Information card for entry 4313389

Structure parameters

• Formula: C32 H56 Au B9 P3
• Calculated formula: C32 H55 Au B9 P3
• SMILES: [Au]1([P]([C]234[C]56([P]1(C(C)C)C(C)C)[BH]178[BH]9%10%11[BH]251[BH]139[BH]23%10[BH]57%11[BH]3([BH]412)[BH]685)(C(C)C)C(C)C)[P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Luminescentnido-Carborane-Diphosphine Anions [(PR2)2C2B9H10]-(R = Ph,iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes
• Authors of publication: Olga Crespo; M. Concepción Gimeno; Peter G. Jones; Antonio Laguna; José M. López-de-Luzuriaga; Miguel Monge; Juan L. Pérez; Miguel A. Ramón
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 2061 - 2068
• a: 17.7478 ± 0.0016 Å
• b: 19.8792 ± 0.0018 Å
• c: 21.396 ± 0.0018 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7548.8 ± 1.2 ų
• Cell temperature: 143 ± 2 K
• Ambient diffraction temperature: 143 ± 2 K
• Number of distinct elements: 5
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0459
• Residual factor for significantly intense reflections: 0.0232
• Weighted residual factors for significantly intense reflections: 0.0479
• Weighted residual factors for all reflections included in the refinement: 0.0521
• Goodness-of-fit parameter for all reflections included in the refinement: 0.976
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No