Information card for entry 4310546

Structure parameters

• Chemical name: (μ~2~-terbutylisocianide)bis(terbutylisocianide) (bis(μ~2~-bis(diphenylphosphino) methane)-di-nickel hexafluorophosphate
• Formula: C66 H73 Cl2 F6 N3 Ni2 P5
• Calculated formula: C66 H73 Cl2 F6 N3 Ni2 P5
• Title of publication: Structural, Spectroscopic, and Electrochemical Studies of the Complexes [Ni2(μ-CNR)(CNR)2(μ-dppm)2]n+ (n= 0, 1, 2): Unusual Examples of Nickel(0)-Nickel(I) and Nickel(0)-Nickel(II) Mixed Valency
• Authors of publication: Gregory M. Ferrence; Eugenio Simón-Manso; Brian K. Breedlove; Leah Meeuwenberg; Clifford P. Kubiak
• Journal of publication: Inorganic Chemistry
• Year of publication: 2004
• Journal volume: 43
• Pages of publication: 1071 - 1081
• a: 10.6578 ± 0.0007 Å
• b: 13.3188 ± 0.0009 Å
• c: 13.5122 ± 0.0006 Å
• α: 103.439 ± 0.003°
• β: 101.316 ± 0.003°
• γ: 110.051 ± 0.003°
• Cell volume: 1670.64 ± 0.18 ų
• Cell temperature: 193 K
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 7
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for significantly intense reflections: 0.047
• Weighted residual factors for all reflections included in the refinement: 0.115
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MO-Kα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No