Information card for entry 4313008

Structure parameters

• Common name: trans(P,P)-[Ru(bpy)(Me~2~Pqn)~2~](PF~6~)~2~
• Chemical name: trans(P,P)-(2,2'-bipyridyl)bis(8-dimethylphosphinoquinoline)ruthenium(II) Bis(hexafluorophosphate)
• Formula: C32 H32 F12 N4 P4 Ru
• Calculated formula: C32 H32 F12 N4 P4 Ru
• SMILES: [Ru]123([P](c4cccc5ccc[n]1c45)(C)C)([P](c1cccc4ccc[n]2c14)(C)C)[n]1ccccc1c1[n]3cccc1.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Ruthenium(II) Complexes Containing 8-(Dimethylphosphino)quinoline (Me2Pqn): Preparation, Crystal Structures, and Electrochemical and Spectroscopic Properties of [Ru(bpy or phen)3-n(Me2Pqn)n](PF6)2(bpy = 2,2'-Bipyridine; phen = 1,10-Phenanthroline; n= 1, 2, or 3)
• Authors of publication: Takayoshi Suzuki; Takashi Kuchiyama; Shinobu Kishi; Sumio Kaizaki; Hideo D. Takagi; Masako Kato
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 785 - 795
• a: 37.414 ± 0.008 Å
• b: 40.172 ± 0.007 Å
• c: 9.9872 ± 0.0013 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 15011 ± 5 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 6
• Space group number: 43
• Hermann-Mauguin space group symbol: F d d 2
• Hall space group symbol: F 2 -2d
• Residual factor for all reflections: 0.1053
• Residual factor for significantly intense reflections: 0.0388
• Weighted residual factors for significantly intense reflections: 0.0991
• Weighted residual factors for all reflections included in the refinement: 0.1187
• Goodness-of-fit parameter for all reflections included in the refinement: 1.002
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No