Information card for entry 4320029

Structure parameters

• Chemical name: [Ta(N-2,6-C6H3Pri2){MeC(2-NC5H4)(CH2NSiMe3)2}Cl(py)]
• Formula: C32 H51 Cl N5 Si2 Ta
• Calculated formula: C32 H51 Cl N5 Si2 Ta
• SMILES: [Ta]12(=Nc3c(cccc3C(C)C)C(C)C)(N([Si](C)(C)C)CC(c3[n]2cccc3)(CN1[Si](C)(C)C)C)([n]1ccccc1)Cl
• Title of publication: Group 5 Imido Complexes Derived from Diamido-Pyridine Ligands
• Authors of publication: Stephen M. Pugh; Alexander J. Blake; Lutz H. Gade; Philip Mountford
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 3992 - 4001
• a: 10.631 ± 0.002 Å
• b: 10.968 ± 0.003 Å
• c: 16.225 ± 0.004 Å
• α: 94.62 ± 0.02°
• β: 96.77 ± 0.02°
• γ: 106.06 ± 0.02°
• Cell volume: 1792.6 ± 0.8 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0426
• Weighted residual factors for significantly intense reflections: 0.05
• Goodness-of-fit parameter for significantly intense reflections: 0.9592
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No