Information card for entry 4303365

Structure parameters

• Formula: C28 H47 Cl2 N2 P Si W
• Calculated formula: C28 H47 Cl2 N2 P Si W
• SMILES: [WH]([Si](Cl)(Cl)C)([P](C)(C)C)(=Nc1c(cccc1C(C)C)C(C)C)=Nc1c(cccc1C(C)C)C(C)C
• Title of publication: β-Agostic Silylamido and Silyl-Hydrido Compounds of Molybdenum and Tungsten
• Authors of publication: Stanislav K. Ignatov; Andrey Y. Khalimon; Nicholas H. Rees; Alexei G. Razuvaev; Philip Mountford; Georgii I. Nikonov
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 9605 - 9622
• a: 10.0467 ± 0.0002 Å
• b: 32.2846 ± 0.0003 Å
• c: 10.5529 ± 0.0002 Å
• α: 90°
• β: 107.754 ± 0.0005°
• γ: 90°
• Cell volume: 3259.86 ± 0.1 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0402
• Residual factor for significantly intense reflections: 0.0295
• Weighted residual factors for significantly intense reflections: 0.0616
• Weighted residual factors for all reflections included in the refinement: 0.0652
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No