Information card for entry 4316818

Structure parameters

• Formula: C61 H52.5 Mn N6.5 O P2
• Calculated formula: C61 H49 Mn N6.5 O P2
• Title of publication: Mechanism for the Formation of Substituted Manganese(V) Cyanidonitrido Complexes: Crystallographic and Kinetic Study of the Substitution Reactions of trans-[MnN(H2O)(CN)4]2- with Monodentate Pyridine and Bidentate Pyridine-Carboxylate Ligands
• Authors of publication: Hendrik J. van der Westhuizen; Reinout Meijboom; Marietjie Schutte; Andreas Roodt
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 9599 - 9608
• a: 10.2924 ± 0.0015 Å
• b: 13.106 ± 0.002 Å
• c: 20.557 ± 0.003 Å
• α: 79.521 ± 0.003°
• β: 87.217 ± 0.004°
• γ: 78.756 ± 0.004°
• Cell volume: 2674.1 ± 0.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1429
• Residual factor for significantly intense reflections: 0.0524
• Weighted residual factors for significantly intense reflections: 0.099
• Weighted residual factors for all reflections included in the refinement: 0.1274
• Goodness-of-fit parameter for all reflections included in the refinement: 0.925
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No