Information card for entry 4319274

Structure parameters

• Common name: [{(2-C5H4N)CMe(CH2NSiMe3)2}Ti(Nt-Bu)(py)]
• Formula: C24 H43 N5 Si2 Ti
• Calculated formula: C24 H43 N5 Si2 Ti
• SMILES: [Ti]12(=NC(C)(C)C)(N([Si](C)(C)C)CC(C)(CN1[Si](C)(C)C)c1[n]2cccc1)[n]1ccccc1
• Title of publication: Group 4 Imido Complexes Stabilized by a Tridentate Diamido-Donor Ligand
• Authors of publication: Alexander J. Blake; Philip E. Collier; Lutz H. Gade; Philip Mountford; Julian Lloyd; Stephen M. Pugh; Martin Schubart; Michael E. G. Skinner; Dominique J. M. Trösch
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 870 - 877
• a: 9.535 ± 0.003 Å
• b: 10.125 ± 0.003 Å
• c: 15.948 ± 0.003 Å
• α: 90.63 ± 0.03°
• β: 106.61 ± 0.03°
• γ: 105.4 ± 0.02°
• Cell volume: 1416.1 ± 0.7 ų
• Cell temperature: 150 ± 0.2 K
• Ambient diffraction temperature: 150 ± 0.2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0494
• Residual factor for significantly intense reflections: 0.0416
• Weighted residual factors for all reflections: 0.1084
• Weighted residual factors for significantly intense reflections: 0.1011
• Goodness-of-fit parameter for all reflections: 1.025
• Goodness-of-fit parameter for significantly intense reflections: 1.033
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No