Information card for entry 4310960

Structure parameters

• Chemical name: Bis((tetrakis(mu2-trifluoroacetato-O,O')-dirhodium(II,II)- acetone-O)
• Formula: C22 H12 F24 O18 Rh4
• Calculated formula: C22 H12 F24 O18 Rh4
• SMILES: [Rh]1234([Rh]5([O]=C(O1)C(F)(F)F)([O]([Rh]1678[Rh]([O]=C(O1)C(F)(F)F)([O]=C([O]56)C(F)(F)F)(OC(=[O]7)C(F)(F)F)([O]=C(O8)C(F)(F)F)[O]=C(C)C)C(=[O]2)C(F)(F)F)(OC(=[O]3)C(F)(F)F)[O]=C(O4)C(F)(F)F)[O]=C(C)C
• Title of publication: On the Road to a Termolecular Complex with Acetone: A Heterometallic Supramolecular Network {[Rh2(O2CCF3)4].μ2-OCMe2.[Cu4(O2CCF3)4]}
• Authors of publication: Evgeny V. Dikarev; Kristian W. Andreini; Marina A. Petrukhina
• Journal of publication: Inorganic Chemistry
• Year of publication: 2004
• Journal volume: 43
• Pages of publication: 3219 - 3224
• a: 17.789 ± 0.0007 Å
• b: 8.6834 ± 0.0004 Å
• c: 26.3947 ± 0.0011 Å
• α: 90°
• β: 104.546 ± 0.001°
• γ: 90°
• Cell volume: 3946.5 ± 0.3 ų
• Cell temperature: 98 ± 2 K
• Ambient diffraction temperature: 98 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0692
• Residual factor for significantly intense reflections: 0.0514
• Weighted residual factors for significantly intense reflections: 0.1117
• Weighted residual factors for all reflections included in the refinement: 0.1196
• Goodness-of-fit parameter for all reflections included in the refinement: 1.066
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No