Information card for entry 4305467

Structure parameters

• Formula: C48 H73 Cl O2 P4 Pt2 Si2
• Calculated formula: C48 H73 Cl O2 P4 Pt2 Si2
• SMILES: [Pt]12(Cl)[P](c3c([Si]2(O[Si]24O[PtH]([P](c5c4cccc5)(C(C)C)C(C)C)[P](c4c2cccc4)(C(C)C)C(C)C)c2ccccc2[P]1(C(C)C)C(C)C)cccc3)(C(C)C)C(C)C
• Title of publication: Silanol-Based Pincer Pt(II) Complexes: Synthesis, Structure, and Unusual Reactivity
• Authors of publication: Edward E. Korshin; Gregory Leitus; Linda J. W. Shimon; Leonid Konstantinovski; David Milstein
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 7177 - 7189
• a: 22.827 ± 0.005 Å
• b: 12.115 ± 0.002 Å
• c: 18.502 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5116.7 ± 1.8 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 29
• Hermann-Mauguin space group symbol: P c a 21
• Hall space group symbol: P 2c -2ac
• Residual factor for all reflections: 0.0458
• Residual factor for significantly intense reflections: 0.0378
• Weighted residual factors for significantly intense reflections: 0.0635
• Weighted residual factors for all reflections included in the refinement: 0.0656
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No