Information card for entry 4304955

Structure parameters

• Chemical name: U(VI) hexakis(tert-butoxide)
• Formula: C24 H54 O6 U
• Calculated formula: C24 O6 U
• Title of publication: Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)6
• Authors of publication: Skye Fortier; Guang Wu; Trevor W. Hayton
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 4752 - 4761
• a: 28.536 ± 0.006 Å
• b: 16.791 ± 0.003 Å
• c: 9.7246 ± 0.0019 Å
• α: 90°
• β: 93.8 ± 0.03°
• γ: 90°
• Cell volume: 4649.3 ± 1.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 12
• Hermann-Mauguin space group symbol: C 1 2/m 1
• Hall space group symbol: -C 2y
• Residual factor for all reflections: 0.1176
• Residual factor for significantly intense reflections: 0.0537
• Weighted residual factors for significantly intense reflections: 0.1206
• Weighted residual factors for all reflections included in the refinement: 0.1393
• Goodness-of-fit parameter for all reflections included in the refinement: 0.911
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No