Information card for entry 4317567

Structure parameters

• Formula: Cs4 Fe4 H62 O97 Se2 W18
• Calculated formula: Cs4 Fe4 O97 Se2 W18
• Title of publication: Synthesis and Characterization of Iron()-Substituted, Dimeric Polyoxotungstates, [Fe~4~(H~2~O)~10~(β-XW~9~O~33~)~2~]^n-^ (n = 6, X = As^III^, Sb^III^; n = 4, X = Se^IV^, Te^IV^)
• Authors of publication: Ulrich Kortz; Masha G. Savelieff; Bassem S. Bassil; Bineta Keita; Louis Nadjo
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 783 - 789
• a: 12.6648 ± 0.001 Å
• b: 12.8247 ± 0.001 Å
• c: 16.1588 ± 0.0013 Å
• α: 75.654 ± 0.001°
• β: 87.955 ± 0.001°
• γ: 64.361 ± 0.001°
• Cell volume: 2284.6 ± 0.3 ų
• Cell temperature: 167 ± 2 K
• Ambient diffraction temperature: 167 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0734
• Residual factor for significantly intense reflections: 0.0487
• Weighted residual factors for significantly intense reflections: 0.1107
• Weighted residual factors for all reflections included in the refinement: 0.1268
• Goodness-of-fit parameter for all reflections included in the refinement: 1.086
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No