Ruthenium(II) and Ruthenium(IV) Complexes Containing κ1-P-, κ2-P,O-, and κ3-P,N,O-Iminophosphorane-Phosphine Ligands Ph2PCH2P{NP(O)(OR)2}Ph2 (R = Et, Ph): Synthesis, Reactivity, Theoretical Studies, and Catalytic Activity in Transfer Hydrogenation of Cyclohexanone
Authors of publication
Victorio Cadierno; Pascale Crochet; Josefina Díez; Joaquín García-Álvarez; Sergio E. García-Garrido; José Gimeno; Santiago García-Granda; Miguel A. Rodríguez
Journal of publication
Inorganic Chemistry
Year of publication
2003
Journal volume
42
Pages of publication
3293 - 3307
a
23.3059 ± 0.0003 Å
b
9.1822 ± 0.0001 Å
c
22.6599 ± 0.0004 Å
α
90°
β
90°
γ
90°
Cell volume
4849.21 ± 0.12 Å3
Cell temperature
200 ± 2 K
Ambient diffraction temperature
200 ± 2 K
Number of distinct elements
7
Space group number
29
Hermann-Mauguin space group symbol
P c a 21
Hall space group symbol
P 2c -2ac
Residual factor for all reflections
0.0424
Residual factor for significantly intense reflections
0.0385
Weighted residual factors for significantly intense reflections
0.107
Weighted residual factors for all reflections included in the refinement
0.1354
Goodness-of-fit parameter for all reflections included in the refinement
