Information card for entry 4318156

Structure parameters

• Common name: {(MeOH)2Rh2(OAc(CF2)9F)4}.2MeOH
• Formula: C44 H16 F76 O12 Rh2
• Calculated formula: C44 H14 F76 O12 Rh2
• Title of publication: Carbon Dioxide as a Solubility "Switch" for the Reversible Dissolution of Highly Fluorinated Complexes and Reagents in Organic Solvents: Application to Crystallization
• Authors of publication: Philip G. Jessop; Marilyn M. Olmstead; Christopher D. Ablan; Megan Grabenauer; Daniel Sheppard; Charles A. Eckert; Charles L. Liotta
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 3463 - 3468
• a: 9.665 ± 0.003 Å
• b: 13.903 ± 0.004 Å
• c: 14.195 ± 0.004 Å
• α: 90.917 ± 0.004°
• β: 95.208 ± 0.004°
• γ: 107.581 ± 0.004°
• Cell volume: 1808.9 ± 0.9 ų
• Cell temperature: 91 ± 2 K
• Ambient diffraction temperature: 91 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.215
• Residual factor for significantly intense reflections: 0.1574
• Weighted residual factors for significantly intense reflections: 0.4379
• Weighted residual factors for all reflections included in the refinement: 0.4641
• Goodness-of-fit parameter for all reflections included in the refinement: 1.096
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No