Information card for entry 4304952

Structure parameters

• Chemical name: Lithium tetrahydrofuran Uranium(IV) hexakis(tert-butoxide)
• Formula: C32 H70 Li2 O8 U
• Calculated formula: C32 H61 Li2 O8 U
• Title of publication: Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)6
• Authors of publication: Skye Fortier; Guang Wu; Trevor W. Hayton
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 4752 - 4761
• a: 22.17 ± 0.003 Å
• b: 16.43 ± 0.002 Å
• c: 10.885 ± 0.0015 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3964.9 ± 0.9 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.1128
• Residual factor for significantly intense reflections: 0.0596
• Weighted residual factors for significantly intense reflections: 0.1326
• Weighted residual factors for all reflections included in the refinement: 0.1484
• Goodness-of-fit parameter for all reflections included in the refinement: 0.874
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No