Information card for entry 4312717

Structure parameters

• Common name: [Ru2TlBrF3X(PPh3)4].CHCl3
• Formula: C73 H61 Br Cl3 F4 P4 Ru2 Tl
• Calculated formula: C72.719 H60.719 Br1.389 Cl2.157 F3.611 P4 Ru2 Tl
• Title of publication: Bridging Fluorides and Hard/Soft Mismatch in d6 and d8 Complexes: The Case of [Tl(μ-F)3Ru(PPh3)3]
• Authors of publication: Claus Becker; Iris Kieltsch; Diego Broggini; Antonio Mezzetti
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 8417 - 8429
• a: 13.1385 ± 0.0005 Å
• b: 25.1451 ± 0.0009 Å
• c: 22.4359 ± 0.0007 Å
• α: 90°
• β: 93.053 ± 0.001°
• γ: 90°
• Cell volume: 7401.6 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1517
• Residual factor for significantly intense reflections: 0.0568
• Weighted residual factors for significantly intense reflections: 0.1428
• Weighted residual factors for all reflections included in the refinement: 0.1653
• Goodness-of-fit parameter for all reflections included in the refinement: 0.842
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No