Information card for entry 4304463

Structure parameters

• Formula: C45 H43 N2 Ni O P3
• Calculated formula: C45 H43 N2 Ni O P3
• SMILES: [Ni]12345(P(=NP(=N[P]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)[cH]2[cH]1[cH]3[cH]4[cH]52.O1CCCC1
• Title of publication: Migratory Insertion of the R2P Group into a Nitrogen-Nitrogen Bond - A Novel Type of Rearrangement in Phosphorus-Nitrogen Ligand Chemistry. 3. The Rearrangement of Triphosphinohydrazide Ligand -N(PPh2)-N(PPh2)2 to Triphosphazenide Anion {[(Ph2P-N]2PPh2}- in the Coordination Sphere of Divalent Cobalt and Nickel
• Authors of publication: Vyacheslav V. Sushev; Natalia V. Belina; Georgy K. Fukin; Yuriy A. Kurskiy; Alexander N. Kornev; Gleb A. Abakumov
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 2608 - 2612
• a: 9.8206 ± 0.0005 Å
• b: 10.1212 ± 0.0005 Å
• c: 20.944 ± 0.001 Å
• α: 100.428 ± 0.001°
• β: 96.917 ± 0.001°
• γ: 107.854 ± 0.001°
• Cell volume: 1914.05 ± 0.16 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0378
• Residual factor for significantly intense reflections: 0.0332
• Weighted residual factors for significantly intense reflections: 0.0824
• Weighted residual factors for all reflections included in the refinement: 0.0845
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No