Information card for entry 4318921

Structure parameters

• Formula: C26 H24 Br2 N4 O2 Os
• Calculated formula: C26 H24 Br2 N4 O2 Os
• SMILES: [Os]12(Br)(Br)([n]3ccccc3C=[N]1c1ccc(OC)cc1)[n]1ccccc1C=[N]2c1ccc(OC)cc1
• Title of publication: Photoinduced and Chemical Oxidation of Coordinated Imine to Amide in Isomeric Osmium(II) Complexes of N-Arylpyridine-2-carboxaldimines. Synthesis, Characterization, Electron Transfer Properties, and Structural Studies
• Authors of publication: Amit K. Ghosh; Kunal K. Kamar; Parimal Paul; Shie-Ming Peng; Gene-Hsiang Lee; Sreebrata Goswami
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 6343 - 6350
• a: 8.8976 ± 0.0012 Å
• b: 18.37 ± 0.004 Å
• c: 15.956 ± 0.003 Å
• α: 90°
• β: 94.53 ± 0.02°
• γ: 90°
• Cell volume: 2599.8 ± 0.8 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0849
• Residual factor for significantly intense reflections: 0.0429
• Weighted residual factors for significantly intense reflections: 0.1018
• Weighted residual factors for all reflections included in the refinement: 0.1146
• Goodness-of-fit parameter for all reflections included in the refinement: 1.003
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No