Information card for entry 4304196

Structure parameters

• Formula: Co H140 Mo36 N22 O172 Sb6
• Calculated formula: Co Mo36 O193 Sb12
• SMILES: O=[Mo]123(=O)O[Mo]45(=O)(=O)[O]6[Mo]7(=O)(O[Mo]89%10%11=[O][Co]%12([O]=[Mo]%13%14(O9)(=O)O[Mo]9%15([O]1[Sb]16([O]%10%13)([O]25)[O]7[Mo]256([O]7[Sb]%10%13%16%17[O]%14[Mo]%14(=O)(O[Mo]%18%19%20(O[Mo]%21(=O)(O[Mo]%22(=O)(=O)(O8)O[Mo]8%23([O]%24[Sb]%25%26([O]%21%22)([O]%18[Mo]%18%21([O]%26([Sb]([O]%17[Mo]([O]%11%10)(=O)([O]8%25)(O2)=O)O[Sb]([O]%16%14)[O]%20%18)[Mo]%24(O%23)(=O)(O%21)=O)(=O)=O)[O]%13%19)(=O)=O)=O)=O)([O]2[Sb]8%107([O]91)[O]5[Mo]1(O[Mo]5([O]8[Mo]2(O%15)(=O)(=O)O5)(=O)([O]%101)=O)(=O)(O6)=O)=O)=O)(=O)O3)([OH2])([O]=[Mo]1235O[Mo]67(O[Mo]8(=O)(=O)[O]7[Sb]79%10%11[O]%13[Mo]%14%15(O8)(=O)[O]%10[Sb]8%10%16%17[O]%18[Mo]%19(=[O]%12)(O1)(=O)O[Mo]1%12%20([O]%21[Mo]%22(=O)(=O)(O[Mo]%23%24(=O)(=O)[O]%25[Mo](=O)(O3)(O%23)(=O)[O]3[Sb]%21%25([O]2%19)([O]%22%24)[O]%12[Sb]2%12%19%21[O]%22[Mo]%18(=O)(O%14)(=O)[O]%16[Sb]%14[O]%15[Mo]%15%13([O]%13%11[Sb]([O]%17[Mo]([O]58)(=O)([O]9[Mo]5(O6)([O]7[Mo]%13(O5)(=O)(O%15)=O)(=O)=O)(O[Mo]53([O]%102)(=O)[O]%12[Mo]2(O[Mo]3([O]%19[Mo]%22(O%20)(=O)(=O)O3)(=O)([O]%212)=O)(=O)(O5)=O)=O)O%14)(=O)=O)O1)=O)(=O)=O)[OH2])(O4)=O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O
• Title of publication: An Unusual Asymmetric Polyoxomolybdate Containing Mixed-Valence Antimony and Its Derivatives: [Sb4VSb2IIIMo18O73(H2O)2]12- and {M(H2O)2[Sb4VSb2IIIMo18O73(H2O)2]2}22- (M = MnII, FeII, CuII or CoII)
• Authors of publication: Ganglin Xue; Xuemei Liu; Haisheng Xu; Huaiming Hu; Feng Fu; Jiwu Wang
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 2011 - 2016
• a: 13.8343 ± 0.0007 Å
• b: 17.9604 ± 0.0011 Å
• c: 19.8332 ± 0.0011 Å
• α: 69.774 ± 0.003°
• β: 82.854 ± 0.003°
• γ: 69.451 ± 0.003°
• Cell volume: 4329.8 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0539
• Residual factor for significantly intense reflections: 0.0409
• Weighted residual factors for significantly intense reflections: 0.1477
• Weighted residual factors for all reflections included in the refinement: 0.1605
• Goodness-of-fit parameter for all reflections included in the refinement: 1.153
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No