Variable Coordination Modes of NO2- in a Series of Ag(I) Complexes Containing Triorganophosphines, -arsines, and -stibines. Syntheses, Spectroscopic Characterization (IR, 1H and 31P NMR, Electrospray Ionization Mass), and Structures of [AgNO2(R3E)x] Adducts (E = P, As, Sb, x = 1-3)
Authors of publication
Augusto Cingolani; Effendy; Maura Pellei; Claudio Pettinari; Carlo Santini; Brian W. Skelton; Allan H. White
Journal of publication
Inorganic Chemistry
Year of publication
2002
Journal volume
41
Pages of publication
6633 - 6645
a
13.333 ± 0.002 Å
b
11.599 ± 0.002 Å
c
22.787 ± 0.003 Å
α
90°
β
99.748 ± 0.003°
γ
90°
Cell volume
3473.1 ± 0.9 Å3
Cell temperature
150 K
Ambient diffraction temperature
150 K
Number of distinct elements
7
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.048
Residual factor for significantly intense reflections
0.03
Weighted residual factors for all reflections
0.048
Weighted residual factors for all reflections included in the refinement
0.044
Goodness-of-fit parameter for all reflections
1.056
Goodness-of-fit parameter for all reflections included in the refinement
