Information card for entry 4304591

Structure parameters

• Chemical name: Bis[μ-(4,4'-bipyridyl-κN;κN')(μ-bis(bis(o-methoxyphenoxy) phosphino)phenylamine-κP;κP')digold(I)] Perchlorate
• Formula: C88 H82 Au4 Cl4 N6 O32 P4
• Calculated formula: C88 H82 Au4 Cl4 N6 O32 P4
• SMILES: c1(ccccc1OC)O[P](Oc1ccccc1OC)(N(c1ccccc1)[P](Oc1ccccc1OC)(Oc1ccccc1OC)[Au]1)[Au][n]2ccc(cc2)c2cc[n](cc2)[Au][P](Oc2ccccc2OC)(Oc2ccccc2OC)N(c2ccccc2)[P](Oc2ccccc2OC)(Oc2ccccc2OC)[Au][n]2ccc(cc2)c2cc[n]1cc2.[O-]Cl(=O)(=O)=O.Cl(=O)(=O)(=O)[O-].[O-]Cl(=O)(=O)=O.Cl(=O)(=O)(=O)[O-]
• Title of publication: Bi-, Tetra-, and Hexanuclear AuI and Binuclear AgI Complexes and AgI Coordination Polymers Containing Phenylaminobis(phosphonite), PhN{P(OC6H4OMe-o)2}2, and Pyridyl Ligands
• Authors of publication: Chelladurai Ganesamoorthy; Maravanji S. Balakrishna; Joel T. Mague; Heikki M. Tuononen
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 2764 - 2776
• a: 17.779 ± 0.003 Å
• b: 13.18 ± 0.002 Å
• c: 20.72 ± 0.003 Å
• α: 90°
• β: 106.502 ± 0.002°
• γ: 90°
• Cell volume: 4655.3 ± 1.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.045
• Residual factor for significantly intense reflections: 0.0331
• Weighted residual factors for significantly intense reflections: 0.0728
• Weighted residual factors for all reflections included in the refinement: 0.0774
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No