Information card for entry 4311634

Structure parameters

• Formula: C26 H28 Cl6 N8 O2 Pt2 Zn
• Calculated formula: C26 H28 Cl6 N8 O2 Pt2 Zn
• SMILES: [Pt]12([n]3c(N=[N]2c2[n]([Pt]4([n]5c(N=[N]4c4[n]1cccc4)cccc5)Cl)cccc2)cccc3)Cl.[Zn](Cl)(Cl)([Cl-])[Cl-].O=C(C)C.O=C(C)C
• Title of publication: Complex Reduction Chemistry of (abpy)PtCl2, abpy = 2,2'-Azobispyridine: Formation of Cyclic [(μ,η2:η1-abpy)PtCl]22+ with a New Coordination Mode for abpy and a Near-Infrared Ligand-to-Ligand Intervalence Charge Transfer Absorption of the One-Electron Reduced State
• Authors of publication: Akbey Dogan; Biprajit Sarkar; Axel Klein; Falk Lissner; Thomas Schleid; Jan Fiedler; Stanislav Záliš; Vimal K. Jain; Wolfgang Kaim
• Journal of publication: Inorganic Chemistry
• Year of publication: 2004
• Journal volume: 43
• Pages of publication: 5973 - 5980
• a: 10.378 ± 0.002 Å
• b: 14.727 ± 0.003 Å
• c: 22.318 ± 0.003 Å
• α: 90°
• β: 93.306 ± 0.014°
• γ: 90°
• Cell volume: 3405.3 ± 1.1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0612
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0843
• Weighted residual factors for all reflections included in the refinement: 0.0898
• Goodness-of-fit parameter for all reflections included in the refinement: 0.68
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No