Information card for entry 4303394

Structure parameters

• Formula: Co4 Ge2 H66 Mo18 Na11 O101
• Calculated formula: Co4 Ge2 Mo18 Na11 O101
• SMILES: [Ge]123[O]45[Mo]678(=O)O[Mo]9%10%11(=O)O[Mo]%12%13(=O)(O6)O[Mo]6%14%15(=O)O[Mo]%16%17(=O)(O[Mo]%18(=O)(O[Mo]%194(=O)(O[Mo]45(=O)(O[Mo](=O)(O6)(O%12)([O]5[Co]6%12%20([O]4[Co]4%21%22([O]=%19)[O]%193[Co]3([O]=%18)([O]=%16)([OH2])[O]%21[Mo]%16%18%21(=O)O[Mo]%23%24(=O)(O[Mo]%25%26(=O)(O[Mo]%27%28(=O)(O[Mo]%29%30%31(=O)O[Mo]%32%33(=O)(O%16)O[Mo]%16%34(=O)(O[Mo]%35(=O)(O[Mo](=O)(O%16)(O%23)(O%18)[O]%21%24[Ge]([O]%31%33%34)([O]%26%28%35)[O]%20%22[Co]5%19([O]=%14)([O]=%30)[O]3%32)(O%27)O%25)O%29)=[O]6)=[O]%12)=[O]4)[OH2])[O]2%13%15)O8)O7)(O9)[O]1%11%17)O%10.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[Na+].[Na+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O
• Title of publication: Rare Sandwich-Type Polyoxomolybdates Constructed from Di-/Tetra-Nuclear Transition-Metal Clusters and Trivacant Keggin Germanomolybdate Fragments
• Authors of publication: Suzhi Li; Junwei Zhao; Pengtao Ma; Juan Du; Jingyang Niu; Jingping Wang
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 9819 - 9830
• a: 11.584 ± 0.003 Å
• b: 12.856 ± 0.004 Å
• c: 17.173 ± 0.007 Å
• α: 97.38 ± 0.006°
• β: 106.906 ± 0.006°
• γ: 111.713 ± 0.004°
• Cell volume: 2191.7 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0653
• Residual factor for significantly intense reflections: 0.0601
• Weighted residual factors for significantly intense reflections: 0.1672
• Weighted residual factors for all reflections included in the refinement: 0.1733
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No