Information card for entry 4320281

Structure parameters

• Chemical name: Bis-5,5'-(1,3-propanediyldiimino)-2,2-dimethyl-4-hexene-3-onato samarium bis(trimethylsilyl)-amido
• Formula: C25 H50 N3 O2 Si2 Sm
• Calculated formula: C25 H50 N3 O2 Si2 Sm
• SMILES: [Sm]123(N([Si](C)(C)C)[Si](C)(C)C)OC(=CC(=[N]3CCC[N]1=C(C=C(O2)C(C)(C)C)C)C)C(C)(C)C
• Title of publication: Anhydrous Lanthanide Schiff Base Complexes and Their Preparation Using Lanthanide Triflate Derived Amides
• Authors of publication: Steven A. Schuetz; Victor W. Day; Roger D. Sommer; Arnold L. Rheingold; John A. Belot
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 5292 - 5295
• a: 10.6401 ± 0.0015 Å
• b: 25.826 ± 0.004 Å
• c: 12.042 ± 0.002 Å
• α: 90°
• β: 106.338 ± 0.002°
• γ: 90°
• Cell volume: 3175.4 ± 0.8 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0609
• Residual factor for significantly intense reflections: 0.0327
• Weighted residual factors for all reflections: 0.0616
• Weighted residual factors for significantly intense reflections: 0.0562
• Goodness-of-fit parameter for all reflections: 0.939
• Goodness-of-fit parameter for significantly intense reflections: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No