Information card for entry 4309875

Structure parameters

• Chemical name: trans-Dichloro(1,3-di-tert-butyl-2,4-bis(2- methoxyphenoxy)-[1,3,2,4]-diazadiphosphetidine) palladium(II) Dichloromethane solvate
• Formula: C46 H68 Cl6 N4 O8 P4 Pd
• Calculated formula: C46 H68 Cl6 N4 O8 P4 Pd
• Title of publication: Cyclodiphosphazanes with Hemilabile Ponytails: Synthesis, Transition Metal Chemistry (Ru(II), Rh(I), Pd(II), Pt(II)), and Crystal and Molecular Structures of Mononuclear (Pd(II), Rh(I)) and Bi- and Tetranuclear Rhodium(I) Complexes
• Authors of publication: P. Chandrasekaran; Joel T. Mague; Maravanji S. Balakrishna
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 7925 - 7932
• a: 10.1978 ± 0.0009 Å
• b: 19.0612 ± 0.0002 Å
• c: 15.449 ± 0.001 Å
• α: 90°
• β: 107.108 ± 0.001°
• γ: 90°
• Cell volume: 2870.1 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0422
• Residual factor for significantly intense reflections: 0.0371
• Weighted residual factors for significantly intense reflections: 0.0947
• Weighted residual factors for all reflections included in the refinement: 0.0979
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No