Information card for entry 4316447

Structure parameters

• Common name: [Pt2H2(SetBu)2(PPh3)2]_CH2Cl2
• Chemical name: [Pt2H2(SetBu)2(PPh3)2]_CH2Cl2
• Formula: C45 H52 Cl2 P2 Pt2 Se2
• Calculated formula: C45 H52 Cl2 P2 Pt2 Se2
• SMILES: [PtH]1([Se]([PtH]([Se]1C(C)(C)C)[P](c1ccccc1)(c1ccccc1)c1ccccc1)C(C)(C)C)[P](c1ccccc1)(c1ccccc1)c1ccccc1.C(Cl)Cl
• Title of publication: Syntheses of Selenolato-Bridged Dinuclear Hydridoplatinum Complexes [Pt2H2(μ-SetBu)2(PPh3)2] and [Pt2H(SetBu)(μ-SetBu)2(PPh3)2]: Unusual Thermal Reaction of Hydrido(1,1-Dimethylethaneselenolato) Platinum Complex cis-[PtH(SetBu)(PPh3)2]
• Authors of publication: Norio Nakata; Takashige Ikeda; Akihiko Ishii
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 8112 - 8116
• a: 16.169 ± 0.003 Å
• b: 10.802 ± 0.002 Å
• c: 26.764 ± 0.005 Å
• α: 90°
• β: 105.471 ± 0.004°
• γ: 90°
• Cell volume: 4505.2 ± 1.5 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0708
• Residual factor for significantly intense reflections: 0.0509
• Weighted residual factors for significantly intense reflections: 0.1146
• Weighted residual factors for all reflections included in the refinement: 0.1247
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No