C16 O6 1.264(5) . ?
C16 C17 1.525(7) . ?
C17 F18 1.14(4) . ?
C17 F16 1.17(5) . ?
C17 F17' 1.315(7) . ?
C17 F18' 1.324(7) . ?
C17 F16' 1.339(7) . ?
C17 F17 1.49(4) . ?
C18 C19 1.374(6) . ?
C18 C22 1.403(6) . ?
C18 C23 1.464(6) . ?
C19 C20 1.381(6) . ?
C19 H19 0.9300 . ?
C20 C21 1.380(6) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C24 C26 1.517(6) . ?
C24 C25 1.532(6) . ?
C24 C27 1.563(6) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 C29 1.520(6) . ?
C27 C28 1.533(6) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
O1 C2 1.262(11) . ?
O2 C4 1.258(10) . ?
O3 C7 1.271(9) . ?
O4 C9 1.260(11) . ?
C1 F3 1.319(6) . ?
C1 F2 1.319(7) . ?
C1 F1 1.335(7) . ?
C1 C2 1.522(7) . ?
C2 C3 1.377(6) . ?
C3 C4 1.400(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.523(7) . ?
C5 F5 1.290(7) . ?
C5 F6 1.295(7) . ?
C5 F4 1.328(7) . ?
C6 F8 1.315(7) . ?
C6 F7 1.318(7) . ?
C6 F9 1.319(7) . ?
C6 C7 1.522(7) . ?
C7 C8 1.411(7) . ?
C8 C9 1.384(7) . ?
C8 H8 0.9300 . ?
C9 C10 1.517(7) . ?
C10 F11 1.323(7) . ?
C10 F10 1.332(7) . ?
C10 F12 1.333(7) . ?
O1' C2' 1.262(11) . ?
O4' C9' 1.261(11) . ?
O2' C4' 1.262(11) . ?
O3' C7' 1.260(11) . ?
C1' F1' 1.341(11) . ?
C1' F2' 1.341(11) . ?
C1' F3' 1.352(11) . ?
C1' C2' 1.509(10) . ?
C2' C3' 1.396(10) . ?
C3' C4' 1.407(11) . ?
C3' H3' 0.9300 . ?
C4' C5' 1.509(11) . ?
C5' F5' 1.341(11) . ?
C5' F4' 1.344(11) . ?
C5' F6' 1.353(11) . ?
C7' C8' 1.392(10) . ?
C7' C6' 1.500(11) . ?
C6' F9' 1.342(11) . ?
C6' F7' 1.347(11) . ?
C6' F8' 1.353(11) . ?
C8' C9' 1.404(11) . ?
C8' H8' 0.9300 . ?
C9' C10' 1.506(11) . ?
C10' F11' 1.335(11) . ?
C10' F10' 1.336(11) . ?
C10' F12' 1.359(11) . ?
O7 Eu1 2.349(3) 2_655 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O4' Eu1 N1 C21 127(2) . . . . ?
O2' Eu1 N1 C21 5.6(12) . . . . ?
O1' Eu1 N1 C21 11(6) . . . . ?
O3' Eu1 N1 C21 75(5) . . . . ?
O7 Eu1 N1 C21 -73.8(3) 2_655 . . . ?
O1 Eu1 N1 C21 5.9(17) . . . . ?
O4 Eu1 N1 C21 75.2(16) . . . . ?
O5 Eu1 N1 C21 -179.7(3) . . . . ?
O6 Eu1 N1 C21 -130.4(3) . . . . ?
O2 Eu1 N1 C21 128.1(7) . . . . ?
O3 Eu1 N1 C21 1.4(4) . . . . ?
O4' Eu1 N1 C22 -40(2) . . . . ?
O2' Eu1 N1 C22 -161.3(12) . . . . ?
O1' Eu1 N1 C22 -155(6) . . . . ?
O3' Eu1 N1 C22 -92(5) . . . . ?
O7 Eu1 N1 C22 119.3(3) 2_655 . . . ?
O1 Eu1 N1 C22 -161.0(17) . . . . ?
O4 Eu1 N1 C22 -91.7(16) . . . . ?
O5 Eu1 N1 C22 13.4(3) . . . . ?
O6 Eu1 N1 C22 62.7(3) . . . . ?
O2 Eu1 N1 C22 -38.9(7) . . . . ?
O3 Eu1 N1 C22 -165.5(5) . . . . ?
F13 C13 C14 O5 -57.2(15) . . . . ?
F14' C13 C14 O5 40(3) . . . . ?
F15 C13 C14 O5 171.3(14) . . . . ?
F14 C13 C14 O5 61.7(13) . . . . ?
F15' C13 C14 O5 -170.8(19) . . . . ?
F13' C13 C14 O5 -71.2(15) . . . . ?
F13 C13 C14 C15 123.6(15) . . . . ?
F14' C13 C14 C15 -140(3) . . . . ?
F15 C13 C14 C15 -8.0(15) . . . . ?
F14 C13 C14 C15 -117.6(12) . . . . ?
F15' C13 C14 C15 10.0(19) . . . . ?
F13' C13 C14 C15 109.5(15) . . . . ?
O5 C14 C15 C16 -3.7(7) . . . . ?
C13 C14 C15 C16 175.4(4) . . . . ?
C14 C15 C16 O6 3.4(8) . . . . ?
C14 C15 C16 C17 -174.2(4) . . . . ?
O6 C16 C17 F18 113(3) . . . . ?
C15 C16 C17 F18 -69(3) . . . . ?
O6 C16 C17 F16 -39(3) . . . . ?
C15 C16 C17 F16 139(3) . . . . ?
O6 C16 C17 F17' 172.1(5) . . . . ?
C15 C16 C17 F17' -10.0(7) . . . . ?
O6 C16 C17 F18' 51.5(6) . . . . ?
C15 C16 C17 F18' -130.6(5) . . . . ?
O6 C16 C17 F16' -67.1(7) . . . . ?
C15 C16 C17 F16' 110.8(6) . . . . ?
O6 C16 C17 F17 -141(2) . . . . ?
C15 C16 C17 F17 37(2) . . . . ?
C22 C18 C19 C20 1.6(6) . . . . ?
C23 C18 C19 C20 -178.5(4) . . . . ?
C18 C19 C20 C21 -1.9(7) . . . . ?
C18 C19 C20 Br1 178.3(3) . . . . ?
C22 N1 C21 C20 3.1(6) . . . . ?
Eu1 N1 C21 C20 -164.6(3) . . . . ?
C19 C20 C21 N1 -0.4(7) . . . . ?
Br1 C20 C21 N1 179.3(3) . . . . ?
C21 N1 C22 C18 -3.5(6) . . . . ?
Eu1 N1 C22 C18 163.4(3) . . . . ?
C19 C18 C22 N1 1.2(6) . . . . ?
C23 C18 C22 N1 -178.7(4) . . . . ?
O7 N2 C23 N3 179.5(3) . . . . ?
C24 N2 C23 N3 -6.5(5) . . . . ?
O7 N2 C23 C18 -0.8(6) . . . . ?
C24 N2 C23 C18 173.2(4) . . . . ?
O8 N3 C23 N2 178.5(4) . . . . ?
C27 N3 C23 N2 -7.0(5) . . . . ?
O8 N3 C23 C18 -1.2(7) . . . . ?
C27 N3 C23 C18 173.3(4) . . . . ?
C19 C18 C23 N2 127.2(5) . . . . ?
C22 C18 C23 N2 -52.9(6) . . . . ?
C19 C18 C23 N3 -53.2(6) . . . . ?
C22 C18 C23 N3 126.8(5) . . . . ?
O7 N2 C24 C26 -48.4(5) . . . . ?
C23 N2 C24 C26 137.5(4) . . . . ?
O7 N2 C24 C25 70.8(5) . . . . ?
C23 N2 C24 C25 -103.3(4) . . . . ?
O7 N2 C24 C27 -169.7(3) . . . . ?
C23 N2 C24 C27 16.2(4) . . . . ?
O8 N3 C27 C29 -47.6(5) . . . . ?
C23 N3 C27 C29 137.8(4) . . . . ?
O8 N3 C27 C28 71.0(5) . . . . ?
C23 N3 C27 C28 -103.6(4) . . . . ?
O8 N3 C27 C24 -169.0(4) . . . . ?
C23 N3 C27 C24 16.4(4) . . . . ?
N2 C24 C27 N3 -17.7(4) . . . . ?
C26 C24 C27 N3 -134.6(4) . . . . ?
C25 C24 C27 N3 94.9(4) . . . . ?
N2 C24 C27 C29 -133.7(4) . . . . ?
C26 C24 C27 C29 109.4(4) . . . . ?
C25 C24 C27 C29 -21.1(5) . . . . ?
N2 C24 C27 C28 95.8(4) . . . . ?
C26 C24 C27 C28 -21.1(5) . . . . ?
C25 C24 C27 C28 -151.6(4) . . . . ?
O4' Eu1 O1 C2 -6(4) . . . . ?
O2' Eu1 O1 C2 130(4) . . . . ?
O1' Eu1 O1 C2 -12(52) . . . . ?
O3' Eu1 O1 C2 64(4) . . . . ?
O7 Eu1 O1 C2 -158(3) 2_655 . . . ?
O4 Eu1 O1 C2 64(3) . . . . ?
O5 Eu1 O1 C2 -43(5) . . . . ?
O6 Eu1 O1 C2 -85(3) . . . . ?
O2 Eu1 O1 C2 -6(3) . . . . ?
O3 Eu1 O1 C2 134(4) . . . . ?
N1 Eu1 O1 C2 129(2) . . . . ?
O4' Eu1 O2 C4 20(44) . . . . ?
O2' Eu1 O2 C4 -39(3) . . . . ?
O1' Eu1 O2 C4 12(4) . . . . ?
O3' Eu1 O2 C4 -86(8) . . . . ?
O7 Eu1 O2 C4 88(2) 2_655 . . . ?
O1 Eu1 O2 C4 11(2) . . . . ?
O4 Eu1 O2 C4 -85(3) . . . . ?
O5 Eu1 O2 C4 166(2) . . . . ?
O6 Eu1 O2 C4 92.0(19) . . . . ?
O3 Eu1 O2 C4 -38(2) . . . . ?
N1 Eu1 O2 C4 -140.9(16) . . . . ?
O4' Eu1 O3 C7 -18(2) . . . . ?
O2' Eu1 O3 C7 -11(19) . . . . ?
O1' Eu1 O3 C7 -63(3) . . . . ?
O3' Eu1 O3 C7 33(8) . . . . ?
O7 Eu1 O3 C7 -171.0(14) 2_655 . . . ?
O1 Eu1 O3 C7 -65.7(16) . . . . ?
O4 Eu1 O3 C7 32(3) . . . . ?
O5 Eu1 O3 C7 109.7(10) . . . . ?
O6 Eu1 O3 C7 -118.9(12) . . . . ?
O2 Eu1 O3 C7 -14.8(16) . . . . ?
N1 Eu1 O3 C7 111.8(13) . . . . ?
O4' Eu1 O4 C9 105(6) . . . . ?
O2' Eu1 O4 C9 -30(4) . . . . ?
O1' Eu1 O4 C9 40(5) . . . . ?
O3' Eu1 O4 C9 -95(100) . . . . ?
O7 Eu1 O4 C9 -67(8) 2_655 . . . ?
O1 Eu1 O4 C9 35(5) . . . . ?
O5 Eu1 O4 C9 175(5) . . . . ?
O6 Eu1 O4 C9 103.3(15) . . . . ?
O2 Eu1 O4 C9 108(6) . . . . ?
O3 Eu1 O4 C9 -34(4) . . . . ?
N1 Eu1 O4 C9 -115(5) . . . . ?
Eu1 O1 C2 C3 2(5) . . . . ?
Eu1 O1 C2 C1 -177(2) . . . . ?
F3 C1 C2 O1 -179(2) . . . . ?
F2 C1 C2 O1 -57(2) . . . . ?
F1 C1 C2 O1 61(2) . . . . ?
F3 C1 C2 C3 2.5(9) . . . . ?
F2 C1 C2 C3 124.4(7) . . . . ?
F1 C1 C2 C3 -118.0(6) . . . . ?
O1 C2 C3 C4 1(3) . . . . ?
C1 C2 C3 C4 179.7(6) . . . . ?
Eu1 O2 C4 C3 -14(3) . . . . ?
Eu1 O2 C4 C5 167.1(12) . . . . ?
C2 C3 C4 O2 5.4(19) . . . . ?
C2 C3 C4 C5 -175.7(6) . . . . ?
O2 C4 C5 F5 100.1(14) . . . . ?
C3 C4 C5 F5 -79.0(8) . . . . ?
O2 C4 C5 F6 -23.3(15) . . . . ?
C3 C4 C5 F6 157.7(6) . . . . ?
O2 C4 C5 F4 -143.7(14) . . . . ?
C3 C4 C5 F4 37.2(9) . . . . ?
Eu1 O3 C7 C8 -22.3(19) . . . . ?
Eu1 O3 C7 C6 161.5(8) . . . . ?
F8 C6 C7 O3 -35.3(12) . . . . ?
F7 C6 C7 O3 -156.3(10) . . . . ?
F9 C6 C7 O3 83.9(11) . . . . ?
F8 C6 C7 C8 148.1(7) . . . . ?
F7 C6 C7 C8 27.1(10) . . . . ?
F9 C6 C7 C8 -92.7(8) . . . . ?
O3 C7 C8 C9 -5.9(15) . . . . ?
C6 C7 C8 C9 170.1(6) . . . . ?
Eu1 O4 C9 C8 25(8) . . . . ?
Eu1 O4 C9 C10 -153(2) . . . . ?
C7 C8 C9 O4 6(7) . . . . ?
C7 C8 C9 C10 -176.5(7) . . . . ?
O4 C9 C10 F11 51(6) . . . . ?
C8 C9 C10 F11 -127.0(6) . . . . ?
O4 C9 C10 F10 173(6) . . . . ?
C8 C9 C10 F10 -4.8(9) . . . . ?
O4 C9 C10 F12 -68(6) . . . . ?
C8 C9 C10 F12 114.3(7) . . . . ?
O4' Eu1 O1' C2' -133(13) . . . . ?
O2' Eu1 O1' C2' 4(10) . . . . ?
O3' Eu1 O1' C2' -62(11) . . . . ?
O7 Eu1 O1' C2' 76(12) 2_655 . . . ?
O1 Eu1 O1' C2' 41(44) . . . . ?
O4 Eu1 O1' C2' -63(11) . . . . ?
O5 Eu1 O1' C2' -167(8) . . . . ?
O6 Eu1 O1' C2' 148(12) . . . . ?
O2 Eu1 O1' C2' -132(12) . . . . ?
O3 Eu1 O1' C2' 8(10) . . . . ?
N1 Eu1 O1' C2' -2(17) . . . . ?
O2' Eu1 O4' C9' 32(7) . . . . ?
O1' Eu1 O4' C9' 81(7) . . . . ?
O3' Eu1 O4' C9' -17(10) . . . . ?
O7 Eu1 O4' C9' 152(4) 2_655 . . . ?
O1 Eu1 O4' C9' 81(6) . . . . ?
O4 Eu1 O4' C9' -17(6) . . . . ?
O5 Eu1 O4' C9' -124(6) . . . . ?
O6 Eu1 O4' C9' 162(6) . . . . ?
O2 Eu1 O4' C9' -90(46) . . . . ?
O3 Eu1 O4' C9' 33(7) . . . . ?
N1 Eu1 O4' C9' -70(6) . . . . ?
O4' Eu1 O2' C4' 39(6) . . . . ?
O1' Eu1 O2' C4' -8(6) . . . . ?
O3' Eu1 O2' C4' 91(9) . . . . ?
O7 Eu1 O2' C4' -115(5) 2_655 . . . ?
O1 Eu1 O2' C4' -10(5) . . . . ?
O4 Eu1 O2' C4' 90(6) . . . . ?
O5 Eu1 O2' C4' 158(4) . . . . ?
O6 Eu1 O2' C4' -58(6) . . . . ?
O2 Eu1 O2' C4' 42(6) . . . . ?
O3 Eu1 O2' C4' -134(24) . . . . ?
N1 Eu1 O2' C4' 169(6) . . . . ?
O4' Eu1 O3' C7' 28(15) . . . . ?
O2' Eu1 O3' C7' -107(20) . . . . ?
O1' Eu1 O3' C7' -37(17) . . . . ?
O7 Eu1 O3' C7' -144(9) 2_655 . . . ?
O1 Eu1 O3' C7' -41(17) . . . . ?
O4 Eu1 O3' C7' 8(100) . . . . ?
O5 Eu1 O3' C7' 98(18) . . . . ?
O6 Eu1 O3' C7' 27(29) . . . . ?
O2 Eu1 O3' C7' 31(15) . . . . ?
O3 Eu1 O3' C7' -110(20) . . . . ?
N1 Eu1 O3' C7' 168(18) . . . . ?
Eu1 O1' C2' C3' 6(14) . . . . ?
Eu1 O1' C2' C1' -179(8) . . . . ?
F1' C1' C2' O1' -165(6) . . . . ?
F2' C1' C2' O1' 75(6) . . . . ?
F3' C1' C2' O1' -44(6) . . . . ?
F1' C1' C2' C3' 10(2) . . . . ?
F2' C1' C2' C3' -110.1(17) . . . . ?
F3' C1' C2' C3' 131.3(15) . . . . ?
O1' C2' C3' C4' -16(7) . . . . ?
C1' C2' C3' C4' 168.7(19) . . . . ?
Eu1 O2' C4' C3' 1(7) . . . . ?
Eu1 O2' C4' C5' -171(4) . . . . ?
C2' C3' C4' O2' 13(4) . . . . ?
C2' C3' C4' C5' -175.4(18) . . . . ?
O2' C4' C5' F5' -88(3) . . . . ?
C3' C4' C5' F5' 101(2) . . . . ?
O2' C4' C5' F4' 152(3) . . . . ?
C3' C4' C5' F4' -20(3) . . . . ?
O2' C4' C5' F6' 27(4) . . . . ?
C3' C4' C5' F6' -145(2) . . . . ?
Eu1 O3' C7' C8' -29(31) . . . . ?
Eu1 O3' C7' C6' 155(8) . . . . ?
O3' C7' C6' F9' -176(18) . . . . ?
C8' C7' C6' F9' 7(2) . . . . ?
O3' C7' C6' F7' 63(18) . . . . ?
C8' C7' C6' F7' -114.1(17) . . . . ?
O3' C7' C6' F8' -55(18) . . . . ?
C8' C7' C6' F8' 128.3(17) . . . . ?
O3' C7' C8' C9' 0(24) . . . . ?
C6' C7' C8' C9' 175.5(17) . . . . ?
Eu1 O4' C9' C8' -1(7) . . . . ?
Eu1 O4' C9' C10' -165(4) . . . . ?
C7' C8' C9' O4' 17(4) . . . . ?
C7' C8' C9' C10' -179.6(16) . . . . ?
O4' C9' C10' F11' -177(3) . . . . ?
C8' C9' C10' F11' 19(2) . . . . ?
O4' C9' C10' F10' -57(3) . . . . ?
C8' C9' C10' F10' 139.0(18) . . . . ?
O4' C9' C10' F12' 61(3) . . . . ?
C8' C9' C10' F12' -103(2) . . . . ?
C15 C14 O5 Eu1 -25.1(7) . . . . ?
C13 C14 O5 Eu1 155.7(3) . . . . ?
O4' Eu1 O5 C14 -45.9(18) . . . . ?
O2' Eu1 O5 C14 -174(2) . . . . ?
O1' Eu1 O5 C14 -13(4) . . . . ?
O3' Eu1 O5 C14 -114(5) . . . . ?
O7 Eu1 O5 C14 103.9(4) 2_655 . . . ?
O1 Eu1 O5 C14 -10.4(15) . . . . ?
O4 Eu1 O5 C14 -113.1(17) . . . . ?
O6 Eu1 O5 C14 33.3(4) . . . . ?
O2 Eu1 O5 C14 -47.7(7) . . . . ?
O3 Eu1 O5 C14 176.2(7) . . . . ?
N1 Eu1 O5 C14 174.0(4) . . . . ?
C15 C16 O6 Eu1 24.7(7) . . . . ?
C17 C16 O6 Eu1 -157.6(3) . . . . ?
O4' Eu1 O6 C16 45.9(14) . . . . ?
O2' Eu1 O6 C16 163.4(13) . . . . ?
O1' Eu1 O6 C16 114.7(19) . . . . ?
O3' Eu1 O6 C16 47(14) . . . . ?
O7 Eu1 O6 C16 -139.2(4) 2_655 . . . ?
O1 Eu1 O6 C16 118.9(7) . . . . ?
O4 Eu1 O6 C16 47(5) . . . . ?
O5 Eu1 O6 C16 -32.9(3) . . . . ?
O2 Eu1 O6 C16 42.8(5) . . . . ?
O3 Eu1 O6 C16 169.7(4) . . . . ?
N1 Eu1 O6 C16 -83.2(4) . . . . ?
C23 N2 O7 Eu1 -85.5(4) . . . 2_655 ?
C24 N2 O7 Eu1 101.1(4) . . . 2_655 ?
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1 PubChem 139127090
