Information card for entry 4313010

Structure parameters

• Common name: fac-[Ru(Me~2~Pqn)~3~](PF~6~)~2~
• Chemical name: fac-Tris(8-dimethylphosphinoquinoline)ruthenium(II) Hexafluorophosphate
• Formula: C33 H36 F12 N3 P5 Ru
• Calculated formula: C33 H36 F12 N3 P5 Ru
• Title of publication: Ruthenium(II) Complexes Containing 8-(Dimethylphosphino)quinoline (Me2Pqn): Preparation, Crystal Structures, and Electrochemical and Spectroscopic Properties of [Ru(bpy or phen)3-n(Me2Pqn)n](PF6)2(bpy = 2,2'-Bipyridine; phen = 1,10-Phenanthroline; n= 1, 2, or 3)
• Authors of publication: Takayoshi Suzuki; Takashi Kuchiyama; Shinobu Kishi; Sumio Kaizaki; Hideo D. Takagi; Masako Kato
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 785 - 795
• a: 20.843 ± 0.003 Å
• b: 17.797 ± 0.003 Å
• c: 23.939 ± 0.003 Å
• α: 90°
• β: 115.644 ± 0.009°
• γ: 90°
• Cell volume: 8005 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1238
• Residual factor for significantly intense reflections: 0.0654
• Weighted residual factors for significantly intense reflections: 0.2091
• Weighted residual factors for all reflections included in the refinement: 0.248
• Goodness-of-fit parameter for all reflections included in the refinement: 1.073
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No