Different Oxidation States of Copper(I, I/II, II) Thiocyanate Complexes Containing 1,2,4-Triazole as a Bridging Ligand: Syntheses, Crystal Structures, and Magnetic Properties of 2-D Polymer CuI(admtrz)SCN, Linear Trinuclear [CuI2CuII(admtrz)6(SCN)2](ClO4)2, and Triangular Trinuclear [CuII3(admtrz)4(SCN)3(μ3-OH)(H2O)](ClO4)2.H2O (admtrz = 4-Amino-3,5-dimethyl-1,2,4-triazole)
Authors of publication
Jia-Cheng Liu; Guo; Jin-Shun Huang; Xiao-Zeng You
Journal of publication
Inorganic Chemistry
Year of publication
2003
Journal volume
42
Pages of publication
235 - 243
a
18.772 ± 0.004 Å
b
11.739 ± 0.002 Å
c
22.838 ± 0.005 Å
α
90°
β
91.11 ± 0.03°
γ
90°
Cell volume
5031.7 ± 1.8 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
7
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0536
Residual factor for significantly intense reflections
0.0482
Weighted residual factors for significantly intense reflections
0.1265
Weighted residual factors for all reflections included in the refinement
0.1325
Goodness-of-fit parameter for all reflections included in the refinement
