Information card for entry 4306158

Structure parameters

• Chemical name: bis(2,2'-bipyridinemethoxo(2-pyridinecarboxylato)ruthenium(IV)) (mu-nitrido) hexafurorophosphate
• Formula: C34 H34 F6 N7 O8 P Ru2
• Calculated formula: C34 H30 F6 N7 O8 P Ru2
• SMILES: [Ru]12(OC)(OC(=O)c3[n]1cccc3)(=[N]=[Ru]13(OC)(OC(=O)c4[n]1cccc4)[n]1c(cccc1)c1[n]3cccc1)[n]1c(cccc1)c1[n]2cccc1.[P](F)(F)(F)(F)(F)[F-].O.O
• Title of publication: Reactions of Ruthenium Complexes Having Pyridyl-Containing Ligands, 2-Pyridinecarboxylato and 2,2'-Bipyridine, with an Azide Ion: Formation of Nitrido-Bridged Diruthenium Complexes
• Authors of publication: Sayuri Matsumura; Kazunori Shikano; Takao Oi; Noriyuki Suzuki; Hirotaka Nagao
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 9125 - 9127
• a: 14.743 ± 0.004 Å
• b: 12.996 ± 0.004 Å
• c: 19.824 ± 0.006 Å
• α: 90°
• β: 92.328 ± 0.0011°
• γ: 90°
• Cell volume: 3795.1 ± 1.9 ų
• Cell temperature: 93.1 K
• Ambient diffraction temperature: 93.1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0648
• Weighted residual factors for all reflections included in the refinement: 0.1371
• Goodness-of-fit parameter for all reflections included in the refinement: 1.173
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No