Information card for entry 4314105

Structure parameters

• Formula: As2 H65 Na12 Ni3 O100.5 W18
• Calculated formula: As2 Na10 Ni3 O99.5 W18
• Title of publication: Structure, Magnetism, and Electrochemistry of the Multinickel Polyoxoanions [Ni~6~As~3~W~24~O~94~(H~2~O)~2~]^17-^, [Ni~3~Na(H~2~O)~2~(AsW~9~O~34~)~2~]^11-^, and [Ni~4~Mn~2~P~3~W~24~O~94~(H~2~O)~2~]^17-^
• Authors of publication: Israel M. Mbomekalle; Bineta Keita; Martine Nierlich; Ulrich Kortz; Patrick Berthet; Louis Nadjo
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 5143 - 5152
• a: 12.228 ± 0.002 Å
• b: 16.743 ± 0.003 Å
• c: 23.342 ± 0.005 Å
• α: 78.5 ± 0.03°
• β: 80.69 ± 0.03°
• γ: 78.66 ± 0.03°
• Cell volume: 4554 ± 1.6 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1319
• Residual factor for significantly intense reflections: 0.0695
• Weighted residual factors for significantly intense reflections: 0.147
• Weighted residual factors for all reflections included in the refinement: 0.174
• Goodness-of-fit parameter for all reflections included in the refinement: 0.968
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No