Information card for entry 4309975

Structure parameters

• Common name: 1b
• Chemical name: tetrakis(μ~2~-Pivalamidato)-tetraammine-tetrabromo-tetrachloro-pentaplatinum
• Formula: C26 H62 Br4 Cl4 N8 O6 Pt5
• Calculated formula: C26 H62 Br4 Cl4 N8 O6 Pt5
• SMILES: C1(C(C)(C)C)=[NH][Pt]2([NH3])([NH]=C(C(C)(C)C)O[Pt]2(O1)(CC(=O)C)(Cl)Cl)[NH3].[Pt](Br)(Br)([Br-])[Br-].[Pt]12([NH]=C(C(C)(C)C)O[Pt]2(OC(C(C)(C)C)=[NH]1)(CC(=O)C)(Cl)Cl)([NH3])[NH3]
• Title of publication: Synthesis of the Pivalamidate-Bridged Pentanuclear Platinum(II,III) Linear Complexes with Pt...Pt Interactions
• Authors of publication: Kazuko Matsumoto; Saiko Arai; Masahiko Ochiai; Wanzhi Chen; Ayako Nakata; Hiromi Nakai; Shuhei Kinoshita
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 8552 - 8560
• a: 11.838 ± 0.006 Å
• b: 11.12 ± 0.005 Å
• c: 20.017 ± 0.009 Å
• α: 90°
• β: 104.014 ± 0.008°
• γ: 90°
• Cell volume: 2557 ± 2 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1854
• Residual factor for significantly intense reflections: 0.0571
• Weighted residual factors for significantly intense reflections: 0.0984
• Weighted residual factors for all reflections included in the refinement: 0.1312
• Goodness-of-fit parameter for all reflections included in the refinement: 0.895
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No