Information card for entry 4312981

Structure parameters

• Formula: C20 H18 Cl2 N2 Pt S2
• Calculated formula: C20 H18 Cl2 N2 Pt S2
• SMILES: [Pt]1(Cl)(Cl)[S](c2c(Sc3ccccc3)cccc2)(c2ccccc2)=NC(C)=[NH]1
• Title of publication: Platinum(IV)-Mediated Nitrile-Sulfimide Coupling: A Route to Heterodiazadienes
• Authors of publication: Anastassiya V. Makarycheva-Mikhailova; Nadezhda A. Bokach; Vadim Yu. Kukushkin; Paul F. Kelly; Liam M. Gilby; Maxim L. Kuznetsov; Kathryn E. Holmes; Matti Haukka; Jonathan Parr; Julia M. Stonehouse; Mark R. J. Elsegood; Armando J. L. Pombeiro
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 301 - 311
• a: 9.4631 ± 0.0005 Å
• b: 17.7135 ± 0.0009 Å
• c: 12.4772 ± 0.0007 Å
• α: 90°
• β: 100.347 ± 0.002°
• γ: 90°
• Cell volume: 2057.47 ± 0.19 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0386
• Residual factor for significantly intense reflections: 0.0242
• Weighted residual factors for significantly intense reflections: 0.0447
• Weighted residual factors for all reflections included in the refinement: 0.0505
• Goodness-of-fit parameter for all reflections included in the refinement: 1.105
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No