Information card for entry 4317978

Structure parameters

• Formula: C60 H86 Ag B Cl2 F4 N4 O0.5 Pt2
• Calculated formula: C60 H86 Ag1.0004 B Cl2 F4 N4 O0.5 Pt2
• Title of publication: Mechanism of Silver-Promoted Ligand Metathesis in Square-Planar Complexes of d8 Ions. Kinetics of Formation and Molecular Structures of a Trinuclear Intermediate [(Me)(N-N)Pt(μ-Cl)Ag(μ-Cl)Pt(N-N)(Me)]+ and Its Dinuclear Evolution Product [(Me)(N-N)Pt(μ-Cl)Pt(N-N)(Me)]+ (N-N = ArNC(Me)C(Me)NAr, Ar = 2,6-(i-Pr)2C6H3)
• Authors of publication: Vincenzo G. Albano; Martino Di Serio; Magda Monari; Ida Orabona; Achille Panunzi; Francesco Ruffo
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 2672 - 2677
• a: 10.5016 ± 0.0003 Å
• b: 17.9486 ± 0.0005 Å
• c: 18.7605 ± 0.0005 Å
• α: 109.921 ± 0.001°
• β: 90.684 ± 0.001°
• γ: 91.212 ± 0.001°
• Cell volume: 3323.12 ± 0.16 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1144
• Residual factor for significantly intense reflections: 0.0425
• Weighted residual factors for significantly intense reflections: 0.085
• Weighted residual factors for all reflections included in the refinement: 0.098
• Goodness-of-fit parameter for all reflections included in the refinement: 0.81
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No