Information card for entry 4313564

Structure parameters

• Common name: (Me)(dpap)Rh(III)TPP
• Formula: C65 H46 N4 P Rh
• Calculated formula: C65 H46 N4 P Rh
• Title of publication: Complexation of Diphenyl(phenylacetenyl)phosphine to Rhodium(III) Tetraphenyl Porphyrins: Synthesis and Structural, Spectroscopic, and Thermodynamic Studies
• Authors of publication: Eugen Stulz; Sonya M. Scott; Andrew D. Bond; Sijbren Otto; Jeremy K. M. Sanders
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 3086 - 3096
• a: 13.3949 ± 0.0007 Å
• b: 13.3979 ± 0.0008 Å
• c: 14.1945 ± 0.0009 Å
• α: 83.942 ± 0.003°
• β: 86.237 ± 0.003°
• γ: 89.875 ± 0.004°
• Cell volume: 2527.7 ± 0.3 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1337
• Residual factor for significantly intense reflections: 0.1134
• Weighted residual factors for significantly intense reflections: 0.2722
• Weighted residual factors for all reflections included in the refinement: 0.2873
• Goodness-of-fit parameter for all reflections included in the refinement: 1.098
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No