Information card for entry 4319494

Structure parameters

• Formula: C30 H36 N2 P2 Si
• Calculated formula: C30 H36 N2 P2 Si
• SMILES: P(=N[Si](C)(C)C)(N(P(c1ccccc1)c1ccccc1)CCC)(c1ccccc1)c1ccccc1
• Title of publication: New Silylated Iminophosphorano(amino)phosphines Me3SiNPPh2N(R)PPh2 (R = Et, nPr, nBu). Crystal and Molecular Structure of Trimethylsilyliminophosphorano(propylamino)diphenylphosphine Me3SiNPPh2N(nPr)PPh2. Further Oxidative Derivatization with S, Se, and Azides, Titanium(IV) Transmetalation of the Imine, and Syntheses of Rhodium(I), Palladium(II), and Platinum(II) Complexes of These Iminophosphorano(amino)phosphines
• Authors of publication: Maravanji S. Balakrishna; S. Teipel; A. Alan Pinkerton; Ronald G. Cavell
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 1802 - 1808
• a: 10.235 ± 0.001 Å
• b: 16.802 ± 0.002 Å
• c: 17.075 ± 0.002 Å
• α: 90°
• β: 101.05 ± 0.01°
• γ: 90°
• Cell volume: 2881.9 ± 0.6 ų
• Cell temperature: 221 ± 1 K
• Ambient diffraction temperature: 221 ± 1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.044
• Weighted residual factors for significantly intense reflections: 0.054
• Goodness-of-fit parameter for all reflections included in the refinement: 1.42
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No